Green Synthesis and the formation kinetics of silver nanoparticles in aqueous Inula Viscosa extract

In this study, we present the production of silver nanoparticles in aqueous Inula Viscosa extract by the green synthesis approach at room temperature. The structural, morphological properties as well as formation kinetics of the synthesized silver nanoparticles were characterized by UV-VIS, STEM, XRD, Raman and FTIR measurements. Mono-dispersed and very stable silver nanoparticles with size of 15$\pm$5 nm and face-centered cubic crystal structure were synthesized in aqueous Inula Viscosa extract. The kinetic studies of silver nanoparticles formation in Inula Viscosa extract show that silver nanoparticle formation reaction reached the equilibrium within 24 h and fit in the first-order reaction kinetics. The results clearly show that the size of fabricated nanoparticles is independent on the dynamical formation process since the reaction time and initial silver ion concentration did not affect on size and morphology of the produced particles

Eco-Friendly Boost for Perovskite Photovoltaics: Harnessing Cellulose-Modified SnO₂ as a High-Performance Electron Transporting Material

In this study, a passivated tin oxide (SnO2) film is successfully obtained through the implementation of sodium carboxymethyl cellulose (Na-CMC) modifier agent and used as the electron transporting layer (ETL) within the assembly of perovskite solar cells (PSCs). The strategic incorporation of the Na-CMC modifier agent yields discernible enhancements in the optoelectronic properties of the ETL. Among the fabricated cells, the champion cell based on Na-CMC-complexed SnO2 ETL achieves a conversion efficiency of 22.2% with an open-circuit voltage (VOC) of 1.12 V, short-circuit current density (JSC) of 24.57 mA/cm2, and fill factor (FF) of 80.6%. On the other hand, these values are measured for the pristine SnO2 ETL-based control cell as VOC = 1.11 V, JSC = 23.59 mA/cm2, and FF = 76.7% with an efficiency of 20.1%. This improvement can be ascribed to the high charge extraction ability, higher optical transmittance, better conductivity, and decrease in the trap state density associated with the passivated ETL structure. In addition, the cells employing Na-CMC-complexed SnO2 ETL exhibit prolonged stability under ambient conditions during 2000 h. Based on the preliminary results, this study also presents a set of findings that could have substantial implications for the potential use of the Na-CMC molecule in both large-scale perovskite cells and perovskite/Si tandem configuration