An interactive computer code for calculation of gas-phase chemical equilibrium (EQLBRM)

A user friendly, menu driven, interactive computer program known as EQLBRM which calculates the adiabatic equilibrium temperature and product composition resulting from the combustion of hydrocarbon fuels with air, at specified constant pressure and enthalpy is discussed. The program is developed primarily as an instructional tool to be run on small computers to allow the user to economically and efficiency explore the effects of varying fuel type, air/fuel ratio, inlet air and/or fuel temperature, and operating pressure on the performance of continuous combustion devices such as gas turbine combustors, Stirling engine burners, and power generation furnaces

Scaled-Particle Theory and the Length-scales Involved in Hydrophobic Hydration of Aqueous Biomolecular Assemblies

Hydrophobic hydration plays a crucial role in self-assembly processes over multiple length-scales, but the extrapolation of molecular-scale models to larger length-scale hydration phenomena is sometimes not warranted. Scaled-particle theories are based upon an interpolative view of that issue. We revisit the scaled-particle theory proposed thirty years ago by Stillinger, adopt a practical generalization, and consider the implications for hydrophobic hydration in light of our current understanding. The generalization is based upon identifying a molecular length, implicit in previous applications of scaled-particle models, that provides an effective radius for joining microscopic and macroscopic descriptions. We demonstrate that the generalized theory correctly reproduces many of the anomalous thermodynamic properties of hydrophobic hydration for molecularly sized solutes, including solubility minima and entropy convergence, successfully interpolates between the microscopic and macroscopic extremes, and provides new insights into the underlying molecular mechanisms. The results are discussed in terms of length-scales associated with component phenomena; in particular we first discuss the micro-macroscopic joining radius identified by the theory, then we discuss in turn the Tolman length that leads to an analogous length describing curvature corrections of a surface area model of hydrophobic hydration free energies, and the length-scales on which entropy convergence of hydration free energies are expected.Comment: 19 pages, 14 figures, one figure added, submitted to Rev. Mod. Phy

Formulating Viscous Hydrodynamics for Large Velocity Gradients

Viscous corrections to relativistic hydrodynamics, which are usually formulated for small velocity g radients, have recently been extended from Navier-Stokes formulations to a class of treatments based on Israel-Stewart equations. Israel-Stewart treatments, which treat the spatial components of the s tress-energy tensor tau_ij as dynamical objects, introduce new parameters, such as the relaxati on times describing non-equilibrium behavior of the elements tau_ij. By considering linear resp onse theory and entropy constraints, we show how the additional parameters are related to fluctuatio ns of tau_ij. Furthermore, the Israel-Stewart parameters are analyzed for their ability to prov ide stable and physical solutions for sound waves. Finally, it is shown how these parameters, which are naturally described by correlation functions in real time, might be constrained by lattice calcu lations, which are based on path-integral formulations in imaginary time.Comment: 16 page

Universal scaling relations in molecular superconductors

Scaling relations between the superconducting transition temperature $T_{\rm c}$, the superfluid stiffness $\rho_{\rm s}$ and the normal state conductivity $\sigma_0(T_{\rm c})$ are identified within the class of molecular superconductors. These new scaling properties hold as $T_{\rm c}$ varies over two orders of magnitude for materials with differing dimensionality and contrasting molecular structure, and are dramatically different from the equivalent scaling properties observed within the family of cuprate superconductors. These scaling relations place strong constraints on theories for molecular superconductivity.Comment: 4 pages, 4 figure

Unconventional Quantum Critical Points

In this paper we review the theory of unconventional quantum critical points that are beyond the Landau's paradigm. Three types of unconventional quantum critical points will be discussed: (1). The transition between topological order and semiclassical spin ordered phase; (2). The transition between topological order and valence bond solid phase; (3). The direct second order transition between different competing orders. We focus on the field theory and universality class of these unconventional quantum critical points. Relation of these quantum critical points with recent numerical simulations and experiments on quantum frustrated magnets are also discussed.Comment: 28 pages, 6 figures. Review article for Int. J. Mod. Phys.

Isospin Fluctuations from a Thermally Equilibrated Hadron Gas

Partition functions, multiplicity distributions, and isospin fluctuations are calculated for canonical ensembles in which additive quantum numbers as well as total isospin are strictly conserved. When properly accounting for Bose-Einstein symmetrization, the multiplicity distributions of neutral pions in a pion gas are significantly broader as compared to the non-degenerate case. Inclusion of resonances compensates for this broadening effect. Recursion relations are derived which allow calculation of exact results with modest computer time.Comment: 10 pages, 5 figure