Universal Ratios of Characteristic Lengths in Semidilute Polymer Solutions

We use experimental and simulation data from the literature to infer five characteristic lengths, denoted $\xi_s$, $\xi_f$, $\xi_\Pi$, $\xi_\phi$, and $\xi_D$ of a semidilute polymer solution. The first two of these are defined in terms of scattering from the solution, the third is defined in terms of osmotic pressure, the fourth by the spatial monomer concentration profile, and the last by co-operative diffusion. In a given solution the ratios of any of these five lengths are expected to be universal constants. Knowing these constants thus allows one to use one measured property of a solution as a means of inferring others. We calculate these ratios and estimate their uncertainties for solutions in theta as well as good-solvent conditions. The analysis is strengthened by use of scattering properties of isolated polymers inferred from computer simulations.Comment: 15 pages(pdf), to be submitted to Macromolecules or J. Chem. Phy

Full alignment of colloidal objects by programmed forcing

By analysis and simulation we demonstrate two methods for achieving complete orientational alignment of a set of identical, asymmetric colloidal objects dispersed randomly in a fluid. Sedimentation or electrophoresis in a constant field can lead to partial alignment, in which the objects rotate about a common body axis, but the phases of rotation for these objects are random. We show that this phase disorder can be removed by two forms of programmed forcing. First, simply alternating the forcing between two directions reduces the statistical entropy of the orientation arbitrarily. Second, addition of a small rotating component to the applied field in analogy to magnetic resonance can lead to phase locking of the objects' orientation. We identify conditions for alignment of a broad class of generic objects and discuss practical limitations.Comment: 5 pages, 2 figure

Theta Dependence In The Large N Limit Of Four-Dimensional Gauge Theories

The theta dependent of pure gauge theories in four dimensions can be studied using a duality of large N gauge theories with string theory on a certain spacetime. Via this duality, one can argue that for every theta, there are infinitely many vacua that are stable in the large N limit. The true vacuum, found by minimizing the energy in this family, is a smooth function of theta except at theta equal to pi, where it jumps. This jump is associated with spontaneous breaking of CP symmetry. Domain walls separating adjacent vacua are described in terms of wrapped sixbranes.Comment: 8 p

Robust propagation direction of stresses in a minimal granular packing

By employing the adaptive network simulation method, we demonstrate that the ensemble-averaged stress caused by a local force for packings of frictionless rigid beads is concentrated along rays whose slope is consistent with unity: forces propagate along lines at 45 degrees to the horizontal or vertical. This slope is shown to be independent of polydispersity or the degree to which the system is sheared. Further confirmation of this result comes from fitting the components of the stress tensor to the null stress constitutive equation. The magnitude of the response is also shown to fall off with the -1/2 power of distance. We argue that our findings are a natural consequence of a system that preserves its volume under small perturbations.Comment: 8 pages, 6 figures. Some extra clarification and minor improvements. To appear in EPJ-

The polymer mat: Arrested rebound of a compressed polymer layer

Compression of an adsorbed polymer layer distorts its relaxed structure. Surface force measurements from different laboratories show that the return to this relaxed structure after the compression is released can be slowed to the scale of tens of minutes and that the recovery time grows rapidly with molecular weight. We argue that the arrested state of the free layer before relaxation can be described as a Guiselin brush structure1, in which the surface excess lies at heights of the order of the layer thickness, unlike an adsorbed layer. This brush structure predicts an exponential falloff of the force at large distance with a decay length that varies as the initial compression distance to the 6/5 power. This exponential falloff is consistent with surface force measurements. We propose a relaxation mechanism that accounts for the increase in relaxation time with chain length.Comment: 24 pages, 5 figre

Surface charge relaxation and the pearling instability of charged surfactant tubes

The pearling instability of bilayer surfactant tubes was recently observed during the collapse of fluid monolayers of binary mixtures of DMPC$-$POPG and DPPC$-$POPG surfactants. We suggested it has the same physics as the well-known Raleigh instability under the action of the bilayer surface tension whose magnitude is dictated by the electrostatic interaction between charged surfactants. In this paper, we calculate the relaxation of charge molecules during the deformation of the tubes into pearling structure. We find the functional dependence of the relaxation energy on the screening length $\kappa^{-1}$ explicitly. Relaxation effect lowers the cost of bending a tube into pearls making the cylindrical tube even more unstable. It is known that for weak screening case where the tube radius is smaller than the screening length of the solution, this relaxation effect is important. However, for the case of strong screening it is negligible. For the experiments mentioned, the situation is marginal. In this case, we show this relaxation effect remains small. It gives less than 20% contribution to the total electrostatic energy.Comment: 7 pages, 3 figures, to be submitted to PR

Asymptotically AdS Magnetic Branes in (n+1)-dimensional Dilaton Gravity

We present a new class of asymptotically AdS magnetic solutions in ($n+1$)-dimensional dilaton gravity in the presence of an appropriate combination of three Liouville-type potentials. This class of solutions is asymptotically AdS in six and higher dimensions and yields a spacetime with longitudinal magnetic field generated by a static brane. These solutions have no curvature singularity and no horizons but have a conic geometry with a deficit angle. We find that the brane tension depends on the dilaton field and approaches a constant as the coupling constant of dilaton field goes to infinity. We generalize this class of solutions to the case of spinning magnetic solutions and find that, when one or more rotation parameters are nonzero, the brane has a net electric charge which is proportional to the magnitude of the rotation parameters. Finally, we use the counterterm method inspired by AdS/CFT correspondence and compute the conserved quantities of these spacetimes. We found that the conserved quantities do not depend on the dilaton field, which is evident from the fact that the dilaton field vanishes on the boundary at infinity.Comment: 15 page

Stress condensation in crushed elastic manifolds

We discuss an M-dimensional phantom elastic manifold of linear size L crushed into a small sphere of radius R << L in N-dimensional space. We investigate the low elastic energy states of 2-sheets (M=2) and 3-sheets (M=3) using analytic methods and lattice simulations. When N \geq 2M the curvature energy is uniformly distributed in the sheet and the strain energy is negligible. But when N=M+1 and M>1, both energies appear to be condensed into a network of narrow M-1 dimensional ridges. The ridges appear straight over distances comparable to the confining radius R.Comment: 4 pages, RevTeX + epsf, 4 figures, Submitted to Phys. Rev. Let

Unstable topography of biphasic surfactant monolayers

We study the conformation of a heterogeneous surfactant monolayer at a fluid-fluid interface, near a boundary between two lateral regions of differing elastic properties. The monolayer attains a conformation of shallow, steep `mesas' with a height difference of up to 10 nm. If the monolayer is progressively compressed (e.g. in a Langmuir trough), the profile develops overhangs and finally becomes unstable at a surface tension of about K(delta c_0)^2, where (delta c_0) is the difference in spontaneous curvature and K a bending stiffness. We discuss the relevance of this instability to recently observed folding behavior in lung surfactant monolayers, and to the absence of domain structures in films separating oil and water in emulsions.Comment: 7 pages, 7 figures, LaTex using epl.cls, accepted for Europhys Let