High-efficiency and high-power single-frequency fiber laser at 1.6 um based on cascaded energy-transfer pumping

In this paper, a technique combing cascaded energy-transfer pumping (CEP) method and master-oscillator power-amplifier (MOPA) configuration is proposed for power scaling of 1.6-um-band single-frequency fiber lasers (SFFLs), where the Er3+ ion has a limited gain. The CEP technique is fulfilled by coupling a primary signal light at 1.6 um and a C-band auxiliary laser. The numerical model of the fiber amplifier with the CEP technique reveals that the energy transfer process involves the pump competition and the in-band particle transition between the signal and auxiliary lights. Moreover, for the signal emission, the population density in the upper level is enhanced and the effective population inversion is achieved due to the CEP. A single-frequency MOPA laser at 1603 nm with an output power of 52.6 W is obtained experimentally. Besides, a slope efficiency of 30.4% is improved by more than 10% through the CEP technique. Both the output power and slope efficiency are by far the highest for 1.6-um-band SFFLs. Meanwhile, a laser linewidth of 5.2 kHz and a polarization-extinction ratio of ~18 dB are obtained at the maximum output power. The proposed technique provides an optional method of increasing the slope efficiency and power scaling for fiber lasers operating at L-band

Understanding and Manipulating Helical Nanofilaments in Binary Systems with Achiral Dopants

Here, we report the relationship between helical pitch of the helical nanofilament (HNF) phase formed by bent-core molecule NOBOW and the concentration of achiral dopants 5CB and octane, using linearly polarized resonant soft X-ray scattering (RSoXS). Utilizing theory-based simulation, which fits well with the experiments, the molecular helices in the filament were probed and the superstructure of helical 5CB directed by groove of HNFs was observed. Quantitative pitch determination with RSoXS reveals that helical pitch variation is related to 5CB concentration with no temperature dependence. Doping rodlike immiscible 5CB led to a pitch shortening of up to 30%, which was attributed to a change in interfacial tension. By shedding light not only on phase behavior of binary systems but also enabling control over pitch length, our work may benefit various applications of HNF-containing binary systems, including optical rotation devices, circularly polarized light emitters, and chirality transfer agents

Aerosol Liquid Water Driven by Anthropogenic Inorganic Salts: Implying Its Key Role in Haze Formation over the North China Plain

This study reveals aerosol liquid water content (ALWC) in PM_2.5 ranged from 2% up to 74%, and the associated secondary inorganic fraction rose from 24% to 55%, while ambient relative humidity (RH) increased from 15% to 83% in the atmosphere over Beijing. Unexpectedly, the secondary inorganic fraction in PM_2.5 increased with an increase in the ambient RH, which is a meteorological parameter independent of anthropogenic activities, indicating the presence of a feedback mechanism driven by Henry’s law and thermodynamic equilibrium. During haze episodes, simultaneously elevated RH levels and anthropogenic secondary inorganic mass concentrations resulted in an abundant ALWC. The condensed water could act as an efficient medium for multiphase reactions, thereby facilitating the transformation of reactive gaseous pollutants into particles and accelerating the formation of heavy haze. ALWC was well correlated with the mass concentrations of both nitrate and sulfate, indicating both nitrate and sulfate salts play key roles in determining ALWC. Coincident with a significant reduction in SO₂ emissions throughout China, nitrates will become a dominant anthropogenic inorganic salt driving ALWC. Thus, the abundance of ALWC and its effects on the aerosol chemistry and climate should be reconsidered

Enhancement in Particulate Organic Nitrogen and Light Absorption of Humic-Like Substances over Tibetan Plateau Due to Long-Range Transported Biomass Burning Emissions

To elucidate the influence of long-range transported biomass burning organic aerosols (BBOA) on the Tibetan Plateau, the molecular compositions and light absorption of HUmic-Like Substances (HULIS), major fractions of brown carbon, were characterized during the premonsoon season. Under the significant influence of biomass burning, HULIS concentrations increased to as high as 26 times of the background levels, accounting for 54% of water-soluble organic carbon (WSOC) and 50% of organic carbon (OC). The light absorption of HULIS also enhanced up to 42 times of the background levels, contributing 61% of the WSOC absorption and 50% of OC absorption. Meanwhile, elevated nitrogen-containing compounds (NOCs) among HULIS were observed. The NOCs from fresh and aged BBOA were unambiguously identified on the molecular level, through comparing with the molecular compositions of NOCs from lab-controlled and field burning experiments. N-Heterocyclic bases represent major fractions in the reduced nitrogen compounds from fresh BBOA, and nitroaromatic compounds are important groups among the oxidized nitrogen compounds from aged BBOA. The nitrogen-containing compounds, including nitroaromatics and N-heterocyclic compounds, were also important chromophores, which contributed to the enhanced light absorption of extracted HULIS during biomass burning-influenced periods