2 research outputs found
sj-docx-1-pie-10.1177_09544089221124226 - Supplemental material for Synthesis of Al<sub>2</sub>O<sub>3</sub>/SiO<sub>2</sub> core鈥搒hell composite abrasives toward ultrasmooth and high-efficiency polishing for sapphire wafers
Supplemental material, sj-docx-1-pie-10.1177_09544089221124226 for Synthesis of Al2O3/SiO2 core鈥搒hell composite abrasives toward ultrasmooth and high-efficiency polishing for sapphire wafers by Yongchao Xu, Guangen Zhao, Qianting Wang and
Youji Zhan, Bingsan Chen in Proceedings of the Institution of Mechanical Engineers, Part E: Journal of Process Mechanical Engineering</p
Isoreticular Contraction of Cage-like Metal鈥揙rganic Frameworks with Optimized Pore Space for Enhanced C<sub>2</sub>H<sub>2</sub>/CO<sub>2</sub> and C<sub>2</sub>H<sub>2</sub>/C<sub>2</sub>H<sub>4</sub> Separations
The C2H2 separation from CO2 and
C2H4 is of great importance yet highly challenging
in the petrochemical industry, owing to their similar physical and
chemical properties. Herein, the pore nanospace engineering of cage-like
mixed-ligand MFOF-1 has been accomplished via contracting the size
of the pyridine- and carboxylic acid-functionalized linkers and introducing
a fluoride- and sulfate-bridging cobalt cluster, based on a reticular
chemistry strategy. Compared with the prototypical MFOF-1, the constructed
FJUT-1 with the same topology presents significantly improved C2H2 adsorption capacity, and selective C2H2 separation performance due to the reduced cage cavity
size, functionalized pore surface, and appropriate pore volume. The
introduction of fluoride- and sulfate-bridging cubane-type tetranuclear
cobalt clusters bestows FJUT-1 with exceptional chemical stability
under harsh conditions while providing multiple potential C2H2 binding sites, thus rendering the adequate ability
for practical C2H2 separation application as
confirmed by the dynamic breakthrough experiments under dry and humid
conditions. Additionally, the distinct binding mechanism is suggested
by theoretical calculations in which the multiple supramolecular interactions
involving C鈥揌路路路O, C鈥揌路路路F,
and other van der Waals forces play a critical role in the selective
C2H2 separation