10 research outputs found

    sj-pdf-1-jnm-10.1177_10949968221150933 - Supplemental material for The Effects of Linguistic Coordination on Perceived Quality of Consumer Reviews: A Dual Process Perspective

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    Supplemental material, sj-pdf-1-jnm-10.1177_10949968221150933 for The Effects of Linguistic Coordination on Perceived Quality of Consumer Reviews: A Dual Process Perspective by Angela Xia Liu, Yinglei Wang, and Jurui Zhang in Journal of Interactive Marketing</p

    Solubilities of 2,4-Dinitroanisole in Pure Organic and Mixed Organic Solvents at Temperatures between 283.15 and 313.15 K

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    The solubility of 2,4-dinitroanisole (DNAN) was measured in nine commonly used pure organic solvents, including ethanol, acetone, ethyl acetate, n-propanol, i-propanol, butyl alcohol, cyclohexanone, toluene, and cyclohexane, and four binary mixed solvents between 283.15 K and 313.15 K at atmosphere pressure by the gravimetric method. The solubility of DNAN showed a temperature dependence in all test solvents. The order of the solubility of DNAN was acetone ≈ cyclohexanone > ethyl acetate > n-propanol + acetone ≈ ethanol + acetone ≈ toluene > ethanol > n-propanol > water + acetone > n-butanol + acetone > n-butanol ≈ i-propanol > cyclohexane. The experimental mole fraction solubility data were correlated with the modified Apelblat equation, Yaws equation, and van’t Hoff equation. The correlation showed good agreement with the experimental results, and the largest value of the root-mean-square deviation was 11.88 × 10–4. All of the obtained results would benefit the purification and crystallization of DNAN, which would extend its applications in the field of explosives

    Data_Sheet_1_Novel Energetic Coordination Polymers Based on 1,5-Di(nitramino)tetrazole With High Oxygen Content and Outstanding Properties: Syntheses, Crystal Structures, and Detonation Properties.ZIP

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    In this study, a series of novel 1,5-di(nitramino)tetrazole (DNAT)-based bimetallic energetic coordination polymers, MK2(DNAT)2·4H2O [M = Fe, Cu, Ni, Co, and Zn], were designed and synthesized in a simple and convenient self-assembly synthetic process. The obtained compounds were fully characterized by IR spectroscopy, multinuclear NMR spectroscopy, elemental analysis, and differential scanning calorimetry (DSC). Additionally, the structures of target compounds were confirmed by single-crystal X-ray diffraction. Based on the room-temperature X-ray densities (2.095–2.138 g cm−3) and the calculated (CBS–QB3) heats of formation (−41.3 to 170.5 kJ mol−1), the detonation properties such as detonation velocities (8,147.0–8,478.4 m s−1) and detonation pressures (29.7–32.8 GPa) were computed using the EXPLO5 v6.04 program. Their excellent energetic properties indicated that they could serve as promising “green” primary explosives for replacement of lead azide (LA).</p

    Presentation_1_Novel Energetic Coordination Polymers Based on 1,5-Di(nitramino)tetrazole With High Oxygen Content and Outstanding Properties: Syntheses, Crystal Structures, and Detonation Properties.pdf

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    In this study, a series of novel 1,5-di(nitramino)tetrazole (DNAT)-based bimetallic energetic coordination polymers, MK2(DNAT)2·4H2O [M = Fe, Cu, Ni, Co, and Zn], were designed and synthesized in a simple and convenient self-assembly synthetic process. The obtained compounds were fully characterized by IR spectroscopy, multinuclear NMR spectroscopy, elemental analysis, and differential scanning calorimetry (DSC). Additionally, the structures of target compounds were confirmed by single-crystal X-ray diffraction. Based on the room-temperature X-ray densities (2.095–2.138 g cm−3) and the calculated (CBS–QB3) heats of formation (−41.3 to 170.5 kJ mol−1), the detonation properties such as detonation velocities (8,147.0–8,478.4 m s−1) and detonation pressures (29.7–32.8 GPa) were computed using the EXPLO5 v6.04 program. Their excellent energetic properties indicated that they could serve as promising “green” primary explosives for replacement of lead azide (LA).</p

    Modulation of ADN Crystal Surface Properties by Additives

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    In this paper, a method to reduce the hygroscopicity of the energetic oxidizer ammonium dinitramide (ADN) was proposed by modulating the surface properties of ADN crystals with additive microdoping. Cyclotetramethylene tetranitramine (octogen, HMX) was selected as the additive, and a three-layer solventization model was constructed based on the adhesion energy theory by placing the additive in the solvent layer. The modified adhesion energies and moisture absorption rates of each ADN crystal surface were calculated under the effects of different solvents and additives. The effects of additives on the crystal growth and crystal morphology of ADN in the presence of different solvents were investigated. The interactions between different solvents and crystalline surfaces were analyzed, and the modification of the attachment energy was calculated. The results showed that utilizing HMX as an additive significantly influenced the ADN crystal morphology, crystal face occupancy, and growth rate in different solvent environments. HMX showed the best antihygroscopicity performance as an ADN additive in a dichloromethane (DCM) solvent environment, and the percentage of antihygroscopic crystal faces on the ADN crystal surfaces increased up to 74.70%

    DataSheet1_Hybrid Graphenene Oxide/Cellulose Nanofillers to Enhance Mechanical and Barrier Properties of Chitosan-Based Composites.docx

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    Chitosan-based hybrid nanocomposites, containing cellulose nanocrystals (CNCs), graphene oxide (GO), and borate as crosslinking agents, were successfully prepared by solution-casting technique. The synergistic effect of the two fillers, and the role of the cross-linker, in enhancing the structural and functional properties of the chitosan polymer, was investigated. XPS results confirm the chemical interaction between borate ions and hydroxyl groups of chitosan, GO, and CNCs. The morphological characterization shows that the GO sheets are oriented along the casting surface, whereas the CNC particles are homogenously distributed in the sample. Results of tensile tests reveal that the presence of graphene oxide enhances the elastic modulus, tensile strength, elongation at break, and toughness of chitosan, while cellulose and borate induce an increase in the elastic modulus and stress at the yield point. In particular, the borate-crosslinked chitosan-based sample containing 0.5 wt% of GO and 0.5 wt% of CNCs shows an elongation at a break value of 30.2% and a toughness value of 988 J*m−3 which are improved by 124% and 216%, respectively, compared with the pristine chitosan. Moreover, the water permeability results show that the presence of graphene oxide slightly increases the water barrier properties, whereas the borate and cellulose nanocrystals significantly reduce the water vapor permeability of the polymer by about 50%. Thus, by modulating the content of the two reinforcing fillers, it is possible to obtain chitosan-based nanocomposites with enhanced mechanical and water barrier properties which can be potentially used in various applications such as food and electronic packaging.</p

    Relieving Stress Concentration through Anion–Cation Codoping toward Highly Stable Nickel-Rich Cathode

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    Nickel-rich LiNi0.8Co0.15Al0.015O2 (NCA) with excellent energy density is considered one of the most promising cathodes for lithium-ion batteries. Nevertheless, the stress concentration caused by Li+/Ni2+ mixing and oxygen vacancies leads to the structural collapse and obvious capacity degradation of NCA. Herein, a facile codoping of anion (F–)-cation (Mg2+) strategy is proposed to address these problems. Benefiting from the synergistic effect of F– and Mg2+, the codoped material exhibits alleviated Li+/Ni2+ mixing and demonstrates enhanced electrochemical performance at high voltage (≥4.5 V), outperformed the pristine and F–/Mg2+ single-doped counterparts. Combined experimental and theoretical studies reveal that Mg2+ and F– codoping decreases the Li+ diffusion energy barrier and enhances the Li+ transport kinetics. In particular, the codoping synergistically suppresses the Li+/Ni2+ mixing and lattice oxygen escape, and alleviates the stress–strain accumulation, thereby inhibiting crack propagation and improving the electrochemical performance of the NCA. As a consequence, the designed Li0.99Mg0.01Ni0.8Co0.15Al0.05O0.98F0.02 (Mg1+F2) demonstrates a much higher capacity retention of 82.65% than NCA (55.69%) even after 200 cycles at 2.8–4.5 V under 1 C. Furthermore, the capacity retention rate of the Mg1+F2||graphite pouch cell after 500 cycles is 89.6% compared to that of the NCA (only 79.4%)

    Zn<sup>2+</sup> Cross-Linked Alginate Carrying Hollow Silica Nanoparticles Loaded with RL-QN15 Peptides Provides Promising Treatment for Chronic Skin Wounds

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    Chronic and non-healing wounds pose a great challenge to clinical management and patients. Many studies have explored novel interventions against skin wounds, with bioactive peptides, nanoparticles, and hydrogels arousing considerable attention regarding their therapeutic potential. In this study, the prohealing peptide RL-QN15 was loaded into hollow silica nanoparticles (HSNs), with these HSN@RL-QN15 nanocomposites then combined with zinc alginate (ZA) gels to obtain HSN@RL-QN15/ZA hydrogel. The characteristics, biological properties, and safety profiles of the hydrogel composites were then evaluated. Results showed that the hydrogel had good porosity, hemocompatibility, biocompatibility, and broad-spectrum antimicrobial activity, with the slow release of loaded RL-QN15. Further analysis indicated that the hydrogel promoted skin cell proliferation and keratinocyte scratch repair, regulated angiogenesis, reduced inflammation, and accelerated re-epithelialization and granulation tissue formation, resulting in the rapid healing of both full-thickness skin wounds and methicillin-resistant Staphylococcus aureus biofilm-infected chronic wounds in mice. This peptide-based hydrogel provides a novel intervention for the treatment of chronic skin wounds and shows promise as a wound dressing in the field of tissue regeneration
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