10 research outputs found
sj-pdf-1-jnm-10.1177_10949968221150933 - Supplemental material for The Effects of Linguistic Coordination on Perceived Quality of Consumer Reviews: A Dual Process Perspective
Supplemental material, sj-pdf-1-jnm-10.1177_10949968221150933 for The Effects of Linguistic Coordination on Perceived Quality of Consumer Reviews: A Dual Process Perspective by Angela Xia Liu, Yinglei Wang, and Jurui Zhang in Journal of Interactive Marketing</p
Solubilities of 2,4-Dinitroanisole in Pure Organic and Mixed Organic Solvents at Temperatures between 283.15 and 313.15 K
The
solubility of 2,4-dinitroanisole (DNAN) was measured in nine
commonly used pure organic solvents, including ethanol, acetone, ethyl
acetate, n-propanol, i-propanol,
butyl alcohol, cyclohexanone, toluene, and cyclohexane, and four binary
mixed solvents between 283.15 K and 313.15 K at atmosphere pressure
by the gravimetric method. The solubility of DNAN showed a temperature
dependence in all test solvents. The order of the solubility of DNAN
was acetone ≈ cyclohexanone > ethyl acetate > n-propanol + acetone ≈ ethanol + acetone ≈
toluene >
ethanol > n-propanol > water + acetone > n-butanol + acetone > n-butanol ≈ i-propanol > cyclohexane. The experimental mole fraction
solubility data were correlated with the modified Apelblat equation,
Yaws equation, and van’t Hoff equation. The correlation showed
good agreement with the experimental results, and the largest value
of the root-mean-square deviation was 11.88 × 10–4. All of the obtained results would benefit the purification and
crystallization of DNAN, which would extend its applications in the
field of explosives
Data_Sheet_1_Novel Energetic Coordination Polymers Based on 1,5-Di(nitramino)tetrazole With High Oxygen Content and Outstanding Properties: Syntheses, Crystal Structures, and Detonation Properties.ZIP
In this study, a series of novel 1,5-di(nitramino)tetrazole (DNAT)-based bimetallic energetic coordination polymers, MK2(DNAT)2·4H2O [M = Fe, Cu, Ni, Co, and Zn], were designed and synthesized in a simple and convenient self-assembly synthetic process. The obtained compounds were fully characterized by IR spectroscopy, multinuclear NMR spectroscopy, elemental analysis, and differential scanning calorimetry (DSC). Additionally, the structures of target compounds were confirmed by single-crystal X-ray diffraction. Based on the room-temperature X-ray densities (2.095–2.138 g cm−3) and the calculated (CBS–QB3) heats of formation (−41.3 to 170.5 kJ mol−1), the detonation properties such as detonation velocities (8,147.0–8,478.4 m s−1) and detonation pressures (29.7–32.8 GPa) were computed using the EXPLO5 v6.04 program. Their excellent energetic properties indicated that they could serve as promising “green” primary explosives for replacement of lead azide (LA).</p
Presentation_1_Novel Energetic Coordination Polymers Based on 1,5-Di(nitramino)tetrazole With High Oxygen Content and Outstanding Properties: Syntheses, Crystal Structures, and Detonation Properties.pdf
In this study, a series of novel 1,5-di(nitramino)tetrazole (DNAT)-based bimetallic energetic coordination polymers, MK2(DNAT)2·4H2O [M = Fe, Cu, Ni, Co, and Zn], were designed and synthesized in a simple and convenient self-assembly synthetic process. The obtained compounds were fully characterized by IR spectroscopy, multinuclear NMR spectroscopy, elemental analysis, and differential scanning calorimetry (DSC). Additionally, the structures of target compounds were confirmed by single-crystal X-ray diffraction. Based on the room-temperature X-ray densities (2.095–2.138 g cm−3) and the calculated (CBS–QB3) heats of formation (−41.3 to 170.5 kJ mol−1), the detonation properties such as detonation velocities (8,147.0–8,478.4 m s−1) and detonation pressures (29.7–32.8 GPa) were computed using the EXPLO5 v6.04 program. Their excellent energetic properties indicated that they could serve as promising “green” primary explosives for replacement of lead azide (LA).</p
Modulation of ADN Crystal Surface Properties by Additives
In this paper, a method to reduce the hygroscopicity
of the energetic
oxidizer ammonium dinitramide (ADN) was proposed by modulating the
surface properties of ADN crystals with additive microdoping. Cyclotetramethylene
tetranitramine (octogen, HMX) was selected as the additive, and a
three-layer solventization model was constructed based on the adhesion
energy theory by placing the additive in the solvent layer. The modified
adhesion energies and moisture absorption rates of each ADN crystal
surface were calculated under the effects of different solvents and
additives. The effects of additives on the crystal growth and crystal
morphology of ADN in the presence of different solvents were investigated.
The interactions between different solvents and crystalline surfaces
were analyzed, and the modification of the attachment energy was calculated.
The results showed that utilizing HMX as an additive significantly
influenced the ADN crystal morphology, crystal face occupancy, and
growth rate in different solvent environments. HMX showed the best
antihygroscopicity performance as an ADN additive in a dichloromethane
(DCM) solvent environment, and the percentage of antihygroscopic crystal
faces on the ADN crystal surfaces increased up to 74.70%
DataSheet1_Hybrid Graphenene Oxide/Cellulose Nanofillers to Enhance Mechanical and Barrier Properties of Chitosan-Based Composites.docx
Chitosan-based hybrid nanocomposites, containing cellulose nanocrystals (CNCs), graphene oxide (GO), and borate as crosslinking agents, were successfully prepared by solution-casting technique. The synergistic effect of the two fillers, and the role of the cross-linker, in enhancing the structural and functional properties of the chitosan polymer, was investigated. XPS results confirm the chemical interaction between borate ions and hydroxyl groups of chitosan, GO, and CNCs. The morphological characterization shows that the GO sheets are oriented along the casting surface, whereas the CNC particles are homogenously distributed in the sample. Results of tensile tests reveal that the presence of graphene oxide enhances the elastic modulus, tensile strength, elongation at break, and toughness of chitosan, while cellulose and borate induce an increase in the elastic modulus and stress at the yield point. In particular, the borate-crosslinked chitosan-based sample containing 0.5 wt% of GO and 0.5 wt% of CNCs shows an elongation at a break value of 30.2% and a toughness value of 988 J*m−3 which are improved by 124% and 216%, respectively, compared with the pristine chitosan. Moreover, the water permeability results show that the presence of graphene oxide slightly increases the water barrier properties, whereas the borate and cellulose nanocrystals significantly reduce the water vapor permeability of the polymer by about 50%. Thus, by modulating the content of the two reinforcing fillers, it is possible to obtain chitosan-based nanocomposites with enhanced mechanical and water barrier properties which can be potentially used in various applications such as food and electronic packaging.</p
Additional file 1 of Hollow polydopamine nanoparticles loading with peptide RL-QN15: a new pro-regenerative therapeutic agent for skin wounds
Additional file 1: Table S1. Surface areas, pore diameter and pore volume of HPDA nanoparticles. Figure S1. Biodistribution and clearance of HPDA and HPDAlR
Relieving Stress Concentration through Anion–Cation Codoping toward Highly Stable Nickel-Rich Cathode
Nickel-rich LiNi0.8Co0.15Al0.015O2 (NCA) with excellent energy density is considered
one
of the most promising cathodes for lithium-ion batteries. Nevertheless,
the stress concentration caused by Li+/Ni2+ mixing
and oxygen vacancies leads to the structural collapse and obvious
capacity degradation of NCA. Herein, a facile codoping of anion (F–)-cation (Mg2+) strategy is proposed to
address these problems. Benefiting from the synergistic effect of
F– and Mg2+, the codoped material exhibits
alleviated Li+/Ni2+ mixing and demonstrates
enhanced electrochemical performance at high voltage (≥4.5
V), outperformed the pristine and F–/Mg2+ single-doped counterparts. Combined experimental and theoretical
studies reveal that Mg2+ and F– codoping
decreases the Li+ diffusion energy barrier and enhances
the Li+ transport kinetics. In particular, the codoping
synergistically suppresses the Li+/Ni2+ mixing
and lattice oxygen escape, and alleviates the stress–strain
accumulation, thereby inhibiting crack propagation and improving the
electrochemical performance of the NCA. As a consequence, the designed
Li0.99Mg0.01Ni0.8Co0.15Al0.05O0.98F0.02 (Mg1+F2) demonstrates
a much higher capacity retention of 82.65% than NCA (55.69%) even
after 200 cycles at 2.8–4.5 V under 1 C. Furthermore, the capacity
retention rate of the Mg1+F2||graphite pouch cell after 500 cycles
is 89.6% compared to that of the NCA (only 79.4%)
Additional file 1 of Mesoporous polydopamine nanoparticles carrying peptide RL-QN15 show potential for skin wound therapy
Additional file 1: Figure S1. Infrared spectra between 1800cm-1-400cm-1. Table S1. Surface area, pore volume and pore diameter of MPDA nanoparticles
Zn<sup>2+</sup> Cross-Linked Alginate Carrying Hollow Silica Nanoparticles Loaded with RL-QN15 Peptides Provides Promising Treatment for Chronic Skin Wounds
Chronic and non-healing wounds pose
a great challenge to clinical
management and patients. Many studies have explored novel interventions
against skin wounds, with bioactive peptides, nanoparticles, and hydrogels
arousing considerable attention regarding their therapeutic potential.
In this study, the prohealing peptide RL-QN15 was loaded into hollow
silica nanoparticles (HSNs), with these HSN@RL-QN15 nanocomposites
then combined with zinc alginate (ZA) gels to obtain HSN@RL-QN15/ZA
hydrogel. The characteristics, biological properties, and safety profiles
of the hydrogel composites were then evaluated. Results showed that
the hydrogel had good porosity, hemocompatibility, biocompatibility,
and broad-spectrum antimicrobial activity, with the slow release of
loaded RL-QN15. Further analysis indicated that the hydrogel promoted
skin cell proliferation and keratinocyte scratch repair, regulated
angiogenesis, reduced inflammation, and accelerated re-epithelialization
and granulation tissue formation, resulting in the rapid healing of
both full-thickness skin wounds and methicillin-resistant Staphylococcus aureus biofilm-infected chronic wounds
in mice. This peptide-based hydrogel provides a novel intervention
for the treatment of chronic skin wounds and shows promise as a wound
dressing in the field of tissue regeneration
