Palladium-Catalyzed Domino Heck/Aryne Carbopalladation/C–H Functionalization: Synthesis of Heterocycle-Fused 9,10-Dihydrophenanthrenes

A novel palladium-catalyzed domino Heck/aryne carbopalladation/C–H functionalization reaction using in situ generated arynes has been developed in which three new C–C bonds and a carbon quaternary center are formed. This methodology affords moderate to excellent yields of heterocycle-fused 9,10-dihydrophenanthrenes

sj-docx-1-cad-10.1177_00111287231218706 – Supplemental material for Unveiling Segregation’s Impact: Analyzing the Relationship Between Dimensions and Police-Involved Homicide of Minorities in U.S. Counties

Supplemental material, sj-docx-1-cad-10.1177_00111287231218706 for Unveiling Segregation’s Impact: Analyzing the Relationship Between Dimensions and Police-Involved Homicide of Minorities in U.S. Counties by Yunhan Zhao, Dan He and Shay Reszka in Crime & Delinquency</p

sj-txt-5-cad-10.1177_00111287231218706 – Unveiling Segregation’s Impact: Analyzing the Relationship Between Dimensions and Police-Involved Homicide of Minorities in U.S. Counties

sj-txt-5-cad-10.1177_00111287231218706 for Unveiling Segregation’s Impact: Analyzing the Relationship Between Dimensions and Police-Involved Homicide of Minorities in U.S. Counties by Yunhan Zhao, Dan He and Shay Reszka in Crime & Delinquency</p

sj-docx-3-cad-10.1177_00111287231218706 – Supplemental material for Unveiling Segregation’s Impact: Analyzing the Relationship Between Dimensions and Police-Involved Homicide of Minorities in U.S. Counties

Supplemental material, sj-docx-3-cad-10.1177_00111287231218706 for Unveiling Segregation’s Impact: Analyzing the Relationship Between Dimensions and Police-Involved Homicide of Minorities in U.S. Counties by Yunhan Zhao, Dan He and Shay Reszka in Crime & Delinquency</p

sj-docx-4-cad-10.1177_00111287231218706 – Supplemental material for Unveiling Segregation’s Impact: Analyzing the Relationship Between Dimensions and Police-Involved Homicide of Minorities in U.S. Counties

Supplemental material, sj-docx-4-cad-10.1177_00111287231218706 for Unveiling Segregation’s Impact: Analyzing the Relationship Between Dimensions and Police-Involved Homicide of Minorities in U.S. Counties by Yunhan Zhao, Dan He and Shay Reszka in Crime & Delinquency</p

sj-docx-2-cad-10.1177_00111287231218706 – Supplemental material for Unveiling Segregation’s Impact: Analyzing the Relationship Between Dimensions and Police-Involved Homicide of Minorities in U.S. Counties

Supplemental material, sj-docx-2-cad-10.1177_00111287231218706 for Unveiling Segregation’s Impact: Analyzing the Relationship Between Dimensions and Police-Involved Homicide of Minorities in U.S. Counties by Yunhan Zhao, Dan He and Shay Reszka in Crime & Delinquency</p

Data_Sheet_2_A configurational analysis on career success of scientific and technological innovation talents in universities.pdf

IntroductionIncreasing the career success of scientific and technological innovation talents has become an important means of keeping and using talents in countries around the world. However, the problem has not been solved effectively.MethodsThirty-five cases were chosen in this study. The combined effects of human capital, psychological capital, micro-social capital, team social capital, and macro-social capital on the career success of scientific and technological innovation talents, as well as relevant influencing mechanisms, were discussed using qualitative comparative analysis (QCA).ResultsResults demonstrate that: (a) while a single factor cannot be the only condition for the high career success of scientific and technological innovation talents in universities, increasing macro-social capital plays a relatively universal role in a high career success rate. (b) There are three paths driving the high career success of scientific and technological innovation talents in universities. (c) There are two paths driving the non-high career success of scientific and technological innovation. Both have characteristics of absent psychological capital and micro-social capital. Moreover, the driving mechanism of high career success has an asymmetrical causal relationship.DiscussionResearch conclusions are not only conducive to expanding the research perspectives of social capital theory and career success, but also provide valuable insight into how to stimulate the career success of scientific and technological innovation talents in universities.</p

Data_Sheet_1_A configurational analysis on career success of scientific and technological innovation talents in universities.CSV

IntroductionIncreasing the career success of scientific and technological innovation talents has become an important means of keeping and using talents in countries around the world. However, the problem has not been solved effectively.MethodsThirty-five cases were chosen in this study. The combined effects of human capital, psychological capital, micro-social capital, team social capital, and macro-social capital on the career success of scientific and technological innovation talents, as well as relevant influencing mechanisms, were discussed using qualitative comparative analysis (QCA).ResultsResults demonstrate that: (a) while a single factor cannot be the only condition for the high career success of scientific and technological innovation talents in universities, increasing macro-social capital plays a relatively universal role in a high career success rate. (b) There are three paths driving the high career success of scientific and technological innovation talents in universities. (c) There are two paths driving the non-high career success of scientific and technological innovation. Both have characteristics of absent psychological capital and micro-social capital. Moreover, the driving mechanism of high career success has an asymmetrical causal relationship.DiscussionResearch conclusions are not only conducive to expanding the research perspectives of social capital theory and career success, but also provide valuable insight into how to stimulate the career success of scientific and technological innovation talents in universities.</p

Synergistic effects of celecoxib and radiation on the inhibition of colony formation.

Colony numbers were determined by counted under a microscope. Data are presented as the mean ± standard deviation (n = 3). ***P###P<0.001 vs. radiation only.</p

Methanofullerenes, C₆₀(CH₂)_<i>n</i> (<i>n</i> = 1, 2, 3), as Building Blocks for High‑Performance Acceptors Used in Organic Solar Cells

Selective preparation of C₆₀(CH₂)_<i>n</i> (<i>n</i> = 1, 2, 3) was realized via a “Bingel-decarboxylation” route. A 54π-electron derivative of C₆₀(CH₂)₂, OQBMF, demonstrates an outstanding power conversion efficiency (PCE) of 6.43% (<i>V</i>_oc = 0.95 V, <i>J</i>_sc = 9.67 mA cm^–2, FF = 70%) in fullerene:P3HT solar cells since the small CH₂ addends lift up fullerene LUMO and increase <i>V</i>_oc significantly without decreasing mobility significantly