Detecting mixedness of qutrit systems using the uncertainty relation

We show that the uncertainty relation as expressed in the Robertson-Schrodinger generalized form can be used to detect the mixedness of three-level quantum systems in terms of measureable expectation values of suitably chosen observables when prior knowledge about the basis of the given state is known. In particular, we demonstrate the existence of observables for which the generalized uncertainty relation is satisfied as an equality for pure states and a strict inequality for mixed states corresponding to single as well as bipartite sytems of qutrits. Examples of such observables are found for which the magnitude of uncertainty is proportional to the linear entropy of the system, thereby providing a method for measuring mixedness.Comment: 7 pages, 2 figure, Eqs.(10) and (14) are corrected, and results and conclusions are unchange

First principles investigation of finite-temperature behavior in small sodium clusters

A systematic and detailed investigation of the finite-temperature behavior of small sodium clusters, Na_n, in the size range of n= 8 to 50 are carried out. The simulations are performed using density-functional molecular-dynamics with ultrasoft pseudopotentials. A number of thermodynamic indicators such as specific heat, caloric curve, root-mean-square bond length fluctuation, deviation energy, etc. are calculated for each of the clusters. Size dependence of these indicators reveals several interesting features. The smallest clusters with n= 8 and 10, do not show any signature of melting transition. With the increase in size, broad peak in the specific heat is developed, which alternately for larger clusters evolves into a sharper one, indicating a solidlike to liquidlike transition. The melting temperatures show irregular pattern similar to experimentally observed one for larger clusters [ M. Schmidt et al., Nature (London) 393, 238 (1998) ]. The present calculations also reveal a remarkable size-sensitive effect in the size range of n= 40 to 55. While Na_40 and Na_55 show well developed peaks in the specific heat curve, Na_50 cluster exhibits a rather broad peak, indicating a poorly-defined melting transition. Such a feature has been experimentally observed for gallium and aluminum clusters [ G. A. Breaux et al., J. Am. Chem. Soc. 126, 8628 (2004); G. A.Breaux et al., Phys. Rev. Lett. 94, 173401 (2005) ].Comment: 8 pages, 11 figure