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Introduction: an anthropology of intellectual exchange
Dialogues, encounters and interactions through which particular ways of knowing, understanding and thinking about the world are forged lie at the centre of anthropology. Such âintellectual exchangeâ is also central to anthropologistsâ own professional practice: from their interactions with research participants and modes of pedagogy to their engagements with each other and scholars from adjacent disciplines. This collection of essays explores how such processes might best be studied cross-culturally. Foregrounding the diverse interactions, ethical reasoning, and intellectual lives of people from across the continent of Asia, the volume develops an anthropology of intellectual exchange itself
One-Pot Multi-Tracer Synthesis of Novel <sup>18</sup>FâLabeled PET Imaging Agents
<sup>18</sup>F labeled phosphonium salts are increasingly important
molecular probes for targeting the mitochondrial membrane potential
depletion during apoptosis and for detecting myocardial perfusion
deficit. Here, we introduce three new tracers, [<sup>18</sup>F]ÂMitoPhos_04,
[<sup>18</sup>F]ÂMitoPhos_05, and [<sup>18</sup>F]ÂMitoPhos_07, that
have the potential to act as mitochondrial imaging agents. Moreover,
they have the added advantage of being synthesized in the same reaction
vial from one radiolabeled synthon, demonstrating a new approach to
synthesizing multiple tracers in one-pot, which is a highly useful
means for increasing the throughput of radiotracer development. The
radiosynthesis of the tracers was carried out on a fully automated
system via a facile two-step reaction. Utilizing the radiolabeling
of an ethyl azide, a copper-mediated 1,3-cycloaddition reaction and
isolation via semiprep high-performance liquid chromatography (HPLC)
allowed for the simultaneous synthesis of two or three tracers with
a total synthesis time of less than 1 h
Yttrium Phosphasalen Initiators for <i>rac</i>-Lactide Polymerization: Excellent Rates and High Iso-Selectivities
Highly active yttrium phosphasalen initiators for the
stereocontrolled
ring-opening polymerization of <i>rac</i>-lactide are reported.
The initiators are coordinated by a new class of ancillary ligand:
an iminophosphorane derivative of the popular âsalenâ
ligand, termed âphosphasalenâ. Changing the phosphasalen
structure enables access to high iso-selectivities (<i>P</i><sub>i</sub> = 0.84) or hetero-selectivities (<i>P</i><sub>s</sub> = 0.87). The initiators also show very high rates, excellent
polymerization control, and tolerance to low loadings; furthermore,
no chiral auxiliaries/ligands are needed for the stereocontrol. The
combination of such high rates with high iso-selectivities is very
unusual
Yttrium Phosphasalen Initiators for <i>rac</i>-Lactide Polymerization: Excellent Rates and High Iso-Selectivities
Highly active yttrium phosphasalen initiators for the
stereocontrolled
ring-opening polymerization of <i>rac</i>-lactide are reported.
The initiators are coordinated by a new class of ancillary ligand:
an iminophosphorane derivative of the popular âsalenâ
ligand, termed âphosphasalenâ. Changing the phosphasalen
structure enables access to high iso-selectivities (<i>P</i><sub>i</sub> = 0.84) or hetero-selectivities (<i>P</i><sub>s</sub> = 0.87). The initiators also show very high rates, excellent
polymerization control, and tolerance to low loadings; furthermore,
no chiral auxiliaries/ligands are needed for the stereocontrol. The
combination of such high rates with high iso-selectivities is very
unusual