2 research outputs found
Synthesis of Benzidine Derivatives via FeCl<sub>3</sub>·6H<sub>2</sub>O‑Promoted Oxidative Coupling of Anilines
No full textUnder
open-flask conditions in the presence of commercially available
FeCl<sub>3</sub>·6H<sub>2</sub>O, N,N-disubstituted anilines
can be converted into diversely functionalized benzidines with yields
of up to 99%. Oxidative coupling was extended to N-monosubstituted
anilines, and the method was applied to the efficient preparation
of 6,6′-biquinoline. Mechanistic investigations have also been
performed to explain the observed reactivities
Synthesis of Benzidine Derivatives via FeCl<sub>3</sub>·6H<sub>2</sub>O‑Promoted Oxidative Coupling of Anilines
No full textUnder
open-flask conditions in the presence of commercially available
FeCl<sub>3</sub>·6H<sub>2</sub>O, N,N-disubstituted anilines
can be converted into diversely functionalized benzidines with yields
of up to 99%. Oxidative coupling was extended to N-monosubstituted
anilines, and the method was applied to the efficient preparation
of 6,6′-biquinoline. Mechanistic investigations have also been
performed to explain the observed reactivities
