Methodology for Disjoining Pressure of Free Water Nanofilms

The disjoining pressure has a significant influence on the stability of thin films, which is important in various biological, environmental, and industrial processes. However, due to its complicated nature, especially in nanoscale, a convenient way is still lack. Here, a methodology derived from film thermodynamics was developed to determine the disjoining pressure of thin films using molecular dynamics (MD) simulations. The obtained disjoining pressure was purely attractive for pure water films, and compared with that from the Hamaker constant by Lifshitz-van der Waals theory. This method can be readily applied to similar aqueous films, which will enhance the interpretation of laboratory experiments and extend previous theoretical framework

Emerging One-/Two-Dimensional Heteronanostructure Integrating SiC Nanowires with MoS₂ Nanosheets for Efficient Electrocatalytic Hydrogen Evolution

MoS2 has emerged as a good application prospect in the electrocatalytic hydrogen evolution reaction (HER). Nevertheless, the catalytic activity of MoS2 is greatly restricted by its inferior electrical conductivity, inadequate exposure of active edge sites, and sluggish water dissociation dynamics. Herein, a 1D/2D heteronanostructure composed of SiC nanowires wrapped with MoS2 nanosheets was prepared via the hydrothermal synthesis of MoS2 on highly connected SiC nanowires (SiCnw). The nanocomposites exhibit an emerging tectorum-like morphology with interface connections of C–Mo bonds, which benefit the efficient interfacial transmission of electrons. Due to the synergetic catalytic effects of MoS2 nanosheets and SiC nanowires, the MoS2/SiCnw nanocomposites possess efficient catalytic performance with a low Tafel slope (55 mV/dec). SiC nanocrystals could reduce the activated water dissociation energy barrier, and the morphologies of connected nanowires could improve the active site exposure and charge transport. The nanocomposites possess favorable hydrogen adsorption free energy from density functional theory (DFT) calculations. The electrocatalytic performance of MoS2/SiCnw nanocomposites could be further improved by assembling the nanocomposites on a carbon fiber paper to enhance the electronic transmission efficiency

Table_3_Cerebral Intraparenchymal Hemorrhage Changes Patients’ Gut Bacteria Composition and Function.xls

Gut bacteria consists of 150 times more genes than humans that are vital for health. Several studies revealed that gut bacteria are associated with disease status and influence human behavior and mentality. Whether human brain injury alters the gut bacteria is yet unclear, we tested 20 fecal samples from patients with cerebral intraparenchymal hemorrhage and corresponding healthy controls through metagenomic shotgun sequencing. The composition of patients’ gut bacteria changed significantly at the phylum level; Verrucomicrobiota was the specific phylum colonized in the patients’ gut. The functional alteration was observed in the patients’ gut bacteria, including high metabolic activity for nutrients or neuroactive compounds, strong antibiotic resistance, and less virulence factor diversity. The changes in the transcription and metabolism of differential species were more evident than those of the non-differential species between groups, which is the primary factor contributing to the functional alteration of patients with cerebral intraparenchymal hemorrhage.</p

DataSheet_1_Cerebral Intraparenchymal Hemorrhage Changes Patients’ Gut Bacteria Composition and Function.pdf

Gut bacteria consists of 150 times more genes than humans that are vital for health. Several studies revealed that gut bacteria are associated with disease status and influence human behavior and mentality. Whether human brain injury alters the gut bacteria is yet unclear, we tested 20 fecal samples from patients with cerebral intraparenchymal hemorrhage and corresponding healthy controls through metagenomic shotgun sequencing. The composition of patients’ gut bacteria changed significantly at the phylum level; Verrucomicrobiota was the specific phylum colonized in the patients’ gut. The functional alteration was observed in the patients’ gut bacteria, including high metabolic activity for nutrients or neuroactive compounds, strong antibiotic resistance, and less virulence factor diversity. The changes in the transcription and metabolism of differential species were more evident than those of the non-differential species between groups, which is the primary factor contributing to the functional alteration of patients with cerebral intraparenchymal hemorrhage.</p

Additive Manufacturing of Resilient SiC Nanowire Aerogels

Resilient ceramic aerogels are emerging as a fascinating material that features light weight, low thermal conductivity, and recoverable compressibility, promising widespread prospects in the fields of heat insulation, catalysis, filtration, and aerospace exploration. However, the construction of the resilient ceramic aerogels with rational designed multiscale architectures aiming for tunable physical and mechanical performances remains a major challenge. Here, 3D constructed resilient SiC nanowire aerogels possessing programmed geometries and engineered mechanical properties are created via additive manufacturing. The Young’s modulus of the fabricated SiC nanowire aerogel lattices are tuned systematically from 0.012 MPa to 5.800 MPa spanning over 2 orders of magnitude. More importantly, the customized lightweight and resilient SiC nanowire aerogels show a low thermal conductivity (0.046 W m–1 K–1). The present work provides another approach to the design and rapid fabrication of resilient ceramic aerogels toward flexible thermal management devices, lightweight engineered structures, and other potential applications

One-Pot Synthesis of Benzoazole-Substituted Thioenamines via a Cross Dehydrogenation Coupling (CDC) Reaction

An iodine-catalyzed synthesis of benzoazole-substituted thioenamines in a one-pot manner was reported. Using 2-aminothiophenols (or 2-aminophenols or 1,2-phenylenediamines), tetramethylthiuram disulfide (TMTD), and enamines (mainly indoles) as starting materials, the target C­(sp2)–S formation products (benzoazole-substituted thioenamines) could be furnished smoothly in good yields. The reaction might proceed through an electrophilic substitution pathway in a cross dehydrogenation coupling (CDC) manner. The protocol is metal-free and features easy performance, a one-pot manner, a good functional group tolerance, and good yields

Table_7_Cerebral Intraparenchymal Hemorrhage Changes Patients’ Gut Bacteria Composition and Function.xls

Gut bacteria consists of 150 times more genes than humans that are vital for health. Several studies revealed that gut bacteria are associated with disease status and influence human behavior and mentality. Whether human brain injury alters the gut bacteria is yet unclear, we tested 20 fecal samples from patients with cerebral intraparenchymal hemorrhage and corresponding healthy controls through metagenomic shotgun sequencing. The composition of patients’ gut bacteria changed significantly at the phylum level; Verrucomicrobiota was the specific phylum colonized in the patients’ gut. The functional alteration was observed in the patients’ gut bacteria, including high metabolic activity for nutrients or neuroactive compounds, strong antibiotic resistance, and less virulence factor diversity. The changes in the transcription and metabolism of differential species were more evident than those of the non-differential species between groups, which is the primary factor contributing to the functional alteration of patients with cerebral intraparenchymal hemorrhage.</p

Table_2_Cerebral Intraparenchymal Hemorrhage Changes Patients’ Gut Bacteria Composition and Function.xls

Gut bacteria consists of 150 times more genes than humans that are vital for health. Several studies revealed that gut bacteria are associated with disease status and influence human behavior and mentality. Whether human brain injury alters the gut bacteria is yet unclear, we tested 20 fecal samples from patients with cerebral intraparenchymal hemorrhage and corresponding healthy controls through metagenomic shotgun sequencing. The composition of patients’ gut bacteria changed significantly at the phylum level; Verrucomicrobiota was the specific phylum colonized in the patients’ gut. The functional alteration was observed in the patients’ gut bacteria, including high metabolic activity for nutrients or neuroactive compounds, strong antibiotic resistance, and less virulence factor diversity. The changes in the transcription and metabolism of differential species were more evident than those of the non-differential species between groups, which is the primary factor contributing to the functional alteration of patients with cerebral intraparenchymal hemorrhage.</p

Additive Manufacturing of Resilient SiC Nanowire Aerogels

Resilient ceramic aerogels are emerging as a fascinating material that features light weight, low thermal conductivity, and recoverable compressibility, promising widespread prospects in the fields of heat insulation, catalysis, filtration, and aerospace exploration. However, the construction of the resilient ceramic aerogels with rational designed multiscale architectures aiming for tunable physical and mechanical performances remains a major challenge. Here, 3D constructed resilient SiC nanowire aerogels possessing programmed geometries and engineered mechanical properties are created via additive manufacturing. The Young’s modulus of the fabricated SiC nanowire aerogel lattices are tuned systematically from 0.012 MPa to 5.800 MPa spanning over 2 orders of magnitude. More importantly, the customized lightweight and resilient SiC nanowire aerogels show a low thermal conductivity (0.046 W m–1 K–1). The present work provides another approach to the design and rapid fabrication of resilient ceramic aerogels toward flexible thermal management devices, lightweight engineered structures, and other potential applications

Additive Manufacturing of Resilient SiC Nanowire Aerogels

Resilient ceramic aerogels are emerging as a fascinating material that features light weight, low thermal conductivity, and recoverable compressibility, promising widespread prospects in the fields of heat insulation, catalysis, filtration, and aerospace exploration. However, the construction of the resilient ceramic aerogels with rational designed multiscale architectures aiming for tunable physical and mechanical performances remains a major challenge. Here, 3D constructed resilient SiC nanowire aerogels possessing programmed geometries and engineered mechanical properties are created via additive manufacturing. The Young’s modulus of the fabricated SiC nanowire aerogel lattices are tuned systematically from 0.012 MPa to 5.800 MPa spanning over 2 orders of magnitude. More importantly, the customized lightweight and resilient SiC nanowire aerogels show a low thermal conductivity (0.046 W m–1 K–1). The present work provides another approach to the design and rapid fabrication of resilient ceramic aerogels toward flexible thermal management devices, lightweight engineered structures, and other potential applications