Fundamental Properties and Durability of Concrete with Gasification Molten Slag as Fine Aggregate

The proportion of electricity generated by coal-fired thermal power plants has been rising in Japan as a result of the nuclear plant accident caused by the Great East Japan Earthquake of 2011. Coal-fired electricity generation has a large environment impact, so the commercial application of integrated coal gasification combined cycle (IGCC) has been promoted. IGCC is an efficient generating method combining a steam turbine and a gas turbine. However, IGCC plants generate coal gasification molten slag (CGMS) and it is necessary to establish effective utilization methods for this slag for further promotion of IGCC technology. In this paper, the fresh properties, hardened properties and durability of concrete containing CGMS as fine aggregate are investigated. The results show that, in comparison with concrete using conventional fine aggregate, the air content introduced by an air-entraining agent is lower and bleeding is increased when CGMS is used as a fine aggregate. As for the hardened properties, compressive strength is slightly lower, while freeze-thaw resistance is significantly reduced. In additional tests, it is found possible to improve freeze-thaw resistance by increasing the air conten

Ionization and electron excitation of C60 in a carbon nanotube: A variable temperature/voltage transmission electron microscopic study

SignificanceThe destruction of specimen molecules by an electron beam (e-beam) is either beneficial, as in mass spectrometry capitalizing on ion formation, or deleterious, as in electron microscopy. In the latter application, the e-beam not only produces the specimen image, but also causes information loss upon prolonged irradiation. However, the atomistic mechanism of such loss has been unclear. Performing single-molecule kinetic analysis of C60 dimerization in a carbon nanotube (CNT) under variable-temperature/voltage conditions, we identified three reactive species-that is, radical cation, singlet, and triplet excited states-reacting competitively as the voltage and the properties of the CNT were changed. The key enabler was in situ continuous recording of the whole reaction process, suggesting an upcoming new era of "cinematic chemistry."11Nsciescopu

Direct Microscopic Analysis of Individual C₆₀ Dimerization Events: Kinetics and Mechanisms

Modern transition state theory states that the statistical behavior of a chemical reaction is the sum of individual chemical events that occur randomly. Statistical analysis of each event for individual molecules in a three-dimensional space however is practically impossible. We report here that kinetics and mechanisms of chemical reactions can be investigated by using a one-dimensional system where reaction events can be observed in situ and counted one by one using variable-temperature (VT) atomic-resolution transmission electron microscopy (TEM). We thereby provide direct proof that the ensemble behavior of random events conforms to the Rice–Ramsperger–Kassel–Marcus theory, as illustrated for [2 + 2] cycloaddition of C₆₀ molecules in carbon nanotubes (CNTs). This method gives kinetic and structural information for different types of reactions occurring simultaneously in the microscopic view field, suggesting that the VT-TEM opens a new dimension of chemical kinetics research on molecules and their assemblies in their excited and ionized states. The study carried out at 393–493 K showed that pristine CNT primarily acts as a singlet sensitizer of the cycloaddition reaction that takes place with an activation energy of 33.5 ± 6.8 kJ/mol. On the other hand, CNT suffers electron damage of the conjugated system at 103–203 K and promotes a reactive radical cation path that takes place with an activation energy of only 1.9 ± 0.7 kJ/mol. The pre-exponential factor of the Arrhenius plot gave us further mechanistic insights

Direct Microscopic Analysis of Individual C₆₀ Dimerization Events: Kinetics and Mechanisms

Modern transition state theory states that the statistical behavior of a chemical reaction is the sum of individual chemical events that occur randomly. Statistical analysis of each event for individual molecules in a three-dimensional space however is practically impossible. We report here that kinetics and mechanisms of chemical reactions can be investigated by using a one-dimensional system where reaction events can be observed in situ and counted one by one using variable-temperature (VT) atomic-resolution transmission electron microscopy (TEM). We thereby provide direct proof that the ensemble behavior of random events conforms to the Rice–Ramsperger–Kassel–Marcus theory, as illustrated for [2 + 2] cycloaddition of C₆₀ molecules in carbon nanotubes (CNTs). This method gives kinetic and structural information for different types of reactions occurring simultaneously in the microscopic view field, suggesting that the VT-TEM opens a new dimension of chemical kinetics research on molecules and their assemblies in their excited and ionized states. The study carried out at 393–493 K showed that pristine CNT primarily acts as a singlet sensitizer of the cycloaddition reaction that takes place with an activation energy of 33.5 ± 6.8 kJ/mol. On the other hand, CNT suffers electron damage of the conjugated system at 103–203 K and promotes a reactive radical cation path that takes place with an activation energy of only 1.9 ± 0.7 kJ/mol. The pre-exponential factor of the Arrhenius plot gave us further mechanistic insights

Direct Microscopic Analysis of Individual C₆₀ Dimerization Events: Kinetics and Mechanisms

Modern transition state theory states that the statistical behavior of a chemical reaction is the sum of individual chemical events that occur randomly. Statistical analysis of each event for individual molecules in a three-dimensional space however is practically impossible. We report here that kinetics and mechanisms of chemical reactions can be investigated by using a one-dimensional system where reaction events can be observed in situ and counted one by one using variable-temperature (VT) atomic-resolution transmission electron microscopy (TEM). We thereby provide direct proof that the ensemble behavior of random events conforms to the Rice–Ramsperger–Kassel–Marcus theory, as illustrated for [2 + 2] cycloaddition of C₆₀ molecules in carbon nanotubes (CNTs). This method gives kinetic and structural information for different types of reactions occurring simultaneously in the microscopic view field, suggesting that the VT-TEM opens a new dimension of chemical kinetics research on molecules and their assemblies in their excited and ionized states. The study carried out at 393–493 K showed that pristine CNT primarily acts as a singlet sensitizer of the cycloaddition reaction that takes place with an activation energy of 33.5 ± 6.8 kJ/mol. On the other hand, CNT suffers electron damage of the conjugated system at 103–203 K and promotes a reactive radical cation path that takes place with an activation energy of only 1.9 ± 0.7 kJ/mol. The pre-exponential factor of the Arrhenius plot gave us further mechanistic insights