2 research outputs found
Additional file 1 of Coloration differences in three Camellia reticulata Lindl. cultivars: ‘Tongzimian’, ‘Shizitou’ and ‘Damanao’
Additional file 1: Supplementary Table 1. Correlation coefficients and p-value of ABP and specific function transcripts with transcription factors
Petasis-Type <i>gem</i>-Difluoroallylation Reactions Assisted by the Neighboring Hydroxyl Group in Amines
A three-component
Petasis-type <i>gem</i>-difluoroallylation
reaction of using pinacol <i>gem</i>-difluoroallylboronates,
aldehydes or isatin, and β-amino alcohols enabled by the neighboring
hydroxyl group in amine is reported, affording various racemic and
chiral <i>gem</i>-difluorohomoallylamine derivatives with
good to excellent results. Based on the control experiment and stereochemistry
of the product, a proposed reaction pathway is illustrated to clarify
the origin of regio- and stereoselectivity under protic solvent conditions
