Role of electrostatic forces in cluster formation in a dry ionomer

This simulation study investigates the dependence of the structure of dry Nafion$^{\tiny\textregistered}$-like ionomers on the electrostatic interactions between the components of the molecules. In order to speed equilibration, a procedure was adopted which involved detaching the side chains from the backbone and cutting the backbone into segments, and then reassembling the macromolecule by means of a strong imposed attractive force between the cut ends of the backbone, and between the non-ionic ends of the side chains and the midpoints of the backbone segments. Parameters varied in this study include the dielectric constant, the free volume, side-chain length, and strength of head-group interactions. A series of coarse-grained mesoscale simulations shows the morphlogy to depend sensitively on the ratio of the strength of the dipole-dipole interactions between the side-chain acidic end groups to the strength of the other electrostatic components of the Hamiltonian. Examples of the two differing morphologies proposed by Gierke and by Gebel emerge from our simulations.Comment: 39 pages, 18 figures, accepted for publicatio

Predicted field-induced hexatic structure in an ionomer membrane

Coarse-grained molecular-dynamics simulations were used to study the morphological changes induced in a Nafion$^{\tiny \textregistered}$-like ionomer by the imposition of a strong electric field. We observe the formation of novel structures aligned along the direction of the applied field. The polar head groups of the ionomer side chains aggregate into clusters, which then form rod-like formations which assemble into a hexatic array aligned with the direction of the field. Occasionally these lines of sulfonates and protons form a helical structure. Upon removal of the electric field, the hexatic array of rod-like structures persists, and has a lower calculated free energy than the original isotropic morphology.Comment: 4 pages, 7 figure

Welfare Reform in Agricultural California

When welfare reforms were enacted in 1996, a higher than average percentage of residents in the agricultural heartland of California, the San Joaquin Valley, received cash assistance. Average annual unemployment rates during the 1990s ranged from 12% to 20%, and 15% to 20% of residents in major farming counties received cash benefits. This analysis develops and estimates a two-equation cross-sectionally correlated and timewise autoregressive model to test the hypothesis that in agricultural areas, seasonal work, low earnings, and high unemployment, as well as few entry-level jobs that offer wages and benefits equivalent to welfare benefits, promote welfare use and limit the potential of local labor markets to absorb ex-welfare recipients.cross-sectionally correlated and timewise autoregressive model, farm workers, immigration, welfare reform, Public Economics,

Impact of Flower Harvesting on the Salt Marsh Plant \u3cem\u3eLimonium carolinianum\u3c/em\u3e

Because of the potentially detrimental effects of seed production on adult survivorship and growth, moderate flower harvesting may have little negative impact on population growth of long-lived perennial plants such as Limonium carolinianum (Walter) Britton. We examined this by collecting data on survivorship, growth, and fecundity of an unharvested population over a period of 5 years and conducted a controlled experiment to examine the effect of harvesting on adult survivorship and growth over a 3-year period. Data were summarized in the form of a stage structured matrix population model with a stochastic element that incorporated year-to-year variation in transition probabilities. Contrary to our original hypothesis, we found that preventing seed set through removal of flowers did not increase adult survivorship or growth. By determining the harvest level that reduced population growth rate to 1.0, we estimated the maximum sustainable harvest level to be 16%, a value that is approximately half that of reported harvest levels on accessible marshes in the study area. In spite of this, the reported harvest levels are unlikely to drive local populations to extinction in the foreseeable future. Providing the adult population size is \u3e100 and harvest levels are \u3c90%, time to local extinction will exceed 100 years. This is a function of the very high survivorship of adults in this species and the fact that harvesting has no negative impact on adult survivorship or growth. However, because of the long preadult phase in this species (8–9 years) and the fact that fecundity of young adults is low, recovery from overharvesting is extremely slow. Adult population size can be reduced to 25% of its original value in 7 years at high harvest levels, but it will take 34 years on average to recover once harvesting is terminated

A 2.5-GHz asymmetric multilevel outphasing power amplifier in 65-nm CMOS

We present a high-efficiency transmitter based on asymmetric multilevel outphasing (AMO). AMO transmitters improve their efficiency over LINC (linear amplification using nonlinear components) transmitters by switching the output envelopes of the power amplifiers among a discrete set of levels. This minimizes the occurrence of large outphasing angles, reducing the energy lost in the power combiner. We demonstrate this concept with a 2.5-GHz, 20-dBm peak output power transmitter using 2-level AMO designed in a 65-nm CMOS process. To the authors' knowledge, this IC is the first integrated implementation of the AMO concept. At peak output power, the measured power-added efficiency is 27.8%. For a 16-QAM signal with 6.1dB peak-to-average power ratio, the AMO prototype improves the average efficiency from 4.7% to 10.0% compared to the standard LINC system

Exact Numerical Solution of the BCS Pairing Problem

We propose a new simulation computational method to solve the reduced BCS Hamiltonian based on spin analogy and submatrix diagonalization. Then we further apply this method to solve superconducting energy gap and the results are well consistent with those obtained by Bogoliubov transformation method. The exponential problem of 2^{N}-dimension matrix is reduced to the polynomial problem of N-dimension matrix. It is essential to validate this method on a real quantumComment: 7 pages, 3 figure

radR: an open-source platform for acquiring and analysing data on biological targets observed by surveillance radar

<p>Abstract</p> <p>Background</p> <p>Radar has been used for decades to study movement of insects, birds and bats. In spite of this, there are few readily available software tools for the acquisition, storage and processing of such data. Program radR was developed to solve this problem.</p> <p>Results</p> <p>Program radR is an open source software tool for the acquisition, storage and analysis of data from marine radars operating in surveillance mode. radR takes time series data with a two-dimensional spatial component as input from some source (typically a radar digitizing card) and extracts and retains information of biological relevance (i.e. moving targets). Low-level data processing is implemented in "C" code, but user-defined functions written in the "R" statistical programming language can be called at pre-defined steps in the calculations. Output data formats are designed to allow for future inclusion of additional data items without requiring change to C code. Two brands of radar digitizing card are currently supported as data sources. We also provide an overview of the basic considerations of setting up and running a biological radar study.</p> <p>Conclusions</p> <p>Program radR provides a convenient, open source platform for the acquisition and analysis of radar data of biological targets.</p