383 research outputs found

    Properties of KCo2_2As2_2 and Alloys with Fe and Ru: Density Functional Calculations

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    Electronic structure calculations are presented for KCo2_2As2_2 and alloys with KFe2_2As2_2 and KRu2_2As2_2. These materials show electronic structures characteristic of coherent alloys, with a similar Fermi surface structure to that of the Fe-based superconductors, when the dd electron count is near six per transition metal. However, they are less magnetic than the corresponding Fe compounds. These results are discussed in relation to superconductivity.Comment: 5 page

    Superconductivity at 22 K in Co-doped BaFe2As2 Crystals

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    Here we report bulk superconductivity in BaFe1.8Co0.2As2 single crystals below Tc = 22 K, as demonstrated by resistivity, magnetic susceptibility, and specific heat data. Hall data indicate that the dominant carriers are electrons, as expected from simple chemical reasoning. This is the first example of superconductivity induced by electron doping in this family of materials. In contrast to the cuprates, the BaFe2As2 system appears to tolerate considerable disorder in the FeAs planes. First principles calculations for BaFe1.8Co0.2As2 indicate the inter-band scattering due to Co is weak.Comment: 9 pages, 3 figure

    Raman scattering study of electron-doped Prx_xCa1−x_{1-x}Fe2_2As2_2 superconductors

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    Temperature-dependent polarized Raman spectra of electron-doped superconducting Prx_xCa1−x_{1-x}Fe2_2As2_2 (x≈0.12x \approx 0.12) single crystals are reported. All four allowed by symmetry even-parity phonons are identified. Phonon mode of B1g_{1g} symmetry at 222 cm−1^{-1}, which is associated with the c-axis motion of Fe ions, is found to exhibit an anomalous frequency hardening at low temperatures, that signals non-vanishing electron-phonon coupling in the superconducting state and implies that the superconducting gap magnitude 2Δc<272\Delta_c < 27meV.Comment: 4 pages, 3 figure

    Raman scattering study of (Kx_xSr1−x_{1-x})Fe2_2As2_2 (xx = 0.0, 0.4)

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    Polarized Raman spectra of non-superconducting SrFe2_2As2_2 and superconducting K0.4_{0.4}Sr0.6_{0.6}Fe2_2As2_2 (Tc=37T_c = 37 K) are reported. All four phonon modes (A1g_{1g} + B1g_{1g} + 2Eg_g) allowed by symmetry, are found and identified. Shell model gives reasonable description of the spectra. No detectable anomalies are observed near the tetragonal-to-orthorhombic transition in SrFe2_2As2_2 or the superconducting transition in K0.4_{0.4}Sr0.6_{0.6}Fe2_2As2_2.Comment: 4 pages, 4 figures, 2 table

    BaT2As2 Single Crystals (T = Fe, Co, Ni) and Superconductivity upon Co-doping

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    The crystal structure and physical properties of BaFe2As2, BaCo2As2, and BaNi2As2 single crystals are surveyed. BaFe2As2 gives a magnetic and structural transition at TN = 132(1) K, BaCo2As2 is a paramagnetic metal, while BaNi2As2 has a structural phase transition at T0 = 131 K, followed by superconductivity below Tc = 0.69 K. The bulk superconductivity in Co-doped BaFe2As2 below Tc = 22 K is demonstrated by resistivity, magnetic susceptibility, and specific heat data. In contrast to the cuprates, the Fe-based system appears to tolerate considerable disorder in the transition metal layers. First principles calculations for BaFe1.84Co0.16As2 indicate the inter-band scattering due to Co is weak.Comment: Accepted to Physica

    Response Mixture Modeling of Intraindividual Differences in Responses and Response Times to the Hungarian WISC-IV Block Design Test

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    Response times may constitute an important additional source of information about cognitive ability as it enables to distinguishing between different intraindividual response processes. In this paper, we present a method to disentangle interindividual variation from intraindividual variation in the responses and response times of 978 subjects to the 14 items of the Hungarian WISC-IV Block Design test. It is found that faster and slower responses differ in their measurement properties suggesting that there are intraindivual differences in the response processes adopted by the subjects

    Acousto-optical Scanning-Based High-Speed 3D Two-Photon Imaging In Vivo.

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    Recording of the concerted activity of neuronal assemblies and the dendritic and axonal signal integration of downstream neurons pose different challenges, preferably a single recording system should perform both operations. We present a three-dimensional (3D), high-resolution, fast, acousto-optic two-photon microscope with random-access and continuous trajectory scanning modes reaching a cubic millimeter scan range (now over 950 × 950 × 3000 μm3) which can be adapted to imaging different spatial scales. The resolution of the system allows simultaneous functional measurements in many fine neuronal processes, even in dendritic spines within a central core (>290 × 290 × 200 μm3) of the total scanned volume. Furthermore, the PSF size remained sufficiently low (PSFx < 1.9 μm, PSFz < 7.9 μm) to target individual neuronal somata in the whole scanning volume for simultaneous measurement of activity from hundreds of cells. The system contains new design concepts: it allows the acoustic frequency chirps in the deflectors to be adjusted dynamically to compensate for astigmatism and optical errors; it physically separates the z-dimension focusing and lateral scanning functions to optimize the lateral AO scanning range; it involves a custom angular compensation unit to diminish off-axis angular dispersion introduced by the AO deflectors, and it uses a high-NA, wide-field objective and high-bandwidth custom AO deflectors with large apertures. We demonstrate the use of the microscope at different spatial scales by first showing 3D optical recordings of action potential back propagation and dendritic Ca2+ spike forward propagation in long dendritic segments in vitro, at near-microsecond temporal resolution. Second, using the same microscope we show volumetric random-access Ca2+ imaging of spontaneous and visual stimulation-evoked activity from hundreds of cortical neurons in the visual cortex in vivo. The selection of active neurons in a volume that respond to a given stimulus was aided by the real-time data analysis and the 3D interactive visualization accelerated selection of regions of interest

    Superconductivity at 38 K in the iron arsenide (Ba1-xKx)Fe2As2

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    The ternary iron arsenide BaFe2As2 becomes superconducting by hole doping, which was achieved by partial substitution of the barium site with potassium. We have discovered bulk superconductivity up to Tc = 38 K in (Ba1-xKx)Fe2As2 with x = 0.4. The parent compound BaFe2As2 as well as KFe2As2 both crystallize in the tetragonal ThCr2Si2-type structure, which consists of (FeAs)- iron arsenide layers separated by barium or potassium ions. BaFe2As2 is a poor metal and exhibits a SDW anomaly at 140 K. By substituting Ba2+ for K+ ions we have introduced holes in the (FeAs)- layers, which suppress the SDW anomaly and induce superconductivity. This scenario is very similar to the recently discovered arsenide-oxide superconductors. The Tc of 38 K in (Ba1-xKx)Fe2As2 is the highest observed critical temperature in hole doped iron arsenide superconductors so far. Therefore, we were able to expand this class of superconductors by oxygen-free compounds with the ThCr2Si2-type structure. Our results suggest, that superconductivity in these systems essentially evolves from the (FeAs)- layers and may occur in other related compounds.Comment: 4 pages, 5 figures, submitted to Phys. Rev. Let
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