Implikasi Putusan Mahkamah Konstitusi Nomor 11-017/puu-i/2003 terhadap Perlindungan Hukum Hak Dipilih

Paper that had the title: "Juridical implications of the Constitutional Court Decision Number 011-017/PUU-I/2003 on the Legal Protection for the Rights to be Eelected." This explores two issues: 1) how the legal protection of the settings selected in the state system of Indonesia ; 2) what are juridical implications of the Constitutional Court Decision Number 011-017/PUU-I/2003 on the legal protection for the rights to be elected. To solve both problems, this paper uses normative legal research methods. Approach being used is the statute approach, case approach, and a conceptual approach. Further legal materials collected were identified and analyzed using descriptive analysis techniques. Legal protection for the right to be elected in the state system of Indonesia can be traced from the 1945 opening, the articles in the body of the 1945 Constitution, Article 27 paragraph (1), Article 28D (1) and paragraph (3) and Article 28 paragraph (3) 1945 Second Amendment, MPR Decree Number XVII/MPR/1998, Article 43 of Law Number 39 of 1999, Article 21 of the Universal Declaration of Human Rights, and Article 25 of the International Covenant on Civil and Political Rights. Discussion of the juridical implications of the Constitutional Court Decision Number 011-017/PUU-I/2003 on the legal protection for the rights to be elected have been included: a) only on the juridical implications of representative institutions no longer marked with specified requirements as stipulated in Article 60 letter g of Law Number 12 Year 2003 in Law Number 10 Year 2008; b) juridical implications of the political field for the right to be elected is the absence of any discriminatory treatment in legislative product formed by the House of Representatives and the President as well as products of other legislation forward

Revisiting the Chemistry of Phosphinidene Sulfides

The reaction of triethylamine with the [4 + 2] cycloadducts of phosphole sulfides and 3-bromo-<i>N</i>-phenyl­maleimide provides a convenient access to phosphinidene sulfides [RPS]. These transient species are trapped by 2,3-dimethyl-1,3-butadiene to give the previously unknown trivalent [4 + 2] cycloadducts. One of these (R = Ph) has been characterized as its P-W­(CO)₅ complex by X-ray crystal structure analysis. With cyclopentadiene, the subsequent insertion of a second molecule of [RPS] leads to a new type of bicyclic product containing a thia­diphos­pholane ring

Oxidative Addition across Sb–H and Sb–Sb Bonds by an Osmium Carbonyl Cluster: Trapping the Intermediate

The cluster Os₃(CO)₁₁(NCCH₃) oxidatively adds across the Sb–H bond in SbPh₂H to afford the clusters Os₃(CO)₁₁(H)­(μ-SbPh₂) and Os₃(CO)₁₁(μ-H)­(μ-SbPh₂)­Os₃(CO)₁₁. Similarly, its reaction with Sb₂Ph₄ afforded Os₃(CO)₁₁(μ-SbPh₂)₂Os₃(CO)₁₁ as the major product. In both cases, the intermediate from the oxidative addition reaction was trapped as a W­(CO)₅ adduct

Binuclear Oxidative Addition of Sb–Cl Bonds: A Facile Synthetic Route to Main Group–Transition Element Clusters and Rings

Binuclear oxidative addition of Sb–Cl bonds with the clusters Os₃(CO)₁₁(NCCH₃), <b>1</b>, or Os₃(CO)₁₀(NCCH₃)₂, <b>2</b>, was found to be an effective synthetic route to organometallic clusters and rings containing μ₂-SbPh₂ or μ₃-SbPh moieties. Thus, the reaction of SbPh₂Cl with <b>1</b> afforded the tetranuclear ring Os₃(CO)₁₁(Cl)­(μ-SbPh₂), <b>3</b>, while its reaction with <b>2</b> afforded the pentanuclear ring Os₃(CO)₁₀(Cl)₂(μ-SbPh₂)₂, <b>6</b>. In each case, two or three isomeric products were isolated depending on the reaction conditions. The analogous reaction of SbPhCl₂ with <b>1</b>, on the other hand, afforded the spiked triangular cluster Os₃(CO)₁₁(Cl)₂(μ₃-SbPh), <b>7</b>, which also existed as two isomers. Pathways for these reactions have been proposed, and the experimental and computational evidence presented

Alkene–Carbene Isomerization induced by Borane: Access to an Asymmetrical Diborene

A 2,3-dihydro-1<i>H</i>-1,2-azaborole derivative <b>2</b> was converted to a cyclic (alkyl) (amino)­carbene (cAAC) via 1,2-hydrogen migration triggered by boranes to afford cAAC-borane adducts. This procedure allowed us to develop an asymmetrical diborene cAAC·(Br)­BB­(Br)·IDip <b>6</b>, which was isolated and fully characterized. The ¹¹B NMR spectrum, X-ray diffraction analysis and computational studies indicate that π-electrons on the central B₂ moiety in <b>6</b> are unequivalently distributed, and thus polarized. A complete scission of the BB double bond in <b>6</b> was achieved by the treatment with an isonitrile, which led to the formation of a base-stabilized B,N-containing methylenecyclopropane <b>7</b>

Generation and Reactivity of Methylphosphaketene in the Coordination Sphere of Tungsten

The [4 + 2] cycloadduct between the 1-methyl-2-keto-1,2-dihydrophosphinine pentacarbonyltungsten complex and dimethyl acetylenedicarboxylate can be used as a precursor for the methylphosphaketene tungsten complex under UV irradiation at room temperature. Under these conditions, the phosphaketene complex easily loses CO to give the methylphosphinidene complex. Highly reactive alcohols and primary alkylamines trap both the phosphaketene and the phosphinidene complexes. Less reactive phenol and bulky amines together with alkynes and conjugated dienes only trap the phosphinidene complex

Binuclear Oxidative Addition of Sb–Cl Bonds: A Facile Synthetic Route to Main Group–Transition Element Clusters and Rings

Binuclear oxidative addition of Sb–Cl bonds with the clusters Os₃(CO)₁₁(NCCH₃), <b>1</b>, or Os₃(CO)₁₀(NCCH₃)₂, <b>2</b>, was found to be an effective synthetic route to organometallic clusters and rings containing μ₂-SbPh₂ or μ₃-SbPh moieties. Thus, the reaction of SbPh₂Cl with <b>1</b> afforded the tetranuclear ring Os₃(CO)₁₁(Cl)­(μ-SbPh₂), <b>3</b>, while its reaction with <b>2</b> afforded the pentanuclear ring Os₃(CO)₁₀(Cl)₂(μ-SbPh₂)₂, <b>6</b>. In each case, two or three isomeric products were isolated depending on the reaction conditions. The analogous reaction of SbPhCl₂ with <b>1</b>, on the other hand, afforded the spiked triangular cluster Os₃(CO)₁₁(Cl)₂(μ₃-SbPh), <b>7</b>, which also existed as two isomers. Pathways for these reactions have been proposed, and the experimental and computational evidence presented

A New Type of Phosphaferrocene–Pyrrole–Phosphaferrocene P-N-P Pincer Ligand

A 2-ethoxycarbonylphosphaferrocene was reduced to the corresponding 2-hydroxymethyl derivative, which was condensed with pyrrole in a 2:1 ratio in the presence of BF₃ to give a phosphaferrocene–pyrrole–phosphaferrocene pincer ligand. This tridentate ligand, in turn, reacted with [Rh­(acac)­(CO)₂] to yield a rhodium carbonyl pincer complex. This complex was characterized by X-ray crystal structure analysis and tested in the hydroformylation of internal olefins

A New Type of Phosphaferrocene–Pyrrole–Phosphaferrocene P-N-P Pincer Ligand

A 2-ethoxycarbonylphosphaferrocene was reduced to the corresponding 2-hydroxymethyl derivative, which was condensed with pyrrole in a 2:1 ratio in the presence of BF₃ to give a phosphaferrocene–pyrrole–phosphaferrocene pincer ligand. This tridentate ligand, in turn, reacted with [Rh­(acac)­(CO)₂] to yield a rhodium carbonyl pincer complex. This complex was characterized by X-ray crystal structure analysis and tested in the hydroformylation of internal olefins

A New Type of Phosphaferrocene–Pyrrole–Phosphaferrocene P-N-P Pincer Ligand

A 2-ethoxycarbonylphosphaferrocene was reduced to the corresponding 2-hydroxymethyl derivative, which was condensed with pyrrole in a 2:1 ratio in the presence of BF₃ to give a phosphaferrocene–pyrrole–phosphaferrocene pincer ligand. This tridentate ligand, in turn, reacted with [Rh­(acac)­(CO)₂] to yield a rhodium carbonyl pincer complex. This complex was characterized by X-ray crystal structure analysis and tested in the hydroformylation of internal olefins