Electrode Potentials Part 1: Fundamentals and Aqueous Systems

Electrochemistry deals with the interrelationship between electrical and chemical energy. Various potentials appear in electrochemistry and pertain to one another in practical cells. Understanding the electrode potential is an important step in acquiring basic knowledge of electrochemistry and extending it to specific applications. This comprehensive paper outlines the fundamentals and related subjects of electrode potentials, including electrochemical cells and liquid junction potentials. Aqueous solution systems are ideal for connecting the theoretical background of electrode potentials to practical electrochemical measurements. Accordingly, the basic electrode chemistry in aqueous systems is described in this paper, as well as several advanced concepts introduced in recent studies

Lubrication Tests to Support Optimal Performance Design Guidelines for Thrust Slide-Bearings in Scroll Compressors

This study focuses on the role of lubrication in the optimal performance design guidelines for the thrust slide-bearings in scroll compressors. The theoretical analysis of Ishii et al. showed that the minimum friction power loss in the thrust slide-bearing occurs at a certain outer radius of the friction surface. In the theoretical development, the physical thrust slide-bearing was modeled as a cylindrical thrust plate, representing the orbiting scroll, and the flat plate, representing the fixed scroll, with the same friction area as the physical bearing. The outer radius of the friction surface was varied for a fixed inner radius, where the fluid wedge angle between the sliding surfaces, due to axial loading on the thrust plate, was assumed to be constant at a small value. The average Reynolds equation by Patier & Cheng and the solid contact theory by Greenwood & Williamson were applied to calculate the resultant lubrication performance and finally the friction power loss at the sliding surface. The model showed that the friction power loss drastically decreases and then gradually increases, with increasing outer radius of the sliding surface.  The minimum value of friction power loss was about 80% lower than that of the conventional design thrust slide-bering. In order to confirm experimentally this predicted optimal lubrication performance, a thrust slide-bearing cylindrical-model submerged in a refrigerant oil SUNISO-RB68A was operated under pressurized conditions using R410A as the pressurizing gas. The pressure difference across the friction surface of the thrust bearing was fixed at 0.6 MPa, corresponding to the rated operation condition of a small cooling capacity scroll compressor. In the experiments, a special device was fabricated to maintain a constant fluid wedge angle between the friction surfaces due to the net pressure-induced elastic deformation of the thrust plate. The friction power loss at the friction surface was measured over a wide range of orbiting speeds from 1200 rpm up to 6000 rpm for a fixed orbiting radius of 3.0 mm. The resulting measured data exhibited showed the predicted tendency that the lubrication of the thrust slide-bearing is substabtially by increasing the outer radius. The friction power loss decreased with increasing outer-to-inner radii ratio of friction surface. The minimum loss occurred at an outer-to-inner radii ratio of about 2.1 for an operating speed of 3600 rpm, a significant 80% reduction relative to the usual conventional design ratio

Unique Li deposition behavior in Li₃PS₄ solid electrolyte observed via operando X-ray computed tomography

The problem of lithium dendrites must be addressed for practical lithium metal all-solid-state batteries. Herein, three-dimensional morphological changes within Li₃PS₄ electrolyte away from the anode were observed using operando X-ray computed tomography. We revealed that the electronic conduction of decomposition and the electrolyte/void interface cause the lithium deposition within the Li₃PS₄

A reversible oxygen redox reaction in bulk-type all-solid-state batteries

An all-solid-state lithium battery using inorganic solid electrolytes requires safety assurance and improved energy density, both of which are issues in large-scale applications of lithium-ion batteries. Utilization of high-capacity lithium-excess electrode materials is effective for the further increase in energy density. However, they have never been applied to all-solid-state batteries. Operational difficulty of all-solid-state batteries using them generally lies in the construction of the electrode-electrolyte interface. By the amorphization of Li₂RuO₃ as a lithium-excess model material with Li₂SO₄, here, we have first demonstrated a reversible oxygen redox reaction in all-solid-state batteries. Amorphous nature of the Li₂RuO₃-Li₂SO₄ matrix enables inclusion of active material with high conductivity and ductility for achieving favorable interfaces with charge transfer capabilities, leading to the stable operation of all-solid-state batteries

Angular correlation of the two gamma rays produced in the thermal neutron capture on gadolinium-155 and gadolinium-157

The ANNRI-Gd collaboration studied in detail the single $\gamma$-ray spectrum produced from the thermal neutron capture on $^{155}$Gd and $^{157}$Gd in our previous publications. Gadolinium targets were exposed to a neutron beam provided by the Japan Spallation Neutron Source (JSNS) in J-PARC, Japan. In the present analysis, one new additional coaxial germanium crystal was used in the analysis in combination with the fourteen germanium crystals in the cluster detectors to study the angular correlation of the two $\gamma$ rays emitted in the same neutron capture. We present for the first time angular correlation functions for two $\gamma$ rays produced during the electromagnetic cascade transitions in the (n, $\gamma$) reactions on $^{\rm 155}$Gd and $^{\rm 157}$Gd. As expected, we observe the mild angular correlations for the strong, but rare transitions from the resonance state to the two energy levels of known spin-parities. Contrariwise, we observe negligibly small angular correlations for arbitrary pairs of two $\gamma$ rays produced in the majority of cascade transitions from the resonance state to the dense continuum states.Comment: 21 pages, 13 figure

Gamma Ray Spectra from Thermal Neutron Capture on Gadolinium-155 and Natural Gadolinium

Abstract Natural gadolinium is widely used for its excellent thermal neutron capture cross section, because of its two major isotopes: $^{\rm 155}$Gd and $^{\rm 157}$Gd. We measured the $\gamma$-ray spectra produced from the thermal neutron capture on targets comprising a natural gadolinium film and enriched $^{\rm 155}$Gd (in Gd$_{2}$O$_{3}$ powder) in the energy range from 0.11 MeV to 8.0 MeV, using the ANNRI germanium spectrometer at MLF, J-PARC. The freshly analyzed data of the $^{\rm 155}$Gd($n, \gamma$) reaction are used to improve our previously developed model (ANNRI-Gd model) for the $^{\rm 157}$Gd($n, \gamma$) reaction [K. Hagiwara et al. [ANNRI-Gd Collaboration], Prog. Theor. Exp. Phys. 2019, 023D01 (2019)], and its performance confirmed with the independent data from the $^{\rm nat}$Gd($n, \gamma$) reaction. This article completes the development of an efficient Monte Carlo model required to simulate and analyze particle interactions involving the thermal neutron captures on gadolinium in any relevant future experiments

Observation of the acceleration of a single bunch by using the induction device in the kek proton synchrotron

A single rf bunch in the KEK proton synchrotron was accelerated with an induction acceleration method from the injection energy of 500 MeV to 5 GeV.</p