Liquid-phase hydrogenation of bio-refined succinic acid to 1,4-butanediol using bimetallic catalysts

open access articleDevelopment of a Crotalaria juncea based biorefinery produce large quantity of waste glycerol after trans-esterification of the juncea seeds. This glycerol, after purification, is used as a substrate for producing succinic acid on a microbial route. Hydrogenation of this bio-refined succinic acid is carried out under high pressure in order to produce 1,4- butanediol (BDO) using a batch slurry reactor with cobalt supported ruthenium bimetallic catalysts, synthesized inhouse. It is demonstrated that, using small amounts of ruthenium to cobalt increases the overall hydrogenation activity for the production of 1,4-butanediol. Hydrogenation reactions are carried out at various operating temperatures and pressures along with changes in the mixing ratios of ruthenium chloride and cobalt chloride hexahydrate, which are used to synthesize the catalyst. The Ru-Co bimetallic catalysts are characterized by XRD, FE-SEM and TGA. Concentrations of the hydrogenation product are analyzed using Gas chromatography-Mass spectrometry (GC-MS). Statistical analysis of the overall hydrogenation process is performed using a Box-Behnken Design (BBD)

Social Network Games with Obligatory Product Selection

Recently, Apt and Markakis introduced a model for product adoption in social networks with multiple products, where the agents, influenced by their neighbours, can adopt one out of several alternatives (products). To analyze these networks we introduce social network games in which product adoption is obligatory. We show that when the underlying graph is a simple cycle, there is a polynomial time algorithm allowing us to determine whether the game has a Nash equilibrium. In contrast, in the arbitrary case this problem is NP-complete. We also show that the problem of determining whether the game is weakly acyclic is co-NP hard. Using these games we analyze various types of paradoxes that can arise in the considered networks. One of them corresponds to the well-known Braess paradox in congestion games. In particular, we show that social networks exist with the property that by adding an additional product to a specific node, the choices of the nodes will unavoidably evolve in such a way that everybody is strictly worse off.Comment: In Proceedings GandALF 2013, arXiv:1307.416

Evidence of an interaction from resolved stellar populations: The curious case of NGC1313

The galaxy NGC1313 has attracted the attention of various studies due to the peculiar morphology observed in optical bands, although it is classified as a barred, late-type galaxy with no apparent close-by companions. However, the velocity field suggests an interaction with a satellite companion. Using resolved stellar populations, we study different parts of the galaxy to understand further its morphology. Based on HST/ACS images, we estimated star formation histories by means of the synthetic CMD method in different areas in the galaxy. Incompleteness limits our analysis to ages younger than ~100Myr. Stars in the red and blue He burning phases are used to trace the distribution of recent star formation. Star formation histories suggest a burst in the southern-west region. We support the idea that NGC1313 is experiencing an interaction with a satellite companion, observed as a tidally disrupted satellite galaxy in the south-west of NGC1313. However, we do not observe any indication of a perturbation due to the interaction with the satellite galaxy at other locations across the galaxy, suggesting that only a modest-sized companion that did not trigger a global starburst was involved.Comment: 10 pages, 4 figures, accepted for publication in MNRA

Flowmeter and Ground Penetrating Radar: comparison between hydrogeological and geophysical methods

We discuss a comparison between saturated hydraulic conductivity calculated with Electromagnetic Borehole Flowmeter (EBF) and water content obtained by Ground Penetrating Radar (GPR) Zero Offset Profile (ZOP

Dry anaerobic digestion of organic waste: A review of operational parameters and their impact on process performance.

open access articleDry digestion is a suitable technology for treating organic wastes with varying composition such as the organic fraction of municipal solids waste. Yet, there is a need for further research to overcome some of the disadvantages associated with the high total solids content of the process. Optimisation of inoculum to substrate ratio, feedstock composition and size, liquid recirculation, bed compaction and use of bulking agents are some of the parameters that need further investigation in batch dry anaerobic digestion, to limit localised inhibition effects and avoid process instability. In addition, further attention on the relation between feedstock composition, organic loading rate and mixing regimes is required for continuous dry anaerobic digestion systems. This paper highlights all the areas where knowledge is scarce and value can be added to increase dry anaerobic digestion performance and expansion