123,796 research outputs found
Light-Driven Hydrogen Production from Aqueous Solutions Based on a New Dubois-Type Nickel Catalyst
In this work, we report a new photocatalytic system that links multifunctional semiconductor nanocrystals with emerging water-soluble molecular catalysts made of earth-abundant elements for H2 generation [Ni(P2RN2R′)2(BF4)2]4−, R = Ph, R′ = [PhSO3]− (NiS). This noble metal free hybrid exhibits remarkable catalytic activity with a turnover number of 511 for H2 production and a photon-to-H2 conversion efficiency of 12.5%. The mechanistic insight into such high efficiency in this photocatalytic system was examined using a combination of steady-state emission and time-resolved absorption spectroscopy
Scaling of nuclear modification factors for hadrons and light nuclei
The number of constituent quarks (NCQ-) scaling of hadrons and the number of
constituent nucleons (NCN-) scaling of light nuclei are proposed for nuclear
modification factors () of hadrons and light nuclei, respectively,
according to the experimental investigations in relativistic heavy-ion
collisions. Based on coalescence mechanism the scalings are performed for pions
and protons in quark level, and light nuclei and He for
nucleonic level, respectively, formed in Au + Au and Pb + Pb collisions and
nice scaling behaviour emerges. NCQ or NCN scaling law of can be
respectively taken as a probe for quark or nucleon coalescence mechanism for
the formation of hadron or light nuclei in relativistic heavy-ion collisions.Comment: 6 pages, 6 figure
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