4,220 research outputs found
Group theory for structural analysis and lattice vibrations in phosphorene systems
Group theory analysis for two-dimensional elemental systems related to
phosphorene is presented, including (i) graphene, silicene, germanene and
stanene, (ii) dependence on the number of layers and (iii) two stacking
arrangements. Departing from the most symmetric graphene space
group, the structures are found to have a group-subgroup relation, and analysis
of the irreducible representations of their lattice vibrations makes it
possible to distinguish between the different allotropes. The analysis can be
used to study the effect of strain, to understand structural phase transitions,
to characterize the number of layers, crystallographic orientation and
nonlinear phenomena.Comment: 24 pages, 3 figure
Modelling and analysis of time dependent processes in a chemically reactive mixture
In this paper, we study the propagation of sound waves and the dynamics of local wave disturbances
induced by spontaneous internal fluctuations in a reactive mixture. We consider a non-diffusive, non-heat
conducting and non-viscous mixture described by an Eulerian set of evolution equations. The model is derived from the kinetic theory in a hydrodynamic regime of a fast chemical reaction. The reactive source terms are explicitly computed from the kinetic theory and are built in themodel in a proper way. For both time-dependent problems, we first derive the appropriate dispersion relation, which retains the main effects of the chemical process, and then investigate the influence of the chemical reaction on the properties of interest in the problems studied here. We complete our study by developing a rather detailed analysis using the Hydrogen–Chlorine system as reference. Several numerical computations are included illustrating the behavior of the phase velocity and attenuation coefficient in a low-frequency regime and describing the spectrum of the eigenmodes in the small wavenumber limit.The paper is partially supported by the Research Centre of Mathematics of the University of Minho, with the Portuguese Funds from the Foundation for Science and Technology (FCT) through the Project UID/MAT/00013/2013. We wish to thank the anonymous Referees for their valuable comments and suggestions that helped us to improve the paper.info:eu-repo/semantics/publishedVersio
Group Theory analysis of phonons in two-dimensional Transition Metal Dichalcogenides
Transition metal dichalcogenides (TMDCs) have emerged as a new two
dimensional materials field since the monolayer and few-layer limits show
different properties when compared to each other and to their respective bulk
materials. For example, in some cases when the bulk material is exfoliated down
to a monolayer, an indirect-to-direct band gap in the visible range is
observed. The number of layers ( even or odd) drives changes in space
group symmetry that are reflected in the optical properties. The understanding
of the space group symmetry as a function of the number of layers is therefore
important for the correct interpretation of the experimental data. Here we
present a thorough group theory study of the symmetry aspects relevant to
optical and spectroscopic analysis, for the most common polytypes of TMDCs,
i.e. , and , as a function of the number of layers. Real space
symmetries, the group of the wave vectors, the relevance of inversion symmetry,
irreducible representations of the vibrational modes, optical selection rules
and Raman tensors are discussed.Comment: 32 pages, 4 figure
Procedure for Sr and Nd isotope analysis in the terrigenous component of marine sediments
Neste trabalho, apresenta-se um protocolo analítico para a obtenção das razões isotópicas 87Sr/86Sr e 143Nd/144Nd na fracção detrítica de sedimentos marinhos. Dado ser comum estes materiais apresentarem uma fracção biogénica carbonatada significativa, foram testadas diversas metodologias com o objectivo de extrair selectivamente os carbonatos sem comprometer a composição da componente terrígena. O ataque com ácido acético 5N durante 12h, à temperatura ambiente, revelou ser eficaz na remoção dos carbonatos e, simultaneamente, preservar fases detríticas que incorporam concentrações significativas de lantanídeos. A aplicabilidade do protocolo desenvolvido é ilustrado com a análise isotópica de amostras de um core colhido no talude continental da Galiza. Os resultados obtidos, em ambos os sistemas de decaimento radioactivo, para além de serem consistentes com a assinatura isotópica de materiais resultantes da erosão de crosta continental, também permitem detectar, através do decréscimo dos valores de εNd em determinados níveis do core, alguns episódios (eventos de Heinrich) em que a fonte crustal terá sido bastante diferente da habitual.In this paper, an experimental procedure for measuring 87Sr/86Sr and 143Nd/144Nd ratios in the detrital fraction of marine sediments is presented. Since these sediments commonly include a significant biogenic carbonate fraction, several methodologies were tested in order to leach the carbonates without compromising the composition of the terrigenous component. The extraction with 5N acetic acid for 12 hours, at room temperature, reveals (a) to be effective in the removal of carbonates, and (b) to preserve detrital phases that incorporate important amounts of REE. The applicability of this chemical procedure is illustrated with analyses done on samples from a core collected in the Galician continental slope. The results for both radiogenic decay systems, on one hand, are consistent with the isotope signature of material resulting from the erosion of continental crust and, one the other hand, allow the identification of several episodes of modification of the source areas involved
Informações meteorológicas para pesquisa e planejamento agrícola, referentes ao município de Santo Antonio de Goiás, GO, 2007.
Os dados meteorológicos aqui apresentados, permitirão aos usuários do setor agrícola, obter informações sobre as variações dos elementos climáticos do município de Santo Antônio de Goiás, GO, a partir de observações contínuas das variáveis climáticas.bitstream/CNPAF-2009-09/27607/1/doc_221.pd
- …