In the Beginning: The First Sources of Light and the Reionization of the Universe

The formation of the first stars and quasars marks the transformation of the universe from its smooth initial state to its clumpy current state. In popular cosmological models, the first sources of light began to form at redshift 30 and reionized most of the hydrogen in the universe by redshift 7. Current observations are at the threshold of probing the hydrogen reionization epoch. The study of high-redshift sources is likely to attract major attention in observational and theoretical cosmology over the next decade.Comment: Final revision: 136 pages, including 42 figures; to be published in Physics Reports 2001. References updated, and a few minor corrections made. In this submission, several figures were compressed, resulting in just a slight reduction in quality; a postscript file with the full figures is available at http://www.cita.utoronto.ca/~barkana/review.htm

Properties of Graphene: A Theoretical Perspective

In this review, we provide an in-depth description of the physics of monolayer and bilayer graphene from a theorist's perspective. We discuss the physical properties of graphene in an external magnetic field, reflecting the chiral nature of the quasiparticles near the Dirac point with a Landau level at zero energy. We address the unique integer quantum Hall effects, the role of electron correlations, and the recent observation of the fractional quantum Hall effect in the monolayer graphene. The quantum Hall effect in bilayer graphene is fundamentally different from that of a monolayer, reflecting the unique band structure of this system. The theory of transport in the absence of an external magnetic field is discussed in detail, along with the role of disorder studied in various theoretical models. We highlight the differences and similarities between monolayer and bilayer graphene, and focus on thermodynamic properties such as the compressibility, the plasmon spectra, the weak localization correction, quantum Hall effect, and optical properties. Confinement of electrons in graphene is nontrivial due to Klein tunneling. We review various theoretical and experimental studies of quantum confined structures made from graphene. The band structure of graphene nanoribbons and the role of the sublattice symmetry, edge geometry and the size of the nanoribbon on the electronic and magnetic properties are very active areas of research, and a detailed review of these topics is presented. Also, the effects of substrate interactions, adsorbed atoms, lattice defects and doping on the band structure of finite-sized graphene systems are discussed. We also include a brief description of graphane -- gapped material obtained from graphene by attaching hydrogen atoms to each carbon atom in the lattice.Comment: 189 pages. submitted in Advances in Physic

The optical properties of three type II supernovae: 2014cx, 2014cy and 2015cz

We present the photometric and spectroscopic analysis of three Type II SNe: 2014cx, 2014cy and 2015cz. SN 2014cx is a conventional Type IIP with a shallow slope (0.2 mag/50d) and an atypical short plateau ($\sim$86 d). SNe 2014cy and 2015cz show relatively large decline rates (0.88 and 1.64 mag/50d, respectively) at early times before settling to the plateau phase, unlike the canonical Type IIP/L SN light curves. All of them are normal luminosity SN II with an absolute magnitude at mid-plateau of M$_{V,14cx}^{50}$=$-$16.6$\pm$0.4$\,\rm{mag}$, M$_{V,14cy}^{50}$=$-$16.5$\,\pm\,$0.2$\,\rm{mag}$ and M$_{V,15cz}^{50}$=$-$17.4$\,\pm\,$0.3$\,\rm{mag}$. A relatively broad range of $^{56}$Ni masses is ejected in these explosions (0.027-0.070 M$_\odot$). The spectra show the classical evolution of Type II SNe, dominated by a blue continuum with broad H lines at early phases and narrower metal lines with P Cygni profiles during the plateau. High-velocity H I features are identified in the plateau spectra of SN 2014cx at 11600 km s$^{-1}$, possibly a sign of ejecta-circumstellar interaction. The spectra of SN 2014cy exhibit strong absorption profile of H I similar to normal luminosity events whereas strong metal lines akin to sub-luminous SNe. The analytical modelling of the bolometric light curve of the three events yields similar radii for the three objects within errors (478, 507 and 608 R$_\odot$ for SNe 2014cx, 2014cy and 2015cz, respectively) and a range of ejecta masses (15.0, 22.2 and 18.7 M$_\odot$ for SNe 2014cx, 2014cy and 2015cz), and a modest range of explosion energies (3.3 - 6.0 foe where 1 foe = 10$^{51}$ erg).Comment: 20 pages, 23 Figures, 3 figures in appendix, accepted for publication in MNRA

SN 2020udy: A new piece of the homogeneous bright group in the diverse Iax subclass

We present optical observations and analysis of a bright type Iax SN~2020udy hosted by NGC 0812. The light curve evolution of SN~2020udy is similar to other bright Iax SNe. Analytical modeling of the quasi bolometric light curves of SN 2020udy suggests that 0.08$\pm$0.01 M$_{\odot}$ of $^{56}$Ni would have been synthesized during the explosion. Spectral features of SN 2020udy are similar to the bright members of type Iax class showing weak Si {\sc II} line. The late-time spectral sequence is mostly dominated by Iron Group Elements (IGEs) with broad emission lines. Abundance tomography modeling of the spectral time series of SN~2020udy using TARDIS indicates stratification in the outer ejecta, however, to confirm this, spectral modeling at a very early phase is required. After maximum light, uniform mixing of chemical elements is sufficient to explain the spectral evolution. Unlike the case of normal type Ia SNe, the photospheric approximation remains robust until +100 days, requiring an additional continuum source. Overall, the observational features of SN 2020udy are consistent with the deflagration of a Carbon-Oxygen white dwarf.Comment: 18 pages, 17 figures, 3 tables, Accepted for publication in Ap

Changes in global groundwater organic carbon driven by climate change and urbanization

YesClimate change and urbanization can increase pressures on groundwater resources, but little is known about how groundwater quality will change. Here, we rely on a global synthesis (n = 9,404) to reveal the drivers of dissolved organic carbon (DOC), which is an important component of water chemistry and substrate for microorganisms which control many biogeochemical reactions. Groundwater ions, local climate and land use explained ~ 31% of observed variability in groundwater DOC, whilst aquifer age explained an additional 16%. We identify a 19% increase in DOC associated with urban land cover. We predict major groundwater DOC increases following changes in precipitation and temperature in key areas relying on groundwater. Climate change and conversion of natural or agricultural areas to urban areas will decrease groundwater quality and increase water treatment costs, compounding existing threats to groundwater resources

SN 2017gmr: An Energetic Type II-P Supernova with Asymmetries

We present high-cadence UV, optical, and near-infrared data on the luminous Type II-P supernova SN2017gmr from hours after discovery through the first 180 days. SN2017gmr does not show signs of narrow, high-ionization emission lines in the early optical spectra, yet the optical light-curve evolution suggests that an extra energy source from circumstellar medium (CSM) interaction must be present for at least 2 days after explosion. Modeling of the early light curve indicates a ∼500 Re progenitor radius, consistent with a rather compact red supergiant, and latetime luminosities indicate that up to 0.130±0.026 Me of 56Ni are present, if the light curve is solely powered by radioactive decay, although the 56Ni mass may be lower if CSM interaction contributes to the post-plateau luminosity. Prominent multipeaked emission lines of Hα and [O I] emerge after day 154, as a result of either an asymmetric explosion or asymmetries in the CSM. The lack of narrow lines within the first 2 days of explosion in the likely presence of CSM interaction may be an example of close, dense, asymmetric CSM that is quickly enveloped by the spherical supernova ejecta

Flash ionization signatures in the type Ibn supernova SN 2019uo

We present photometric and spectroscopic observations of the type Ibn supernova (SN) 2019uo, the second ever SN Ibn with flash ionization (He II, C III, N III) features in its early spectra. SN 2019uo displays a rapid post-peak luminosity decline of 0.1 mag d$^{-1}$ similar to most of the SNe Ibn, but is fainter ($M^V_{max} = -18.30 \pm 0.24$ mag) than a typical SN Ibn and shows a color evolution that places it between SNe Ib and the most extreme SNe Ibn. SN 2019uo shows P-cygni He I features in the early spectra which gradually evolves and becomes emission dominated post peak. It also shows faster evolution in line velocities as compared to most other members of the type Ibn subclass. The bolometric light curve is fairly described by a $^{56}$Ni + circumstellar interaction model.Comment: 14 figures, 4 tables, Accepted for publication in ApJ, Corner plots are put in low resolution due to size limitations, please contact authors for original figur

Recent advances in hydrothermal carbonisation:from tailored carbon materials and biochemicals to applications and bioenergy

Introduced in the literature in 1913 by Bergius, who at the time was studying biomass coalification, hydrothermal carbonisation, as many other technologies based on renewables, was forgotten during the "industrial revolution". It was rediscovered back in 2005, on the one hand, to follow the trend set by Bergius of biomass to coal conversion for decentralised energy generation, and on the other hand as a novel green method to prepare advanced carbon materials and chemicals from biomass in water, at mild temperature, for energy storage and conversion and environmental protection. In this review, we will present an overview on the latest trends in hydrothermal carbonisation including biomass to bioenergy conversion, upgrading of hydrothermal carbons to fuels over heterogeneous catalysts, advanced carbon materials and their applications in batteries, electrocatalysis and heterogeneous catalysis and finally an analysis of the chemicals in the liquid phase as well as a new family of fluorescent nanomaterials formed at the interface between the liquid and solid phases, known as hydrothermal carbon nanodots