Electron Spin Dynamics in Semiconductors without Inversion Symmetry

We present a microscopic analysis of electron spin dynamics in the presence of an external magnetic field for non-centrosymmetric semiconductors in which the D'yakonov-Perel' spin-orbit interaction is the dominant spin relaxation mechanism. We implement a fully microscopic two-step calculation, in which the relaxation of orbital motion due to electron-bath coupling is the first step and spin relaxation due to spin-orbit coupling is the second step. On this basis, we derive a set of Bloch equations for spin with the relaxation times T_1 and T_2 obtained microscopically. We show that in bulk semiconductors without magnetic field, T_1 = T_2, whereas for a quantum well with a magnetic field applied along the growth direction T_1 = T_2/2 for any magnetic field strength.Comment: to appear in Proceedings of Mesoscopic Superconductivity and Spintronics (MS+S2002

Quantum effects in energy and charge transfer in an artificial photosynthetic complex

We investigate the quantum dynamics of energy and charge transfer in a wheel-shaped artificial photosynthetic antenna-reaction center complex.This complex consists of six light-harvesting chromophores and an electron-acceptor fullerene. To describe quantum effects on a femtosecond time scale, we derive the set of exact non-Markovian equations for the Heisenberg operators of this photosynthetic complex in contact with a Gaussian heat bath. With these equations we can analyze the regime of strong system-bath interactions, where reorganization energies are of the order of the intersite exciton couplings. We show that the energy of the initially-excited antenna chromophores is efficiently funneled to the porphyrin-fullerene reaction center, where a charge-separated state is set up in a few picoseconds, with a quantum yield of the order of 95%. In the single-exciton regime, with one antenna chromophore being initially excited, we observe quantum beatings of energy between two resonant antenna chromophores with a decoherence time of $\sim$ 100 fs. We also analyze the double-exciton regime, when two porphyrin molecules involved in the reaction center are initially excited. In this regime we obtain pronounced quantum oscillations of the charge on the fullerene molecule with a decoherence time of about 20 fs (at liquid nitrogen temperatures). These results show a way to directly detect quantum effects in artificial photosynthetic systems