Determination of Phosphite in a Eutrophic Freshwater Lake by Suppressed Conductivity Ion Chromatography

The establishment of a sensitive and specific method for the detection of reduced phosphorus (P) is crucial for understanding P cycle. This paper presents the quantitative evidence of phosphite (P, +3) from the freshwater matrix correspondent to the typically eutrophic Lake Taihu in China. By ion chromatography coupled with gradient elution procedure, efficient separation of micromolar levels of phosphite is possible in the presence of millimolar levels of interfering ions, such as chloride, sulfate, and hydrogen carbonate in freshwater lakes. Optimal suppressed ion chromatography conditions include the use of 500 μL injection volumes and an AS11 HC analytical column heated to 30 °C. The method detection limit of 0.002 μM for phosphite was successfully applied for phosphite determination in natural water samples with recoveries ranging from 90.7 ± 3.2% to 108 ± 1.5%. Phosphite in the freshwater matrix was also verified using a two-dimensional capillary ion chromatography and ion chromatography coupled with mass spectrometry. Results confirmed the presence of phosphite in Lake Taihu ranging from 0.01 ± 0.01 to 0.17 ± 0.01 μM, which correlated to 1–10% of the phosphate. Phosphite is an important component of P and may influence biogeochemical P cycle in lakes

Phosphite in Sedimentary Interstitial Water of Lake Taihu, a Large Eutrophic Shallow Lake in China

The seasonal occurrence and distribution of phosphite (HPO₃^2‑, P) in sedimentary interstitial water from Lake Taihu was monitored from 2011 to 2012 to better understand its possible link to P cycle in the eutrophic shallow lake. Phosphite concentrations ranged from < MDL to 14.32 ± 0.19 μg P/kg with a mean concentration of 1.58 ± 0.33 μg P/kg, which accounts for 5.51% total soluble P (TSP_s) in surficial sediments (0–20 cm). Spatially, the concentrations of sedimentary phosphite in the lake’s northern areas were relatively higher than those in the southern areas. Higher phosphite concentrations were always observed in seriously polluted sites. Generally, phosphite in the deeper layers (20–40 cm and 40–60 cm) showed minor fluctuations compared to that in the surficial sediments, which may be associated with the frequent exchange at the sediment–water interface. Phosphite concentrations in surficial or core sediments decreased as spring > autumn > summer > winter. Higher phosphite levels occurred in the areas with lower redox (Eh), higher P contents, and particularly when metal bonded with P to form Al–P_s and Ca–P_s. Phosphite may be an important media in the P biogeochemical cycle in Lake Taihu and contribute to its internal P transportation

Multifunctional β‑Cyclodextrin Polymer for Simultaneous Removal of Natural Organic Matter and Organic Micropollutants and Detrimental Microorganisms from Water

Natural organic matter (NOM), organic micropollutants (OMPs), and detrimental microorganisms are three major pollutants that affect water quality. To remove these pollutants, a quaternary ammonium-functionalized β-cyclodextrin polymer (β-CDP) is successfully synthesized in the aqueous phase. The N2 and CO2 adsorption/desorption analysis showed that the polymer mainly contains ultra-micropores (2 g–1. Two kinds of NOM, humic acid and fulvic acid, and five OMPs, 2-naphthol (2-NO), 3-phenylphenol (3-PH), 2,4,6-trichlorophenol (2,4,6-TCP), bisphenol A (BPA), and bisphenol S (BPS), were selected as model pollutants to study the performance of β-CDP and three kinds of commercial adsorbents, including granular activated carbon, DARCO-AC, and two resins, XAD-4 and D-201, were used for comparison. The polymer shows ultrarapid adsorption kinetics for the removal of these pollutants, with pseudo-second-order rate constants two to three orders of magnitude higher than that of the commercial activated carbon and resins. Due to the different adsorption sites of NOM and OMPs, β-CDP can simultaneously remove these pollutants without competitive adsorption. The maximum adsorption capacity of β-CDP for HA, FA, 2-NO, 3-PH, 2,4,6-TCP, BPA, and BPS based on the Langmuir model is 40, 166, 74, 101, 108, 103, and 117 mg g–1, respectively. After use, the polymer can be easily regenerated at room temperature. In addition, β-CDP also showed excellent bactericidal properties due to the quaternary ammonium groups. At a concentration of 15 g L–1, β-CDP can remove 98% of the tested Escherichia coli. Moreover, the synthesis of β-CDP is simple, green, and easy to industrialize. All of these findings indicate that β-CDP, as an ideal multifunctional material, presents potential for practical applications for water treatment and disinfection