39 research outputs found
Dear Reader
<p>Cell scratch test and Transwell were used to measure the migration abilities of HSVSMCs. NC = Negative control group, only control siRNA transfected; GAS5(-) = lncRNA-GAS5 knockdown group transfected with silence siRNA. <b>A:</b>Cell scratch test was used to measure the migration abilities of HSVSMCs. The results showed that the HSVSMCs have the best migration abilities in the first 24 hours. Values are mean±SE, N = 4. <b>B:</b> The migration abilities of HSVSMCs measured by Transwell. After transfected by lncRNA-GAS5 siRNA for 48 hours, the HSVSMCs were passage into the Transwell Inserts. Then 4 hours, 7 hours, 10 hours later, the migration HSVSMCs were photographed and counted, respectively. Knockdown of lncRNA-GAS5 expression promotes migration of HSVSMCs. Optical microscope images under 200x magnification. <b>C:</b> The migration abilities of HSVSMCs were reflected indirectly by the new migration cells counting with Transwell. Silencing of lncRNA-GAS5 expression increses migration ability of HSVSMCs. Values are mean±SE, N = 10; *, P<0.05.</p
Supplementary material from Female adult puncture-induced plant volatiles promote mating success of the pea leafminer via enhancing vibrational signals
Table S1: Comparison of cuticular hydrocarbon compounds in whole-body extracts between 2 day old virgin male and female leafminers; Table S2: Comparison of percentages and amount of the headspace volatiles of punctured leaves and female-leaf complex
Supplementary material from Female adult puncture-induced plant volatiles promote mating success of the pea leafminer via enhancing vibrational signals
Table S1: Comparison of cuticular hydrocarbon compounds in whole-body extracts between 2 day old virgin male and female leafminers; Table S2: Comparison of percentages and amount of the headspace volatiles of punctured leaves and female-leaf complex
A Facile and General Coating Approach to Moisture/Water-Resistant Metal–Organic Frameworks with Intact Porosity
The
moisture sensitivity of many metal–organic frameworks
(MOFs) poses a critical issue for their large-scale real application.
One of the most effective methods to solve this problem is to convert
the surface of MOFs from hydrophilic to hydrophobic. Herein, we develop
a general strategy to modify hydrophobic polydimethysiloxane (PDMS)
on the surface of MOF materials to significantly enhance their moisture
or water resistance by a facile vapor deposition technique. MOF-5,
HKUST-1, and ZnBT as representative vulnerable MOFs were successfully
coated by PDMS, and these coated samples well inherited their original
crystalline nature and pore characteristics. Strikingly, the surface
areas of these MOFs were nearly 100% retained upon PDMS-coating. Such
a coating process might render MOFs applicable in the presence of
water or humidity in extended fields such as gas sorption and catalysis
On the Interfacial Behavior of Catenated Poly(l‑lactide) at the Air–Water Interface
Interfacial properties of polymeric materials are significantly
influenced by their architectural structures and spatial features,
while such a study of topologically interesting macromolecules is
rarely reported. In this work, we reported, for the first time, the
interfacial behavior of catenated polyÂ(l-lactide) (C-PLA)
at the air–water interface and compared it with its linear
analogue (L-PLA). The isotherms of surface pressure–area per
repeating unit showed significant interfacial behavioral differences
between the two polymers with different topologies. Isobaric creep
experiments and compression–expansion cycles also showed that
C-PLA demonstrated higher stability at the air–water interface.
Interestingly, when the films at different surface pressures were
transferred via the Langmuir–Blodgett method, successive atomic
force microscopy imaging displayed distinct nanomorphologies, in which
the surface of C-PLA exhibited nanofibrous structures, while that
of the L-PLA revealed a smoother topology with less fiber-like structures
3D Temperature-Controlled Interchangeable Pattern for Size-Selective Nanoparticle Capture
Patterned surfaces with distinct regularity and structured
arrangements
have attracted great interest due to their extensive promising applications.
Although colloidal patterning has conventionally been used to create
such surfaces, herein, we introduce a novel 3D patterned polyÂ(N-isopropylacrylamide) (PNIPAM) surface, synthesized by
using a combination of colloidal templating and surface-initiated
photoinduced electron transfer-reversible addition–fragmentation
chain transfer (SI-PET-RAFT) polymerization. In order to investigate
the temperature-driven 3D morphological variations at a lower critical
solution temperature (LCST) of ∼32 °C, multifaceted characterization
techniques were employed. Atomic force microscopy confirmed the morphological
transformations at 20 and 40 °C, while water contact angle measurements,
upon heating, revealed distinct trends, offering insights into the
correlation between surface wettability and topography adaptations.
Moreover, quartz crystal microbalance with dissipation monitoring
and electrochemical measurements were employed to detect the topographical
adjustments of the unique hollow capsule structure within the LCST.
Tests using different sizes of PSNPs shed light on the size-selective
capture–release potential of the patterned PNIPAM, accentuating
its biomimetic open–close behavior. Notably, our approach negates
the necessity for expensive proteins, harnessing temperature adjustments
to facilitate the noninvasive and efficient reversible capture and
release of nanostructures. This advancement hopes to pave the way
for future innovative cellular analysis platforms
Free-Standing Copper Nanowire Network Current Collector for Improving Lithium Anode Performance
Lithium metal is
one of the most attractive anode materials for next-generation lithium
batteries due to its high specific capacity and low electrochemical
potential. However, the poor cycling performance and serious safety
hazards, caused by the growth of dendritic and mossy lithium, has
long hindered the application of lithium metal based batteries. Herein,
we reported a rational design of free-standing Cu nanowire (CuNW)
network to suppress the growth of dendritic lithium via accommodating
the lithium metal in three-dimensional (3D) nanostructures. We demonstrated
that as high as 7.5 mA h cm–2 of lithium can be
plated into the free-standing copper nanowire (CuNW) current collector
without the growth of dendritic lithium. The lithium metal anode based
on the CuNW exhibited high Coulombic efficiency (average 98.6% during
200 cycles) and outstanding rate performance owing to the suppression
of lithium dendrite growth and high conductivity of CuNW network.
Our results demonstrate that the rational nanostructural design of
current collector could be a promising strategy to improve the performance
of lithium metal anode enabling its application in next-generation
lithium–metal based batteries
DataSheet1_Two kinematic transformations of the Pamir salient since the Mid-Cenozoic: Constraints from multi-timescale deformation analysis.XLSX
The Pamir salient is a key part of the Himalayan–Tibetan Plateau orogenic system and has undergone intense tectonic deformation during the India–Asian collision. Delineating the Cenozoic kinematics and geodynamics of the Pamir salient requires a comprehensive understanding of the active arcuate structures along its frontal margin, from the perspective of the multi-spatiotemporal evolution of deformation patterns. Here, we reviewed the deformation rates of the major structures at different timescales, reanalyzed the published Global Positioning System velocities, and examined the present-day seismicity to constrain the kinematics of the Pamir salient since the Late Cenozoic. Integrated with the crustal evolution history during the Middle–Late Cenozoic and the deep structure, we proposed a new model to explain the multi-stage kinematics and associated geodynamics of the Pamir salient. During ∼37–24 Ma, the initial Pamir salient moved northward via radial thrusting that rotated the basins on both sides, which was driven by the continuous compression of the Indian slab after the breakoff of its oceanic part. During ∼23–12 Ma, the gravitational collapse of the Central and South Pamir crusts, which was induced by the breakoff of the continental part of the Indian slab, triggered the extension within the Pamir and foreland-ward movement of the upper crust. The upper crustal materials moved in varying directions due to the differential strength of the foreland areas, transforming the crustal kinematics from radial thrusting into a combination of radial thrusting and transfer faulting. Since the coupling of the Indian and Pamir slabs at ∼12–11 Ma, the deformation propagation towards the forelands accelerated, after which the kinematics of the Pamir salient exhibited asymmetric radial thrusting that has been sustained until the present. The asymmetric radial thrusting was likely driven by the compressive stress effect of the lithospheric basal shear generated by the underthrusting of the cratonic Indian lithosphere, which further led to the rollback of the Pamir slab and the consequent migratory extension in the South Pamir.</p