870 research outputs found

    Personal Agents for Implicit Culture Support

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    We present an implementation of a multi-agent system that aims at solving the problem of tacit knowledge transfer by means of experiences sharing. In particular, we consider experiences of use of pieces of information. Each agent incorporates a system for implicit culture support (SICS) whose goal is to realize the acceptance of the suggested information. The SICS permits a transparent (implicit) sharing of the information about the use, e.g., requesting and accepting pieces of information

    Visible spectroelectrochemical characterization of geobacter sulfurreducens biofilms on optically transparent indium tin oxide electrode

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    We report visible spectroelectrochemical (SEC) characterization of cytochrome c552 (cyt c552) in viable Geobacter sulfurreducens biofilms on tin-doped indium oxide (ITO) electrodes poised at 0.24 V vs.. SHE. G. sulfurreducens biofilms were grown in minimal medium with acetate as electron donor (turnover conditions), followed by 24 hours incubation in electron donor-depleted medium (non-turnover conditions). The electronic absorption spectra of G. sulfurreducens biofilms showed the lowest energy absorption band in the reduced state at 552 nm, which indicated excess of cyt c552 in the biofilm. The spectra under non-turnover conditions displayed gradual reduction of the cyt c552, following the step-wise decrease of electrode potential from 0.0 V to -0.6 V vs.. standard calomel electrode (SCE). The spectral changes were fully reversible in both positive and negative direction of the scan potential, with average midpoint potential value of -0.42 V vs.. SCE. Confocal microscopy analysis revealed that the thickness of biofilms under turnover conditions and non-turnover conditions was approximately 35 and 3.5 ”m, respectively. This is the first study to observe the reversible redox conversion of cyt c552 in viable G. sulfurreducens biofilms

    analysis and reliability study of luminescent materials for white lighting

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    In this work, we report on the characterization and reliability/stability study of phosphorescent materials for lighting applications. More specifically, we investigated (a) phosphors directly deposited over light-emitting diodes (LED) chip, (b) remote phosphor (RP) solutions encapsulated in plastic medium for LED lighting, and (c) phosphors without binder for extreme high-intensity laser diode white lighting. The optical and thermal properties of phosphors were studied to develop a sample based on a mix of phosphor compounds in order to achieve different correlated color temperatures (CCT) and high color rendering index (CRI) LEDs. Thermal properties of cerium-doped YAG (Yttrium Aluminum Garnet) phosphor materials were evaluated in order to study thermal quenching. A maximum phosphor operating temperature of 190–200 °C was found to cause a sensible efficiency degeneration. Reduced efficiency and Stokes shift also caused a localized temperature increase in the photoluminescent materials. In the case of remote phosphors, heat did not find a low thermal resistance path to the heatsink (as occurred through the GaN LED chip for direct phosphor-converted devices) and thermal analysis indicated that material temperature might therefore increase to values in excess of 60 °C when a radiation of 435 mW/cm2 hit the sample template. Reliability was also investigated for both plastic-encapsulated materials and binder-free depositions. Pure thermal reliability study indicated that phosphors encapsulated in polycarbonate material were stable up to temperature of approximately 100 °C, while binder-free phosphor did not show any sensible degradation up to temperatures of 525 °C

    Trapping phenomena and degradation mechanisms in GaN-based power HEMTs

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    Abstract This paper reports an overview of the most relevant trapping and degradation mechanisms that limit the performance and lifetime of GaN-based transistors for application in power electronics. Results obtained on state-of-the-art devices are described and discussed throughout the paper, with the aim of providing a clear description of the topic. The first part of the paper deals with the issue of dynamic-Ron: after describing a robust test strategy for the analysis of the pulsed characteristics of the devices, we discuss the voltage- and temperature-dependent pulsed I-V characteristics of 650 V-rated transistors, and the physical origin of dynamic Ron in these devices. The results demonstrate that through proper buffer optimization it is possible to reach negligible trapping at high voltage. The properties of the traps responsible for dynamic-Ron are also discussed in detail in the paper, based on drain-current transient data. A specific discussion is devoted to hot-electron trapping processes, that – under hard switching conditions – may lead to significant modifications in the resistance of the 2DEG. The second part of the paper deals with device degradation: based on a wide set of experimental results, we describe the physical mechanisms responsible for the worsening of the properties of the devices. More specifically, we demonstrate that stress in off-state conditions may result in measurable changes in the pinch-off voltage, mostly consisting in a negative-threshold instability (NBTI). The origin of this shift is discussed in detail; we also demonstrate that in a real-life cascode configuration (where a low, subthreshold leakage current flows through the device in the off-state), NBTI effects are mitigated. Finally, we discuss the stability of the gate-stack, induced by the exposure to positive gate bias

    Electric Field and Self-Heating Effects on the Emission Time of Iron Traps in GaN HEMTs

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    In this paper we separately investigate the role of electric field and device self-heating (SHE) in enhancing the charge emission process from Fe-related buffer traps (0.52 eV from Ec) in AlGaN/GaN High Electron Mobility Transistors (HEMTs). The experimental analysis was performed by means of Drain Current Transient (DCT) measurements for either i) different dissipated power (PD,steady) at constant drain-to-source bias (VDS,steady) or ii) constant PD,steady at different VDS,steady. We found that i) an increase in PD,steady yields an acceleration in the thermally activated emission process, consistently with the temperature rise induced by SHE. On the other hand, ii) the field effect turned out to be negligible within the investigated voltage range, indicating the absence of Poole-Frenkel effect (PFE). A qualitative analysis based on the electric field values obtained by numerical simulations is then presented to support the interpretation and conclusions

    Study and development of a fluorescence based sensor system for monitoring oxygen in wine production: The WOW project

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    The importance of oxygen in the winemaking process is widely known, as it affects the chemical aspects and therefore the organoleptic characteristics of the final product. Hence, it is evident the usefulness of a continuous and real-time measurements of the levels of oxygen in the various stages of the winemaking process, both for monitoring and for control. The WOW project (Deployment of WSAN technology for monitoring Oxygen in Wine products) has focused on the design and the development of an innovative device for monitoring the oxygen levels in wine. This system is based on the use of an optical fiber to measure the luminescent lifetime variation of a reference metal/porphyrin complex, which decays in presence of oxygen. The developed technology results in a high sensitivity and low cost sensor head that can be employed for measuring the dissolved oxygen levels at several points inside a wine fermentation or aging tank. This system can be complemented with dynamic modeling techniques to provide predictive behavior of the nutrient evolution in space and time given few sampled measuring points, for both process monitoring and control purposes. The experimental validation of the technology has been first performed in a controlled laboratory setup to attain calibration and study sensitivity with respect to different photo-luminescent compounds and alcoholic or non-alcoholic solutions, and then in an actual case study during a measurement campaign at a renown Italian winery

    Use of Bilayer gate insulator in GaN-on-Si Vertical Trench MOSFETs : impact on performance and reliability

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    We propose to use a bilayer insulator (2.5 nm Al2O3 + 35 nm SiO2) as an alternative to a conventional uni-layer Al2O3 (35 nm), for improving the performance and the reliability of GaN-on-Si semi vertical trench MOSFETs. This analysis has been performed on a test vehicle structure for module development, which has a limited OFF-state performance. We demonstrate that devices with the bilayer dielectric present superior reliability characteristics than those with the uni-layer, including: (i) gate leakage two-orders of magnitude lower; (ii) 11 V higher off-state drain breakdown voltage; and (iii) 18 V higher gate-source breakdown voltage. From Weibull slope extractions, the uni-layer shows an extrinsic failure, while the bilayer presents a wear-out mechanism. Extended reliability tests investigate the degradation process, and hot-spots are identified through electroluminescence microscopy. TCAD simulations, in good agreement with measurements, reflect electric field distribution near breakdown for gate and drain stresses, demonstrating a higher electric field during positive gate stress. Furthermore, DC capability of the bilayer and unilayer insulators are found to be comparable for same bias points. Finally, comparison of trapping processes through double pulsed and V-th transient methods confirms that the V-th shifts are similar, despite the additional interface present in the bilayer devices
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