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    Synthesis, Structure, and Reactivity of a Gallylene Derivative Bearing a Phenalenyl-Based Ligand

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    Phenalenyl-based N,N-bidentate ligand-stabilized monovalent gallium(I) 1 was synthesized and characterized. Compound 1 promotes the oxidative addition of I-I, Si-Cl, C-I, and S-S bonds and oxidative cyclization with various Pi-components. Compound 1 can also coordinate to a tungsten complex to form a gallium-tungsten bond