Polarization of L Dwarfs by Dust Scattering

The degree of polarization in L dwarfs of spectral types L0 to L6 resulting from dust scattering in a rotation-induced oblate photosphere is calculated. Assuming that forsterite is the main condensate, the atmospheric dust distribution is derived for different spectral types based on a chemical equilibrium model. The degree of polarization at optical is then calculated using a single scattering model. The expected linear polarization at optical is found to peak at around spectral type L1. For a fixed rotational velocity, the degree of polarization decreases from hotter to cooler objects. However, with the increase in mean grain size, the degree of linear polarization reduces significantly. We fit the recently observed linear polarimetric data of L dwarfs and find that single dust scattering model coupled with the chemical equilibrium models of condensates is consistent with the observational results.Comment: Latex (aastex sty), 23 pages including 7 postscript figures. Accepted for publication in the Astrophysical Journal (Part 1

On the viability of the PAH model as an explanation of the unidentified infrared emission features

Polycyclic aromatic hydrocarbon (PAH) molecules are widely considered as the preferred candidate for the carrier of the unidentified infrared emission bands observed in the interstellar medium and circumstellar envelopes. In this paper we report the result of fitting a variety of non-PAH spectra (silicates, hydrogenated amorphous carbon, coal and even artificial spectra) using the theoretical infrared spectra of PAHs from the NASA Ames PAH IR Spectroscopic Database. We show that these non-PAH spectra can be well fitted by PAH mixtures. This suggest that a general match between astronomical spectra and those of PAH mixtures does not necessarily provide definitive support for the PAH hypothesis.Comment: 19 pages, 9 figures, accepted for publication in Ap

Unidentified Infrared Emission bands: PAHs or MAONs?

We suggest that the carrier of the unidentified infrared emission (UIE) bands is an amorphous carbonaceous solid with mixed aromatic/aliphatic structures, rather than free-flying polycyclic aromatic hydrocarbon (PAH) molecules. Through spectral fittings of the astronomical spectra of the UIE bands, we show that a significant amount of the energy is emitted by the aliphatic component, implying that aliphatic groups are an essential part of the chemical structure. Arguments in favor of an amorphous, solid-state structure rather than a gas-phase molecule as a carrier of the UIE are also presented.Comment: 9 figures, accepted for publication in The Astrophysical Journa

On the origin of the 11.3 micron unidentified infrared emission feature

The 11.3 $\mu$m emission feature is a prominent member of the family of unidentified infrared emission (UIE) bands and is frequently attributed to out-of-plane bending modes of polycyclic aromatic hydrocarbon (PAH) molecules. We have performed quantum mechanical calculations of 60 neutral PAH molecules and found that it is difficult to reconcile the observed astronomical feature with any or a mix of these PAH molecules. We have further analyzed the fitting of spectra of several astronomical objects by the NASA PAH database program and found that reasonable fittings to the observed spectra are only possible by including significant contributions from oxygen and/or magnesium containing molecules in the mix. A mixed of pure PAH molecules, even including units of different sizes, geometry and charged states, is unable to fit the astronomical spectra. Preliminary theoretical results on the vibrational spectra of simple molecules with mixed aromatic/aliphatic structures show that these structures have consistent bundles of vibrational modes and could be viable carriers of the UIE bands.Comment: 28 pages, 11 figures, accepted for publication in Ap

A Theoretical Study on the Vibrational Spectra of PAH Molecules with Aliphatic Sidegroups

The role of aliphatic side groups on the formation of astronomical unidentified infrared emission (UIE) features is investigated by applying the density functional theory (DFT) to a series of molecules with mixed aliphatic-aromatic structures. The effects of introducing various aliphatic groups to a fixed polycyclic aromatic hydrocarbon (PAH) core (ovalene) are studied. Simulated spectra for each molecule are produced by applying a Drude profile at $T$=500 K while the molecule is kept at its electronic ground state. The vibrational normal modes are classified using a semi-quantitative method. This allows us to separate the aromatic and aliphatic vibrations and therefore provide clues to what types of vibrations are responsible for the emissions bands at different wavelengths. We find that many of the UIE bands are not pure aromatic vibrational bands but may represent coupled vibrational modes. The effects of aliphatic groups on the formation of the 8 $\mu$m plateau are qua ntitatively determined. The vibrational motions of methyl ($-$CH$_3$) and methyl ene ($-$CH$_2-$) groups can cause the merging of the vibrational bands of the pa rent PAH and the forming of broad features. These results suggest that aliphatic structures can play an important role in th e UIE phenomenon.Comment: 29 pages, 13 figures, Accepted for publication in Ap

On the Origin of the 3.3 Micron Unidentified Infrared Emission Feature

The 3.3 $\mu$m unidentified infrared emission feature is commonly attributed to C-H stretching band of aromatic molecules. Astronomical observations have shown that this feature is composed of two separate bands at 3.28 and 3.30 $\mu$m and the origin of these two bands is unclear. In this paper, we perform vibrational analyses based on quantum mechanical calculations of 153 organic molecules, including both pure aromatic molecules and molecules with mixed aromatic/olefinic/aliphatic hydridizations. We find that many of the C-H stretching vibrational modes in polycyclic aromatic hydrocarbon (PAH) molecules are coupled. Even considering the un-coupled modes only, the correlation between the band intensity ratios and the structure of the PAH molecule is not observed and the 3.28 and 3.30 $\mu$m features cannot be directly interpreted in the PAH model. Based on these results, the possible aromatic, olefinic and aliphatic origins of the 3.3 $\mu$m feature are discussed. We suggest that the 3.28 $\mu$m feature is assigned to aromatic C-H stretch whereas the 3.30 $\mu$m feature is olefinic. From the ratio of these two features, the relative olefinic to aromatic content of the carrier can be determined.Comment: 33 pages, 14 figures. Accepted for publication in Ap

Multipolar Planetary Nebulae: Not as Geometrically Diversified as Thought

Planetary nebulae (PNe) have diverse morphological shapes, including point-symmetric and multipolar structures. Many PNe also have complicated internal structures such as torus, lobes, knots, and ansae. A complete accounting of all the morphological structures through physical models is difficult. A first step toward such an understanding is to derive the true three-dimensional structure of the nebulae. In this paper, we show that a multipolar nebula with three pairs of lobes can explain many of such features, if orientation and sensitivity effects are taken into account. Using only six parameters - the inclination and position angles of each pair - we are able to simulate the observed images of 20 PNe with complex structures. We suggest that the multipolar structure is an intrinsic structure of PNe and the statistics of multipolar PNe has been severely underestimated in the past.Comment: 36 pages, 5 figures, 2 table