10 research outputs found
MOESM3 of First result from the GEONET real-time analysis system (REGARD): the case of the 2016 Kumamoto earthquakes
Additional file 3: Figure S3. Simulated update history of the finite-fault models estimated by the REGARD system during the April 14 foreshock (M j 6.5) from top to bottom. Observed (black arrows) and predicted (white arrows) displacements for horizontal (left) and vertical (right) components are shown. Gray arrows denote the displacements predicted by a priori model. The red rectangle represents the estimated fault plane, and the blue arrow shows the slip vector. The epicenter of the April 14 foreshock (M j 6.5) is shown as a red star. The aftershocks in the JMA unified hypocenter catalog between April 14, 2016, and May 18, 2016, are shown as gray dots. Black lines indicate the ground traces of the active faults (HERP 2013). The model parameters are shown in the table at bottom
MOESM1 of First result from the GEONET real-time analysis system (REGARD): the case of the 2016 Kumamoto earthquakes
Additional file 1: Figure S1. Update history of the finite-fault models estimated by the REGARD system during the 2016 Kumamoto earthquake (M j 7.3) from top to bottom. Observed (black arrows) and predicted (white arrows) displacements for horizontal (left) and vertical (right) components are shown. The red rectangle represents the estimated fault plane, and the blue arrow shows the slip vector. The epicenter of the mainshock is shown as a red star. The aftershocks in the JMA unified hypocenter catalog between April 14, 2016, and May 18, 2016, are shown as gray dots. Black lines indicate the ground traces of the active faults (HERP 2013)
Correction to “Total Syntheses of Lyconadins A–C”
Correction
to “Total Syntheses of Lyconadins
A–C
Correction to “Concise Total Synthesis of (+)-Lyconadin A”
Correction
to “Concise Total Synthesis of (+)-Lyconadin
A
Total Syntheses of Lyconadins A–C
The total synthesis of the Lycopodium alkaloid lyconadin A was accomplished and it was applied to the
total syntheses of the related congeners, lyconadins B and C. Lyconadin
A has attracted attention as a challenging target for total synthesis
due to the unprecedented pentacyclic skeleton. Our synthesis of lyconadin
A features a facile construction of the highly fused tetracyclic skeleton
through a combination of an aza-Prins reaction and an electrocyclic
ring opening, followed by formation of a C–N bond. Transformation
of the bromoalkene moiety of the tetracycle to a key enone intermediate
was extensively investigated, and three methods via sulfide, oxime,
or azide intermediates were established. A pyridone ring was constructed
from the key enone intermediate to complete the synthesis of lyconadin
A. A dihydropyridone ring could also be formed from the same enone
intermediate, leading to a synthesis of lyconadin B. Establishment
of the conditions for an electrocyclic ring opening without formation
of the C–N bond resulted in completion of the total synthesis
of lyconadin C
Total Syntheses of Lyconadins A–C
The total synthesis of the Lycopodium alkaloid lyconadin A was accomplished and it was applied to the
total syntheses of the related congeners, lyconadins B and C. Lyconadin
A has attracted attention as a challenging target for total synthesis
due to the unprecedented pentacyclic skeleton. Our synthesis of lyconadin
A features a facile construction of the highly fused tetracyclic skeleton
through a combination of an aza-Prins reaction and an electrocyclic
ring opening, followed by formation of a C–N bond. Transformation
of the bromoalkene moiety of the tetracycle to a key enone intermediate
was extensively investigated, and three methods via sulfide, oxime,
or azide intermediates were established. A pyridone ring was constructed
from the key enone intermediate to complete the synthesis of lyconadin
A. A dihydropyridone ring could also be formed from the same enone
intermediate, leading to a synthesis of lyconadin B. Establishment
of the conditions for an electrocyclic ring opening without formation
of the C–N bond resulted in completion of the total synthesis
of lyconadin C
Correction to 2‑Pyridone Synthesis Using 2‑(Phenylsulfinyl)acetamide
Correction to 2‑Pyridone Synthesis Using 2‑(Phenylsulfinyl)acetamid
MOESM1 of Ground uplift related to permeability enhancement following the 2011 Tohoku earthquake in the Kanto Plain, Japan
Additional file 1. Table S1. SAR acquisition dates and perpendicular baselines. Bperp indicates perpendicular component of baseline
Diastereoselective Addition of Allyltitanocenes to Cyclic Enones
The reaction of allyltitanocenes with five- to seven-membered cyclic enones proceeded with good to high diastereoselectivity depending on the ring size of enones. The stereochemistry of the major isomers produced by the reaction of cinnamyltitanocene was opposite to that of crotyltitanocene
MOESM1 of Volcanic deformation of Atosanupuri volcanic complex in the Kussharo caldera, Japan, from 1993 to 2016 revealed by JERS-1, ALOS, and ALOS-2 radar interferometry
Additional file 1. Fig. S1 Daily vertical displacement observed at GNSS stations around the Kussharo caldera. Fig. S2 Unwrapped SAR interferograms after the small-scale constant deformation correction