Properties of Polyol Esters for Low GWP Refrigerants

HFC (Hydrofluorocarbon) refrigerants, whose ODP (Ozone Depletion Potential) is 0, are used in refrigeration and air conditioning equipments recently. It is known that HFCs are high GWP (Global Warming Potential) refrigerants. In October 2016, Kigali Amendment to the Montreal Protocol was stated to achieve the phase-down of HFC refrigerants to prevent global warming. Transition of current HFCs to low GWP refrigerants would be accelerated around the world. HFO (Hydrofluoroolefin) refrigerants such as R1234yf, R1234ze etc. are low GWP refrigerants. Refrigerant manufacturers are introducing not only HFO itself, but also mixture of HFC and HFO. HFO is known to be less chemically stable compared to HFC since there is double bond in its molecular structure. Also, HFOs tend to dissolve well with refrigeration oil compared to HFCs. As a result, amount of refrigerant dissolving in the oil increase and the kinematic viscosity of the oil decrease. We investigated ways to solve problems which may occur by using HFOs. In particular, it is important to maintain the stability and lubricity of oil. To improve stability, we optimized the amount of the stabilizer. To improve lubricity, since the kinematic viscosity of the oil decrease because the refrigerant dissolve in the oil more than necessary, we applied original base oil formulation to prevent the refrigerant from dissolving too much to the oil. In the presentation, properties of POE refrigeration oils which solve problems of low GWP refrigerants by investigating appropriate base oil and additive formulation are introduced

Mapping dust column density in dark clouds by using NIR scattered light : Case of the Lupus 3 dark cloud

We present a method of mapping dust column density in dark clouds by using near-infrared scattered light. Our observations of the Lupus 3 dark cloud indicate that there is a well defined relation between (1) the H-Ks color of an individual star behind the cloud, i.e., dust column density, and (2) the surface brightness of scattered light toward the star in each of the J, H, and Ks bands. In the relation, the surface brightnesses increase at low H-Ks colors, then saturate and decrease with increasing H-Ks. Using a simple one-dimensional radiation transfer model, we derive empirical equations which plausibly represent the observed relationship between the surface brightness and the dust column density. By using the empirical equations, we estimate dust column density of the cloud for any directions toward which even no background stars are seen. We obtain a dust column density map with a pixel scale of 2.3 x 2.3 arcsec^2 and a large dynamic range up to Av = 50 mag. Compared to the previous studies by Juvela et al., this study is the first to use color excess of the background stars for calibration of the empirical relationship and to apply the empirical relationship beyond the point where surface brightness starts to decrease with increasing column density

A Near-Infrared Study of the Highly-Obscured Active Star-Forming Region W51B

We present wide-field JHKs-band photometric observations of the three compact HII regions G48.9-0.3, G49.0-0.3, and G49.2-0.3 in the active star-forming region W51B. The star clusters inside the three compact HII regions show the excess number of stars in the J-Ks histograms compared with reference fields. While the mean color excess ratio E(J-H)/E(H-Ks) of the three compact HII regions are similar to ~ 2.07, the visual extinctions toward them are somewhat different: ~ 17 mag for G48.9-0.3 and G49.0-0.3; ~ 23 mag for G49.2-0.3. Based on their sizes and brightnesses, we suggest that the age of each compact HII region is =< 2 Myr. The inferred total stellar mass, ~ 1.4 x 10^4 M_sun, of W51B makes it one of the most active star forming regions in the Galaxy with the star formation efficiency of ~ 10 %.Comment: 12 pages, 10 eps figures, uses jkas.st

Experimental Comparative Effects of Botulinum Toxin A between Subtypes A1 and A2 in Movement Disorders in Rats

In the present review, we describe here experimental comparative and beneficial effects of botulinum neurotoxin A (ANTX) between subtypes A1 and A2 in the pathology of movement disorders, particularly rat Parkinson’s disease model. We and other laboratories have shown the beneficial effects, and this novel strategy for intractable brain disorders might confer potent and safety therapy in bedside. First, we show the characteristics of ANTXs in the genetic aspects of these subtypes, and our intriguing findings of immunological profiles in the subtypes between A1NTX and A2NTX. Then, we state the distinct diffusion in the body between A1NTX and A2NTX. Importantly, we describe that the intra-brain treatment of small animals with A2NTX subtype results in improvements of pathologies more effectively and provides greater safety than those of A1NTX in a rat 6-OHDA Parkinson’s disease (PD) model. Finally, we represent that the different efficacies between ANTXs are likely due to each localization in the brain; A2NTX is strictly limited in the injected regions, while A1NTX diffused other brain regions. Thus, therapeutic avenue using A2NTX in incurable PD including other movement disorders could be a druggable target in the future

Near-infrared circular polarization survey in star-forming regions : Correlations and trends

We have conducted a systematic near-infrared circular polarization (CP) survey in star-forming regions, covering high-mass, intermediate-mass, and low-mass young stellar objects. All the observations were made using the SIRPOL imaging polarimeter on the Infrared Survey Facility 1.4 m telescope at the South African Astronomical Observatory. We present the polarization properties of 10 sub-regions in 6 star-forming regions. The polarization patterns, extents, and maximum degrees of linear and circular polarizations are used to determine the prevalence and origin of CP in the star-forming regions. Our results show that the CP pattern is quadrupolar in general, the CP regions are extensive, up to 0.65 pc, the CP degrees are high, up to 20%, and the CP degrees decrease systematically from high- to low-mass young stellar objects. The results are consistent with dichroic extinction mechanisms generating the high degrees of CP in star-forming regions.Peer reviewe

Distortion of Magnetic Fields in a Starless Core II: 3D Magnetic Field Structure of FeSt 1-457

Three dimensional (3D) magnetic field information on molecular clouds and cores is important for revealing their kinematical stability (magnetic support) against gravity which is fundamental for studying the initial conditions of star formation. In the present study, the 3D magnetic field structure of the dense starless core FeSt 1-457 is determined based on the near-infrared polarimetric observations of the dichroic polarization of background stars and simple 3D modeling. With an obtained angle of line-of-sight magnetic inclination axis $\theta_{\rm inc}$ of $45^{\circ}\pm10^{\circ}$ and previously determined plane-of-sky magnetic field strength $B_{\rm pol}$ of $23.8\pm12.1$ $\mu{\rm G}$, the total magnetic field strength for FeSt 1-457 is derived to be $33.7\pm18.0$ $\mu{\rm G}$. The critical mass of FeSt 1-457, evaluated using both magnetic and thermal/turbulent support is ${M}_{\rm cr} = 3.70\pm0.92$ ${\rm M}_{\odot}$, which is identical to the observed core mass, $M_{\rm core}=3.55\pm0.75$ ${\rm M}_{\odot}$. We thus conclude that the stability of FeSt 1-457 is in a condition close to the critical state. Without infalling gas motion and no associated young stars, the core is regarded to be in the earliest stage of star formation, i.e., the stage just before the onset of dynamical collapse following the attainment of a supercritical condition. These properties would make FeSt 1-457 one of the best starless cores for future studies of the initial conditions of star formation.Comment: Accepted to the Astrophysical Journal (ApJ

Distortion of Magnetic Fields in a Starless Core III: Polarization--Extinction Relationship in FeSt 1-457

The relationship between dust polarization and extinction was determined for the cold dense starless molecular cloud core FeSt 1-457 based on the background star polarimetry of dichroic extinction at near-infrared wavelengths. Owing to the known (three-dimensional) magnetic field structure, the observed polarizations from the core were corrected by considering (a) the subtraction of the ambient polarization component, (b) the depolarization effect of inclined distorted magnetic fields, and (c) the magnetic inclination angle of the core. After these corrections, a linear relationship between polarization and extinction was obtained for the core in the range up to $A_V \approx 20$ mag. The initial polarization vs. extinction diagram changed dramatically after the corrections of (a) to (c), with the correlation coefficient being refined from 0.71 to 0.79. These corrections should affect the theoretical interpretation of the observational data. The slope of the finally obtained polarization--extinction relationship is $P_H / E_{H-K_s} = 11.00 \pm 0.72$ $\%$ ${\rm mag}^{-1}$, which is close to the statistically estimated upper limit of the interstellar polarization efficiency (Jones 1989). This consistency suggests that the upper limit of interstellar polarization efficiency might be determined by the observational viewing angle toward polarized astronomical objects.Comment: Accepted to the Astrophysical Journal (ApJ