10 research outputs found

    Shape Control of Ag Shell Growth on Au Nanodisks

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    Core–shell (Au@Ag) bimetallic nanoparticles containing a Au nanodisk in the core were synthesized using Au nanodisks as seeds. The growth direction of the Ag shell on the gold nanodisks could be tuned by the presence of iodide ions. Without the I– ions, the Ag shell was formed homogeneously over the entire surface of the flat Au nanodisks, while the presence of I– induced the selective coating of the Ag shell in the direction perpendicular to the basal plane of the nanodisks. The resulting core–shell (Au@Ag) bimetallic nanoparticles could be further converted to hollow nanostructures containing a central Au nanodisk via galvanic replacement reactions

    Optical Sensitivity Comparison of Multiblock Gold–Silver Nanorods Toward Biomolecule Detection: Quadrupole Surface Plasmonic Detection of Dopamine

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    In this work, we tested multiblock nanorods (NRs) with Au and Ag segments for the surface plasmonic detection of dopamine (DA). A change in the quadrupole surface plasmon mode was found to be sensitive to the Au/Ag block length and relative block ratio in a single NR. The surfaces of the NRs were decorated with monoclonal antibody (Mab) against DA. By comparing the results for pure Au NRs with those obtained for multiblock Au–Ag–Au NRs, we found that the magnitude of peak-shifting for the multiblock NRs was much larger than that for pure Au NRs. This result was attributed to the higher sensitivity of Ag to a change in the dielectric constant of the surrounding medium when compared to Au and the sensitive surface plasmon coupling at the junction between Au and Ag blocks. The magnitude of peak-shifting was tuned as a function of both the length of the Ag block and the number of repeating units of Au and Ag in the NRs

    Galvanically Replaced Hollow Au–Ag Nanospheres: Study of Their Surface Plasmon Resonance

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    We synthesized hollow Au–Ag nanospheres (NSs) by employing a galvanic replacement reaction between HAuCl<sub>4</sub> and Ag NSs. Uniform Ag NSs with controllable sizes were synthesized as sacrificial templates by a seed-mediated strategy. The atomic ratio of Au to Ag in Au–Ag NSs was tunable by controlling the reagent concentration. UV–vis extinction spectra acquired from well-dispersed colloidal NS solutions were used to investigate the optical properties of the solutions. In addition to a common dipole mode exhibited on most transition metal nanoparticles, we observed a quadrupole plasmon resonance mode when the diameters of the Ag and Au–Ag NSs were larger than 100 nm. The quadrupole and dipole peaks both shifted to longer wavelengths with increased Au content in Au–Ag NSs. The experimental observation of optical properties of hollow Au–Ag NSs was compared with the theoretical simulation using DDA calculation, showing a good agreement

    Supplementary Data from Polymer Thin Film–Induced Tumor Spheroids Acquire Cancer Stem Cell–like Properties

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    This Supplementary Material contains chemical structures and characterization data of various polymer thin films, flow cytometric analysis and gene expression of ssiCSCs, functional analyses of ssiCSCs, and tables summarizing tumor formation frequency in vivo.</p
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