7 research outputs found
Study areas, population densities, and distributions of out-of-hospital cardiac arrests (OHCA) cases and hospitals in Kaohsiung, 2011–2013.
<p>Purple points indicate that patients with OHCA were transported to the closest emergency hospital while green points represent bypassing it.</p
Interpolation of the interval from the call to hospital admission by using the Kriging method.
<p>Areas marked with red indicate a prolonged interval of an out-of-hospital cardiac arrest (OHCA) case from the call to hospital admission, while areas marked with green show a short interval (<30 min). Uncolored areas are locations without sufficient interpolation information (sparse OHCA event points).</p
Flow chart of the study design.
<p>Abbreviations: CPR: cardiopulmonary resuscitation; AED: automated external defibrillator; LMA: laryngeal mask airway.</p
Air Gap-Based Cavities Dramatically Enhance the True Intrinsic Spectral Signals of Suspended and Pristine Two-Dimensional Materials
The properties of two-dimensional
(2D) materials are readily affected
by their surroundings. Therefore, the underlying substrates and surrounding
materials always disturb the pristine properties of 2D materials.
Herein, we describe how the pristine properties of suspended 2D materials
can be precisely extracted from Raman and photoluminescence (PL) spectra
with great signal enhancements by taking advantage of both air gap
suspension and nanocavity enhancement effects. The modes of the Raman
emission lines were enhanced to almost the same degree when the 2D
materials were positioned over the nanocavity: the 2D/G peaks of suspended
single-layer graphene (SLG) and the E12g/A1g peaks of MoS2 were significantly enhanced almost
equally. Moreover, recording Raman and PL spectra at different positions
of the suspended 2D materials was a very powerful tool for observing
charge transfer between the pristine 2D materials and the surrounding
materials. We also found that the residual holes of the suspended
SLG could be neutralized by aluminum (Al) at certain positions. By
employing the air cavity structure, we could readily locate the charge
neutrality point of the suspended 2D materials. In addition, the PL
intensity of MoS2 could be greatly enhanced when using
the same nanocavity. The great enhancements in the PL signals from
the suspended 2D materials allowed us to further investigate the spectral
weights of both the A0 exciton and A– trion peaks when MoS2 was suspended or supported upon
various metal films. This approach may open up new doors for techniques
allowing precise characterization of abundant information from pristine
and suspended 2D materials
Using Visible Laser-Based Raman Spectroscopy to Identify the Surface Polarity of Silicon Carbide
In
this study we developed an approach to identify the surface
polarity of silicon carbide (SiC) by using an excitation laser possessing
a photon energy (2.33 eV) much lower than the band gap of 4H-SiC (3.30
eV). By gradually attenuating the intensity of the excitation laser,
the effective depth that the laser could generate Raman signals could
eventually be limited to within the ultrashallow region of the SiC
wafer. Through three-dimensional finite-difference-time-domain (3D-FDTD)
simulations, we found that the depth of the high electric field region
could be limited from several micrometers below the surface to the
near-surface region of 4H-SiC, merely by attenuating the power of
the incident laser. Experimentally, we observed a clear trend in the
Raman peak intensity ratio of the signals at 210 and 203 cm<sup>–1</sup> in the FTA mode: the intensity ratio of the Si face was always higher
than that of the C face regardless of the measurement position on
the 4H-SiC wafer. Even through the carrier concentrations in the 4H-SiC
wafer were nonuniform, the resulting variability in peak intensity
did not influence the trend in the intensity ratio, which could, therefore,
be used to identify the surface polarity. This approach might also
allow characterization of different polytypes of SiC, for example,
6H-SiC and 3C-SiC, the optical band gaps of which are lower than that
of 4H-SiC. Because this optical approach using low-photon-energy laser-based
Raman spectroscopy is nondestructive, simple, and rapid and employs
excitation light of low photon energy, it should be very applicable
for characterizing the surface properties of various other crystalline
materials
Survival percentages of out-of-hospital cardiac arrests (OHCA) by district in areas with high (> = 5,000 persons/km<sup>2</sup>) and low (< 5,000 persons/km<sup>2</sup>) population densities of Kaohsiung City, 2011–2013.
<p>Survival percentages of out-of-hospital cardiac arrests (OHCA) by district in areas with high (> = 5,000 persons/km<sup>2</sup>) and low (< 5,000 persons/km<sup>2</sup>) population densities of Kaohsiung City, 2011–2013.</p
Au/SiC Microfluidic Devices Fabricated by Rapid Laser Cladding for Photocatalytic Degradation of Water Pollutants
The increasing proliferation of third-generation semiconductor
silicon carbide (SiC) products has led to the emergence of SiC powder
as an industrial byproduct. To reutilize the SiC efficiently, we propose
a facile method for fabrication of photocatalytic plates from reclaimed
SiC. Our approach involves affixing the SiC onto a glass surface with
laser cladding, followed by sputter deposition of a gold film and
laser annealing. The resulting nanogold-coated SiC plate exhibited
enhanced photocatalytic activity due to the injection of hot electrons
into the SiC via surface plasmon resonance. Unlike chemical reduction,
which requires hours for the synthesis, purification, and isolation
of Au/SiC, our approach accomplished this in just 30 min. When illuminated,
the Au/SiC plate generated electron–hole pairs that formed
radicals in the presence of water and oxygen, leading to the decomposition
of methylene blue. Furthermore, the Au/SiC plate can be integrated
into a microfluidic device for an enhanced degradation rate and efficiency.
This research provides a simple and environmentally friendly approach
to the production of photocatalytic plates from reclaimed SiC and
contributes to sustainable development
