Mass-Transfer-Induced Multistep Phase Separation in Emulsion Droplets: Toward Self-Assembly Multilayered Emulsions and Onionlike Microspheres

Mass-transfer-induced multistep phase separation was found in emulsion droplets. The agent system consists of a monomer (ethoxylated trimethylolpropane triacrylate, ETPTA), an oligomer (polyethylene glycol diacrylate, PEGDA 700), and water. The PEGDA in the separated layers offered partial miscibility of all the components throughout the multistep phase-separation procedure, which was terminated by the depletion of PEGDA in the outermost layer. The number of separated portions was determined by the initial PEGDA content, and the initial droplet size influenced the mass-transfer process and consequently determined the sizes of the separated layers. The resultant multilayered emulsions were demonstrated to offer an orderly temperature-responsive release of the inner cores. Moreover, the emulsion droplets can be readily solidified into onionlike microspheres by ultraviolet light curing, providing a new strategy in designing particle structures

Microfluidic Assembly of Microblocks into Interlocked Structures for Enhanced Strength and Toughness

Compared with monolithic materials, topologically interlocked materials (TIMs) exhibit higher toughness based on their enhanced crack deflection and deformation tolerance. Importantly, by reducing the block size of TIMs, their structural strength can also be improved due to the reduced flexural span. However, the assembly of microscale blocks remains a huge challenge due to the inadequacy of nanoscale self-assembly or macroscale pick-and-place operations. In this work, octahedral microblocks are fabricated and constructed into interlocked structures with different patterns through microfluidic channels with variable cross sections. The pattern of the interlocked panel is demonstrated to affect its strength and toughness. The failure strength and energy absorption of assembled panels significantly exceed that of their monolithic counterpart by ∼33% and ∼19.1 folds, respectively. Generally, the presented microfluidic method provides a unique technique for the assembly of interlocked architecture, which facilitates the design and fabrication of TIMs with highly improved strength and toughness

Microfluidic Assembly of Microblocks into Interlocked Structures for Enhanced Strength and Toughness

Compared with monolithic materials, topologically interlocked materials (TIMs) exhibit higher toughness based on their enhanced crack deflection and deformation tolerance. Importantly, by reducing the block size of TIMs, their structural strength can also be improved due to the reduced flexural span. However, the assembly of microscale blocks remains a huge challenge due to the inadequacy of nanoscale self-assembly or macroscale pick-and-place operations. In this work, octahedral microblocks are fabricated and constructed into interlocked structures with different patterns through microfluidic channels with variable cross sections. The pattern of the interlocked panel is demonstrated to affect its strength and toughness. The failure strength and energy absorption of assembled panels significantly exceed that of their monolithic counterpart by ∼33% and ∼19.1 folds, respectively. Generally, the presented microfluidic method provides a unique technique for the assembly of interlocked architecture, which facilitates the design and fabrication of TIMs with highly improved strength and toughness

Microfluidic Assembly of Microblocks into Interlocked Structures for Enhanced Strength and Toughness

Compared with monolithic materials, topologically interlocked materials (TIMs) exhibit higher toughness based on their enhanced crack deflection and deformation tolerance. Importantly, by reducing the block size of TIMs, their structural strength can also be improved due to the reduced flexural span. However, the assembly of microscale blocks remains a huge challenge due to the inadequacy of nanoscale self-assembly or macroscale pick-and-place operations. In this work, octahedral microblocks are fabricated and constructed into interlocked structures with different patterns through microfluidic channels with variable cross sections. The pattern of the interlocked panel is demonstrated to affect its strength and toughness. The failure strength and energy absorption of assembled panels significantly exceed that of their monolithic counterpart by ∼33% and ∼19.1 folds, respectively. Generally, the presented microfluidic method provides a unique technique for the assembly of interlocked architecture, which facilitates the design and fabrication of TIMs with highly improved strength and toughness

Microfluidic Assembly of Microblocks into Interlocked Structures for Enhanced Strength and Toughness

Compared with monolithic materials, topologically interlocked materials (TIMs) exhibit higher toughness based on their enhanced crack deflection and deformation tolerance. Importantly, by reducing the block size of TIMs, their structural strength can also be improved due to the reduced flexural span. However, the assembly of microscale blocks remains a huge challenge due to the inadequacy of nanoscale self-assembly or macroscale pick-and-place operations. In this work, octahedral microblocks are fabricated and constructed into interlocked structures with different patterns through microfluidic channels with variable cross sections. The pattern of the interlocked panel is demonstrated to affect its strength and toughness. The failure strength and energy absorption of assembled panels significantly exceed that of their monolithic counterpart by ∼33% and ∼19.1 folds, respectively. Generally, the presented microfluidic method provides a unique technique for the assembly of interlocked architecture, which facilitates the design and fabrication of TIMs with highly improved strength and toughness

Microfluidic Assembly of Microblocks into Interlocked Structures for Enhanced Strength and Toughness

Compared with monolithic materials, topologically interlocked materials (TIMs) exhibit higher toughness based on their enhanced crack deflection and deformation tolerance. Importantly, by reducing the block size of TIMs, their structural strength can also be improved due to the reduced flexural span. However, the assembly of microscale blocks remains a huge challenge due to the inadequacy of nanoscale self-assembly or macroscale pick-and-place operations. In this work, octahedral microblocks are fabricated and constructed into interlocked structures with different patterns through microfluidic channels with variable cross sections. The pattern of the interlocked panel is demonstrated to affect its strength and toughness. The failure strength and energy absorption of assembled panels significantly exceed that of their monolithic counterpart by ∼33% and ∼19.1 folds, respectively. Generally, the presented microfluidic method provides a unique technique for the assembly of interlocked architecture, which facilitates the design and fabrication of TIMs with highly improved strength and toughness

Microfluidic Assembly of Microblocks into Interlocked Structures for Enhanced Strength and Toughness

Compared with monolithic materials, topologically interlocked materials (TIMs) exhibit higher toughness based on their enhanced crack deflection and deformation tolerance. Importantly, by reducing the block size of TIMs, their structural strength can also be improved due to the reduced flexural span. However, the assembly of microscale blocks remains a huge challenge due to the inadequacy of nanoscale self-assembly or macroscale pick-and-place operations. In this work, octahedral microblocks are fabricated and constructed into interlocked structures with different patterns through microfluidic channels with variable cross sections. The pattern of the interlocked panel is demonstrated to affect its strength and toughness. The failure strength and energy absorption of assembled panels significantly exceed that of their monolithic counterpart by ∼33% and ∼19.1 folds, respectively. Generally, the presented microfluidic method provides a unique technique for the assembly of interlocked architecture, which facilitates the design and fabrication of TIMs with highly improved strength and toughness

Microfluidic Assembly of Microblocks into Interlocked Structures for Enhanced Strength and Toughness

Compared with monolithic materials, topologically interlocked materials (TIMs) exhibit higher toughness based on their enhanced crack deflection and deformation tolerance. Importantly, by reducing the block size of TIMs, their structural strength can also be improved due to the reduced flexural span. However, the assembly of microscale blocks remains a huge challenge due to the inadequacy of nanoscale self-assembly or macroscale pick-and-place operations. In this work, octahedral microblocks are fabricated and constructed into interlocked structures with different patterns through microfluidic channels with variable cross sections. The pattern of the interlocked panel is demonstrated to affect its strength and toughness. The failure strength and energy absorption of assembled panels significantly exceed that of their monolithic counterpart by ∼33% and ∼19.1 folds, respectively. Generally, the presented microfluidic method provides a unique technique for the assembly of interlocked architecture, which facilitates the design and fabrication of TIMs with highly improved strength and toughness