Multiphase Porous Electrode Theory

Porous electrode theory, pioneered by John Newman and collaborators, provides a useful macroscopic description of battery cycling behavior, rooted in microscopic physical models rather than empirical circuit approximations. The theory relies on a separation of length scales to describe transport in the electrode coupled to intercalation within small active material particles. Typically, the active materials are described as solid solution particles with transport and surface reactions driven by concentration fields, and the thermodynamics are incorporated through fitting of the open circuit potential. This approach has fundamental limitations, however, and does not apply to phase-separating materials, for which the voltage is an emergent property of inhomogeneous concentration profiles, even in equilibrium. Here, we present a general theoretical framework for "multiphase porous electrode theory" implemented in an open-source software package called "MPET", based on electrochemical nonequilibrium thermodynamics. Cahn-Hilliard-type phase field models are used to describe the solid active materials with suitably generalized models of interfacial reaction kinetics. Classical concentrated solution theory is implemented for the electrolyte phase, and Newman's porous electrode theory is recovered in the limit of solid-solution active materials with Butler-Volmer kinetics. More general, quantum-mechanical models of Faradaic reactions are also included, such as Marcus-Hush-Chidsey kinetics for electron transfer at metal electrodes, extended for concentrated solutions. The full equations and numerical algorithms are described, and a variety of example calculations are presented to illustrate the novel features of the software compared to existing battery models

Development of stitching reinforcement for transport wing panels

The NASA Advanced Composites Technology (ACT) program has the objective of providing the technology required to obtain the full benefit of weight savings and performance improvements offered by composite primary aircraft structures. Achieving the objective is dependent upon developing composite materials and structures which are damage tolerant and economical to manufacture. Researchers are investigating stitching reinforcement combined with resin transfer molding to produce materials meeting the ACT program objective. Research is aimed at materials, processes, and structural concepts for application in both transport wings and fuselages, but the emphasis to date has been on wing panels. Empirical guidelines are being established for stitching reinforcement in structures designed for heavy loads. Results are presented from evaluation tests investigating stitching types, threads, and density (penetrations per square inch). Tension strength, compression strength, and compression after impact data are reported

Measuring the Values for Time

Most economic models for time allocation ignore constraints on what people can actually do with their time. Economists recently have emphasized the importance of considering prior consumption commitments that constrain behavior. This research develops a new model for time valuation that uses time commitments to distinguish consumers' choice margins and the different values of time these imply. The model is estimated using a new survey that elicits revealed and stated preference data on household time allocation. The empirical results support the framework and find an increasing marginal opportunity cost of time as longer time blocks are used.

Interplay of phase boundary anisotropy and electro-autocatalytic surface reactions on the lithium intercalation dynamics in LiX_XFePO4_4 platelet-like nanoparticles

Experiments on single crystal Li$_X$FePO$_4$ (LFP) nanoparticles indicate rich nonequilibrium phase behavior, such as suppression of phase separation at high lithiation rates, striped patterns of coherent phase boundaries, nucleation by binarysolid surface wetting and intercalation waves. These observations have been successfully predicted (prior to the experiments) by 1D depth-averaged phase-field models, which neglect any subsurface phase separation. In this paper, using an electro-chemo-mechanical phase-field model, we investigate the coherent non-equilibrium subsurface phase morphologies that develop in the $ab$- plane of platelet-like single-crystal platelet-like Li$_X$FePO$_4$ nanoparticles. Finite element simulations are performed for 2D plane-stress conditions in the $ab$- plane, and validated by 3D simulations, showing similar results. We show that the anisotropy of the interfacial tension tensor, coupled with electroautocatalytic surface intercalation reactions, plays a crucial role in determining the subsurface phase morphology. With isotropic interfacial tension, subsurface phase separation is observed, independent of the reaction kinetics, but for strong anisotropy, phase separation is controlled by surface reactions, as assumed in 1D models. Moreover, the driven intercalation reaction suppresses phase separation during lithiation, while enhancing it during delithiation, by electro-autocatalysis, in quantitative agreement with {\it in operando} imaging experiments in single-crystalline nanoparticles, given measured reaction rate constants

Single-Electron Spectroscopy

Contains an introduction, reports on four research projects and a list of publications,Joint Services Electronics Program Grant DAAH04-95-1-0038National Science Foundation Young Investigator AwardU.S. Navy - Office of Naval Research Grant N00014-93-1-063

XMM-Newton Witness of M86 X-ray Metamorphosis

The environmental influence of cluster media on its member galaxies, known as Butcher--Oemler effect, has recently been subject to revision due to numerous observations of strong morphological transformations occurring outside the cluster virial radii, caused by some unidentified gas removal processes. In this context we present new XMM-Newton observations of M86 group. The unique combination of high spatial and spectral resolution and large field of view of XMM-Newton allows an in-depth investigation of the processes involved in the spectacular disruption of this object. We identify a possible shock with Mach number of ~1.4 in the process of crushing the galaxy in the North-East direction. The latter is ascribed to the presence of a dense X-ray emitting filament, previously revealed in the RASS data. The shock is not associated with other previously identified features of M86 X-ray emission, such as the plume, the north-eastern arm and the southern extension, which are found to have low entropy, similar to the inner 2 kpc of M86. Finally, mere existence of the large scale gas halo around the M86 group, suggests that the disruptions of M86's X-ray halo may be caused by small-scale types of interactions such as galaxy-galaxy collisions.Comment: 11 pages, A&A in pres

Supernova Remnants in the Magellanic Clouds III: An X-ray Atlas of LMC Supernova Remnants

We have used archival ROSAT data to present X-ray images of thirty-one supernova remnants (SNRs) in the Large Magellanic Cloud (LMC). We have classified these remnants according to their X-ray morphologies, into the categories of Shell-Type, Diffuse Face, Centrally Brightened, Point-Source Dominated, and Irregular. We suggest possible causes of the X-ray emission for each category, and for individual features of some of the SNRs.Comment: 27 pages, 6 figures (9 figure files). To appear in the Supplement Series of the Astrophysical Journal, August 1999 Vol. 123 #