Чисельне моделювання фазових переходів у просторово-розподілених стохастичних системах

У рамках комп’ютерного експерименту у роботі вивчалася можливість реалізації фазового переходу типу порушення симетрії у просторово-розподіленій синергетичній системі за рахунок дії скорельованих у часі шумів. У якості базової моделі була використана система Лоренца із двома шумами та просторовою (дифузійною) складовою у рівнянні на параметр порядку. Побудована модель добре описує ряд процесів, наприклад, самоорганізацію дефектної структури під впливом скорельованих внутрішнього та зовнішнього шумів

La fundación de la Madrasa al-Adāb por la Asociación de ulemas musulmanes argelinos en la ciudad de Hennaya (Tremecén) en 1950

A biphenyl-fused BODIPY was synthesized through a facile oxidative cyclization of peripheral aryl-substituents at the β-position of the BODIPY unit. The extended π-system of the fused BODIPY induces near-infrared (NIR) absorption and strong π–π interactions in the solid state. These features are beneficial for the application of the dye as a functional material. The biphenyl-fused BODIPY dye was demonstrated to exhibit photocurrent conversion ability on the basis of its <i>n</i>-type semiconducting property

Electropolymerized Conjugated Polyelectrolytes with Tunable Work Function and Hydrophobicity as an Anode Buffer in Organic Optoelectronics

A new class of conductive polyelectrolyte films with tunable work function and hydrophobicity has been developed for the anode buffer layer in organic electronic devices. The work function of these films featuring a copolymer of ethylenedioxythiophene (EDOT), and its functionalized analogues were found to be easily tunable over a range of almost 1 eV and reach values as high as those of PEDOT:PSS. The new buffer material does not need the addition of any insulating or acidic material that might limit the film conductivity or device lifetime. Organic photovoltaic devices built with these films showed improved open-circuit voltage over those of the known PSS-free conductive EDOT-based polymers with values as high as that obtained for PEDOT:PSS. Furthermore, the surface hydrophobicity of these new copolymer films was found to be sensitive to the chemical groups attached to the polymer backbone, offering an attractive method for surface energy tuning

FeCl₃-Mediated Synthesis of Fullerenyl Esters as Low-LUMO Acceptors for Organic Photovoltaic Devices

C₆₀ reacted with aromatic and aliphatic carboxylic acids in the presence of inexpensive FeCl₃ at room temperature to produce hydroxyfullerenyl esters C₆₀(OCOR)(OH) in up to 68% isolated yield. The hydroxyl group was utilized in functional group transformations to obtain a diester derivative C₆₀(OCOAr)(OCOPh) (Ar = 2,6-xylyl) and a siloxyl derivative C₆₀(OCOAr)(OSiMe₃). The diester and siloxyl derivatives were found to possess low-lying LUMO levels were utilized in organic photovoltaic devices showing 1.3% power conversion efficiency