Iridium-Catalyzed Direct Arene C–H Bond Amidation with Sulfonyl- and Aryl Azides

Iridium-catalyzed direct ortho C–H amidation of arenes has been shown to work well with sulfonyl- and aryl azides as the nitrogen source. The reaction proceeds efficiently with a broad range of substrates bearing conventional directing groups with excellent functional group compatibility under mild conditions. In addition, substrates forming not only 5- but also 6-membered iridacycle intermediates undergo the C–H amidation with high selectivity

Method of splitting green time according to actions.

Method of splitting green time according to actions.</p

Borane-Catalyzed Selective Hydrosilylation of Internal Ynamides Leading to β‑Silyl (<i>Z</i>)‑Enamides

We have developed a borane-catalyzed regio- and stereoselective hydrosilylation of internal ynamides for the first time. The scope of ynamide substrates and silane reactants was broad under mild reaction conditions, affording synthetically versatile β-silyl (<i>Z</i>)-enamide products. The observed stereoselectivity was reasoned to be due to the β-silicon effect on a postulated ketene iminium intermediate

Borane-Catalyzed Selective Hydrosilylation of Internal Ynamides Leading to β‑Silyl (<i>Z</i>)‑Enamides

We have developed a borane-catalyzed regio- and stereoselective hydrosilylation of internal ynamides for the first time. The scope of ynamide substrates and silane reactants was broad under mild reaction conditions, affording synthetically versatile β-silyl (<i>Z</i>)-enamide products. The observed stereoselectivity was reasoned to be due to the β-silicon effect on a postulated ketene iminium intermediate

Section division based on lane structure.

Section division based on lane structure.</p

The fixed time plans of the simulated intersections.

The fixed time plans of the simulated intersections.</p

Borane-Catalyzed Selective Hydrosilylation of Internal Ynamides Leading to β‑Silyl (<i>Z</i>)‑Enamides

We have developed a borane-catalyzed regio- and stereoselective hydrosilylation of internal ynamides for the first time. The scope of ynamide substrates and silane reactants was broad under mild reaction conditions, affording synthetically versatile β-silyl (<i>Z</i>)-enamide products. The observed stereoselectivity was reasoned to be due to the β-silicon effect on a postulated ketene iminium intermediate

Calculation of the space occupancy based on the collected traffic and signal times.

Calculation of the space occupancy based on the collected traffic and signal times.</p

Intersection delay of each traffic pattern for prototype pre-training.

Intersection delay of each traffic pattern for prototype pre-training.</p

Comparing the stacked queue length of 8 traffic movements for reward definitions.

(a) DDGP-reward1 (Daechi Station). (b) DDGP-reward2 (Daechi Station). (c) DDGP-reward3 (Daechi Station). (d) DDGP-reward1 (Dogok Station). (e) DDGP-reward1 (Dogok Station). (f) DDGP-reward1 (Dogok Station).</p