98 research outputs found
Translating Elizabeth Gaskell's "Right at Last" with an Eye on Italian Translations of Gaskell's Works: Problems and Strategies
Table S1. numerical indices of physicochemical and biochemical properties of amino acids. (XLSX 11 kb
DNA: New materials for substrate selective catalysis
<p>We discovered that random DNA fragments (RDF) could selectively catalyze the oxidation of peroxidase substrates under the H<sub>2</sub>O<sub>2</sub>-TMB system. The activity is closely related with the length of DNA chain. Taking advantage of simplicity and efficiency, the RDF would have potential applications in biotechnology and clinical diagnosis as enzymatic mimetics.</p
Molecular Dynamics Simulation of Methane Hydrate Formation on Pipeline Surface in the Presence of Corrosion Inhibitors
Large
amounts of inhibitors are consumed annually to tackle the
two critical flow assurance problems of pipelines in the oil–gas
industry, namely, corrosion and gas hydrate blockages. Such strategies
can be optimized when the implications of corrosion inhibitor on gas
hydrate formation are clarified as well as the underlying mechanisms.
Therefore, molecular dynamics simulations were performed in this study
to elucidate the effects of a conventional imidazoline corrosion inhibitor
[1-(2-aminoethyl)-11-alkyl-imidazoline, AAI] on the formation of methane
hydrate. A significant hydrate kinetics inhibition effect was observed
according to the F4φ analysis at
different locations. The ability of AAI to inhibit the hydrate formation
was mainly attributed to its constituent of the hydrophobic group,
which either displaced the methane molecules and destroyed the stability
of water cages (AAI concentration at 4.9%), or separated the methane
from the water molecules to markedly reduce their interactions (AAI
concentration at 10.3%). In contrast, the contributions by the hydrophilic
group of AAI were secondary with respect to the limited contact with
water to disrupt the hydrogen bonds of the water cages. The thermodynamic
analysis revealed that the methane hydrate particles were hardly deposited
on the AAI-covered pipeline surface due to the strong repulsion effect
of the hydrophobic groups on the water cages. Such molecular insights
provide theoretical guidance for evaluating the functional groups
of corrosion inhibitors that may affect the formation of gas hydrates
and, subsequently, modifying these functional groups to achieve a
dual inhibition influence on both pipeline corrosion and gas hydrate
formation
A Facile One-Pot Method to Synthesize a Polypyrrole/Hemin Nanocomposite and Its Application in Biosensor, Dye Removal, and Photothermal Therapy
In this work, we introduced a facile
method for the construction of a polypyrrole/hemin (PPy/hemin) nanocomposite
via one-pot chemical oxidative polymerization. In this process, a
hemin molecule serving as a dopant was entrapped in the PPy nanocomposite
during chemical oxidative polymerization. Scanning electron microscopy
(SEM), transmission electron microscopy (TEM), Fourier transform infrared
spectroscopy (FTIR), and UV–visible spectroscopy results demonstrated
that the PPy/hemin nanocomposite was successfully synthesized. The
as-prepared nanocomposite exhibited intrinsic peroxidase-like catalytic
activities, strong adsorption properties, and an excellent near-infrared
(NIR) light-induced thermal effect. We utilized the nanomaterials
to catalyze the oxidation of a peroxidase substrate 3,3,5,5-tetramethylbenzidine
by H<sub>2</sub>O<sub>2</sub> to the oxidized colored product which
provided a colorimetric detection of glucose. As low as 50 ÎĽM
glucose could be detected with a linear range from 0.05 to 8 mM. Moreover,
the obtained nanocomposite also showed excellent removal efficiency
for methyl orange and rhodamine B and a photothermal effect, which
implied a promising application as the pollutant adsorbent and photothermal
agent. The unique nature of the PPy/hemin nanocomposite makes it very
promising for the fabrication of inexpensive, high-performance bioelectronic
devices in the future
Additional file 1 of Giant unruptured sinus of Valsalva aneurysms causing angina pectoris
Supplementary Material
Newcastle-Ottawa Scale (NOS) for assessing the quality of nonrandomized trials.
<p>Newcastle-Ottawa Scale (NOS) for assessing the quality of nonrandomized trials.</p
Relative risk of Grade III/IV adverse events in patients treates with TACE plus sorafenib versus TACE.
<p>Relative risk of Grade III/IV adverse events in patients treates with TACE plus sorafenib versus TACE.</p
Objective response rate (ORR) for the combination of TACE plus sorafenib with TACE.
<p>Objective response rate (ORR) for the combination of TACE plus sorafenib with TACE.</p
Overall survival (OS), time to progression (TTP), and progression.
<p>Overall survival (OS), time to progression (TTP), and progression.</p
Eligibility of studies for inclusion in the meta-analysis.
<p>Eligibility of studies for inclusion in the meta-analysis.</p
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