Scale-dependent desorption of uranium from contaminated subsurface sediments

Column experiments were performed to investigate the scale-dependent desorption of uranyl [U(VI)] from a contaminated sediment collected from the Hanford 300 Area at the U.S. Department of Energy (DOE) Hanford Site, Washington. The sediment was a coarse-textured alluvial flood deposit containing significant mass percentage of river cobble. U(VI) was, however, only associated with its minor fine-grained (\u3c2 mm) mass fraction. U(VI) desorption was investigated both from the field-textured sediment using a large column (80 cm length by 15 cm inner diameter) and from its \u3c2 mm U(VI)- associated mass fraction using a small column (10 cm length by 3.4 cm inner diameter). Dynamic advection conditions with intermittent flow and stop-flow events of variable durations were employed to investigate U(VI) desorption kinetics and its scale dependence. A multicomponent kinetic model that integrated a distributed rate of mass transfer with surface complexation reactions successfully described U(VI) release from the fine-grained U(VI)-associated materials. The field-textured sediment in the large column displayed dual-domain tracer-dependent mass transfer properties that affected the breakthrough curves of bromide, pentafluorobenzoic acid (PFBA), and tritium. The tritium breakthrough curve showed stronger nonequilibrium behavior than did PFBA and bromide and required a larger immobile porosity to describe. The dual-domain mass transfer properties were then used to scale the kinetic model of U(VI) desorption developed for the fine-grained materials to describe U(VI) release and reactive transport in the field-textured sediment. Numerical simulations indicated that the kinetic model that was integrated with the dual-domain properties determined from tracer PFBA and Br best described the experimental results. The kinetic model without consideration of the dual-domain properties overpredicted effluent U(VI) concentrations, while the model based on tritium mass transfer underpredicted the rate of U(VI) release. Overall, our results indicated that the kinetics of U(VI) release from the field-textured sediment were different from that of its fine-grained U(VI)-associated mass fraction. However, the desorption kinetics measured on the U(VI)-containing mass fraction could be scaled to describe U(VI) reactive transport in the contaminated field-textured sediment after proper consideration of the physical transport properties of the sediment. The research also demonstrated a modeling approach to integrate geochemical processes into field-scale reactive transport models

Scale-dependent desorption of uranium from contaminated subsurface sediments

Column experiments were performed to investigate the scale-dependent desorption of uranyl [U(VI)] from a contaminated sediment collected from the Hanford 300 Area at the U.S. Department of Energy (DOE) Hanford Site, Washington. The sediment was a coarse-textured alluvial flood deposit containing significant mass percentage of river cobble. U(VI) was, however, only associated with its minor fine-grained (\u3c2 mm) mass fraction. U(VI) desorption was investigated both from the field-textured sediment using a large column (80 cm length by 15 cm inner diameter) and from its \u3c2 mm U(VI)- associated mass fraction using a small column (10 cm length by 3.4 cm inner diameter). Dynamic advection conditions with intermittent flow and stop-flow events of variable durations were employed to investigate U(VI) desorption kinetics and its scale dependence. A multicomponent kinetic model that integrated a distributed rate of mass transfer with surface complexation reactions successfully described U(VI) release from the fine-grained U(VI)-associated materials. The field-textured sediment in the large column displayed dual-domain tracer-dependent mass transfer properties that affected the breakthrough curves of bromide, pentafluorobenzoic acid (PFBA), and tritium. The tritium breakthrough curve showed stronger nonequilibrium behavior than did PFBA and bromide and required a larger immobile porosity to describe. The dual-domain mass transfer properties were then used to scale the kinetic model of U(VI) desorption developed for the fine-grained materials to describe U(VI) release and reactive transport in the field-textured sediment. Numerical simulations indicated that the kinetic model that was integrated with the dual-domain properties determined from tracer PFBA and Br best described the experimental results. The kinetic model without consideration of the dual-domain properties overpredicted effluent U(VI) concentrations, while the model based on tritium mass transfer underpredicted the rate of U(VI) release. Overall, our results indicated that the kinetics of U(VI) release from the field-textured sediment were different from that of its fine-grained U(VI)-associated mass fraction. However, the desorption kinetics measured on the U(VI)-containing mass fraction could be scaled to describe U(VI) reactive transport in the contaminated field-textured sediment after proper consideration of the physical transport properties of the sediment. The research also demonstrated a modeling approach to integrate geochemical processes into field-scale reactive transport models

New Insights into the Surfactant-Assisted Liquid-Phase Exfoliation of Bi2S3 for Electrocatalytic Applications

During water electrolysis, adding an electrocatalyst for the hydrogen evolution reaction (HER) is necessary to reduce the activation barrier and thus enhance the reaction rate. Metal chalcogenide-based 2D nanomaterials have been studied as an alternative to noble metal electrocatalysts because of their interesting electrocatalytic properties and low costs of production. However, the difficulty in improving the catalytic efficiency and industrializing the synthetic methods have become a problem in the potential application of these species in electrocatalysis. Liquid-phase exfoliation (LPE) is a low-cost and scalable technique for lab- and industrial-scale synthesis of 2D-material colloidal inks. In this work, we present, to the best of our knowledge, for the first time a systematic study on the surfactant-assisted LPE of bulk Bi2S3 crystalline powder to produce nanosheets (NSs). Different dispersing agents and LPE conditions have been tested in order to obtain colloidal low-dimensional Bi2S3 NSs in H2O at optimized concentrations. Eventually, colloidally stable layered nano-sized Bi2S3 suspensions can be produced with yields of up to ~12.5%. The thus obtained low-dimensional Bi2S3 is proven to be more active for HER than the bulk starting material, showing an overpotential of only 235 mV and an optimized Tafel slope of 125 mV/dec. Our results provide a facile top-down method to produce nano-sized Bi2S3 through a green approach and demonstrate that this material can have a good potential as electrocatalyst for HER

EMA-VIO: Deep Visual-Inertial Odometry with External Memory Attention

Accurate and robust localization is a fundamental need for mobile agents. Visual-inertial odometry (VIO) algorithms exploit the information from camera and inertial sensors to estimate position and translation. Recent deep learning based VIO models attract attentions as they provide pose information in a data-driven way, without the need of designing hand-crafted algorithms. Existing learning based VIO models rely on recurrent models to fuse multimodal data and process sensor signal, which are hard to train and not efficient enough. We propose a novel learning based VIO framework with external memory attention that effectively and efficiently combines visual and inertial features for states estimation. Our proposed model is able to estimate pose accurately and robustly, even in challenging scenarios, e.g., on overcast days and water-filled ground , which are difficult for traditional VIO algorithms to extract visual features. Experiments validate that it outperforms both traditional and learning based VIO baselines in different scenes.Comment: Accepted by IEEE Sensors Journa

Histogram of Fuzzy Local Spatio-Temporal Descriptors for Video Action Recognition

Feature extraction plays a vital role in visual action recognition. Many existing gradient-based feature extractors, including histogram of oriented gradients (HOG), histogram of optical flow (HOF), motion boundary histograms (MBH), and histogram of motion gradients (HMG), build histograms for representing different actions over the spatio-temporal domain in a video. However, these methods require to set the number of bins for information aggregation in advance. Varying numbers of bins usually lead to inherent uncertainty within the process of pixel voting with regard to the bins in the histogram. This paper proposes a novel method to handle such uncertainty by fuzzifying these feature extractors. The proposed approach has two advantages: i) it better represents the ambiguous boundarie between the bins and thus the fuzziness of th spatio-temporal visual information entailed in videos, and ii) the contribution of each pixel is flexibly controlled by a fuzziness parameter for various scenarios. The proposed family of fuzzy descriptors and a combination of them were evaluate on two publicly available datasets, demonstrating that the proposed approach outperforms the original counterparts and other state-of-the-art methods

Genome-Wide Profiling of Epstein-Barr Virus (EBV) Isolated from EBV-Related Malignancies

Epstein–Barr virus (EBV) is the cause of certain cancers, such as Burkitt lymphoma, Hodgkin lymphoma, NK/T cell lymphoma, nasopharyngeal carcinoma, and a subset of gastric carcinomas. The genome-wide characteristics of EBV are essential to understand the diversity of strains isolated from EBV-related malignancies, provide the first opportunity to test the general validity of the EBV genetic map and explore recombination, geographic variation, and the major features of variation in this virus. Moreover, understanding more about EBV sequence variations isolated from EBV-related malignancies might give important implications for the development of effective prophylactic and therapeutic vaccine approaches targeting the personalized or geographic-specific EBV antigens in these aggressive diseases. In this chapter, we will mainly focus on the EBV genome-wide profiling in three common EBV-related cancers in Asia, including nasopharyngeal carcinoma, EBV-associated gastric carcinoma, and NK/T-cell lymphoma

Fluorescence spectroscopy of U(VI)-silicates and U(VI)-contaminated Hanford sediment

Time-resolved U(VI) laser fluorescence spectra (TRLFS) were recorded for a series of natural uranium-silicate minerals including boltwoodite, uranophane, soddyite, kasolite, sklodowskite, cuprosklodowskite, haiweeite, and weeksite, a synthetic boltwoodite, and four U(VI)-contaminated Hanford vadose zone sediments. Lowering the sample temperature from RT to ~5.5 K significantly enhanced the fluorescence intensity and spectral resolution of both the minerals and sediments, offering improved possibilities for identifying uranyl species in environmental samples. At 5.5 K, all of the uranyl silicates showed unique, well-resolved fluorescence spectra. The symmetric O = U = O stretching frequency, as determined from the peak spacing of the vibronic bands in the emission spectra, were between 705 to 823 cm−1 for the uranyl silicates. These were lower than those reported for uranyl phosphate, carbonate, or oxy-hydroxides. The fluorescence emission spectra of all four sediment samples were similar to each other. Their spectra shifted minimally at different time delays or upon contact with basic Na/Ca-carbonate electrolyte solutions that dissolved up to 60% of the precipitated U(VI) pool. The well-resolved vibronic peaks in the fluorescence spectra of the sediments indicated that the major fluorescence species was a crystalline uranyl mineral phase, while the peak spacing of the vibronic bands pointed to the likely presence of uranyl silicate. Although an exact match was not found between the U(VI) fluorescence spectra of the sediments with that of any individual uranyl silicates, the major spectral characteristics indicated that the sediment U(VI) was a uranophane-type solid (uranophane, boltwoodite) or soddyite, as was concluded from microprobe, EXAFS, and solubility analyses

Electron beam-induced white emission from iridium complexes-doped polymer dots

The version of record of this article, first published in Photochemical and Photobiological Sciences, is available online at Publisher’s website: https://doi.org/10.1007/s43630-023-00520-3Radiation detection plays an important role in diverse applications, including medical imaging, security, and display technologies. Scintillators, materials that emit light upon exposure to radiation, have garnered significant attention due to their exceptional sensitivity. Previous research explored polymer dots (P-dots) doped with iridium complexes as nano-sized scintillators for radiation detection, but these were constrained to emitting specific colors like red, green, and blue, limiting their utility. Recently, there has been a breakthrough in the development of white light emitters stimulated by UV–visible light. These emitters exhibit a broad spectral range in the visible wavelength, enhancing contrast and simplifying detection by visible-light sensors. Consequently, the quest for white color scintillators in radiation detection has emerged as a promising avenue for enhancing scintillation efficiency. In this study, we present a novel approach by applying P-dots doped with two iridium complexes to create white light-emitting nano-sized scintillators. These scintillators offer a wider spectral coverage within the visible-light wavelength range. Under UV light (365 nm) excitation, our synthesized P-dots exhibited remarkable white light emission. Moreover, when excited by electron beam irradiation, we observed the clear emission close to white emission which is valuable for improving the detection of radiation