Table_1_How Fast Are the Asian Countries Progressing Toward Green Economy? Implications for Public Health.docx

Monitoring progress toward green economy has been a key policy focus globally. The purpose of our study is to assess Asian countries' green development performance and also the progress toward green economy overtime. To achieve this goal, we propose a green development index (GDI) to assess the level and ranking of green development for Asian countries, and then we measure the progress toward green economy by the method based on the compound annual growth rate (CAGR). The result shows that the northeast Asian countries together with Singapore and Israel are leaders in green development performance across Asia, but the most progress toward green economy has been achieved by some medium green development level countries, like China. Countries with the fastest movement away from green economy are some laggard countries with poor green development performance, such as Syria and Yemen. More generally, the leading countries have reached a high green development level, and the medium ones move fast toward green economy, whereas some laggards get worse. We also discuss the implications for public health in environmental protection, green consumption, and green production.</p

Rearranging the Phase Distribution of Quasi-2D Perovskite for Efficient and Narrow Emission Perovskite Light-Emitting Diodes

Quasi-2D perovskite light-emitting diodes (PeLEDs) have attracted significant attention for their promising light-emitting applications. However, quasi-2D perovskite films typically consist of a broad phase distribution and small grains with a large surface area to volume ratio, leading to inferior color purities and higher defect densities. Herein, a bifunctional additive ((l)-tryptophan bromide, l-TrpBr) was introduced into a quasi-2D perovskite film. The CO moiety of l-TprBr formed hydrogen bonds with S-MBA+, retarding the coordination between S-MBABr and [PbBr6]4– and suppressing the formation of small-n phases. The CO moiety also coordinated with unsaturated Pb2+ sites to passivate the defects. Finally, the PeLEDs with l-TrpBr exhibited a significantly improved EQE of 14.32% compared to the control devices (7.88%) and the narrowest fwhm (17 nm) for green quasi-2D PeLEDs reported to date. Our work provides a practical approach to controlling the phase distribution and passivating the defects in quasi-2D perovskite films, toward high-efficiency and color-pure quasi-2D PeLEDs

Single-shot Compressed 3D Imaging by Exploiting Random Scattering and Astigmatism

Based on point spread function (PSF) engineering and astigmatism due to a pair of cylindrical lenses, a novel compressed imaging mechanism is proposed to achieve single-shot incoherent 3D imaging. The speckle-like PSF of the imaging system is sensitive to axial shift, which makes it feasible to reconstruct a 3D image by solving an optimization problem with sparsity constraint. With the experimentally calibrated PSFs, the proposed method is demonstrated by a synthetic 3D point object and real 3D object, and the images in different axial slices can be reconstructed faithfully. Moreover, 3D multispectral compressed imaging is explored with the same system, and the result is rather satisfactory with a synthetic point object. Because of the inherent compatibility between the compression in spectral and axial dimensions, the proposed mechanism has the potential to be a unified framework for multi-dimensional compressed imaging

Data_Sheet_1_Soil texture and microorganisms dominantly determine the subsoil carbonate content in the permafrost-affected area of the Tibetan Plateau.PDF

Under climate warming conditions, storage and conversion of soil inorganic carbon (SIC) play an important role in regulating soil carbon (C) dynamics and atmospheric CO2 content in arid and semi-arid areas. Carbonate formation in alkaline soil can fix a large amount of C in the form of inorganic C, resulting in soil C sink and potentially slowing global warming trends. Therefore, understanding the driving factors affecting carbonate mineral formation can help better predict future climate change. Till date, most studies have focused on abiotic drivers (climate and soil), whereas a few examined the effects of biotic drivers on carbonate formation and SIC stock. In this study, SIC, calcite content, and soil microbial communities were analyzed in three soil layers (0–5 cm, 20–30 cm, and 50–60 cm) on the Beiluhe Basin of Tibetan Plateau. Results revealed that in arid and semi-arid areas, SIC and soil calcite content did not exhibit significant differences among the three soil layers; however, the main factors affecting the calcite content in different soil layers are different. In the topsoil (0–5 cm), the most important predictor of calcite content was soil water content. In the subsoil layers 20–30 cm and 50–60 cm, the ratio of bacterial biomass to fungal biomass (B/F) and soil silt content, respectively, had larger contributions to the variation of calcite content than the other factors. Plagioclase provided a site for microbial colonization, whereas Ca2+ contributed in bacteria-mediated calcite formation. This study aims to highlight the importance of soil microorganisms in managing soil calcite content and reveals preliminary results on bacteria-mediated conversion of organic to inorganic C.</p

Polymerized-Small-Molecule Acceptors Featuring Siloxane-Terminated Side Chains for Mechanically Robust All-Polymer Solar Cells

Flexible and stretchable organic solar cells (OSCs) show great promise in wearable and stretchable electronic applications. However, current high-performance OSCs consisting of polymer donors (PDs) and small-molecule acceptors (SMAs) face significant challenges in achieving both high power conversion efficiency (PCE) and excellent stretch-ability. In this study, we synthesized a new polymerized-small-molecule acceptor (P-SMA) PY-SiO featuring siloxane-terminated side chains and compared its photovoltaic and mechanical performance to that of the reference PY-EH with ethylhexyl-terminated side chains. We found that the incorporation of siloxane-terminated side chains in PY-SiO enhanced the molecular aggregation and charge transport, leading to an optimized film morphology. The resultant of all-polymer solar cells (all-PSCs) based on PBDB-T/PY-SiO showed a higher PCE of 12.04% than the PY-EH-based one (10.85%). Furthermore, the siloxane-terminated side chains also increased the interchain distance and provided a larger free volume for chain rotation and reconfiguration, resulting in a higher film crack-onset strain (COS: 18.32% for PBDB-T/PY-SiO vs 11.15% for PBDB-T/PY-EH). Additionally, the PY-SiO-based stretchable all-PSCs exhibited an impressive PCE of 9.8% and retained >70% of its original PCE even under a substantial 20% strain, exceeding the performance of the PY-EH-based stretchable all-PSCs. Our result suggests the great potential of the siloxane-terminated side chain for achieving high-performance and stretchable OSCs

Relationships between the forest landscape percentage index (PLAND) and four ecosystem service functions.

Plots show the relationship between PLAND and (a) carbon sequestration capacity, (b) oxygen release capacity, (c) NPP capacity, (d) water conservation capacity, (e) biodiversity conservation capacity, and (f) recreation capacity.</p

Interaction Between Optically-Generated Charge-Transfer States and Magnetized Charge-Transfer States toward Magneto-Electric Coupling

This article reports the magneto-dielectric studies on the coupling between optically generated CT states and magnetized CT states based on thin-film devices with the architecture of ITO/TPD:BBOT/TPD/Co/Al. The magnetized CT states are generated at the Co/TPD interface, generating a magneto-dielectric response with a broad, non-Lorentzian line-shape. The optically generated CT states are formed at the TPD:BBOT interfaces in the heterojunction under photoexcitation, leading to a magneto-dielectric signal with a narrow, Lorentzian line-shape. We find that combining the optically generated CT states and magnetized CT states yields a new magneto-dielectric signal with distinctive line-shape and amplitude in the ITO/TPD:BBOT/TPD/Co/Al device. The magneto-dielectric analysis indicates that there exists a coupling between optically generated CT states and magnetized CT states through the interactions between the magnetic Co/TPD interface and the optically excited TPD:BBOT heterojunction. Furthermore, we show that the coupling between optically generated CT states and magnetized CT states experiences Coulomb interactions and spin–orbital interaction by changing (i) the density of optically generated CT states and (ii) the separation distance between optically generated CT states and magnetized CT states. Clearly, this coupling provides a new approach to mutually tune magnetic and electronic properties through thin-film engineering by combining magnetic and organic materials

Relationship between the landscape sprawl index (CONTAG) and forest ecosystem service function.

Relationship between the landscape sprawl index (CONTAG) and forest ecosystem service function.</p

Epigenetic Platinum Complexes Breaking the “Eat Me/Don’t Eat Me” Balance for Enhanced Cancer Chemoimmunotherapy

Platinum complexes, despite being the most successful organometallic anticancer chemotherapy drugs, still suffer from serious side effects and therapy resistance. Inspired by the immunomodulation effect of platinum drugs, an epigenetic platinum­(IV) complex was synthesized for enhanced cancer chemoimmunotherapy by conjugating oxidized oxaliplatin (OXA) with 2-bromo-1-(3,3-dinitro-1-azetidinyl)­ethenone (RRx-001), the latter of which as a nitric oxide (NO) donor is also an epigenetic agent. The obtained complex (named OXA-NO) could significantly increase the level of “eat me” signal CRT expression and decrease the level of “don’t eat me” signal CD47 expression on cancer cell membranes to promote their phagocytosis by macrophages. In addition, OXA-NO could release nitric oxide to trigger the transformation of pro-tumorigenic M2-type macrophages into antitumor M1-type macrophages within the tumor to reverse the immunosuppressive tumor microenvironment. Compared to commercial OXA, OXA-NO exhibited much stronger tumor growth inhibition ability and was much better tolerated, with obviously weakened side effects observed in spleen, lung, and kidneys. Therefore, this epigenetic platinum­(IV) complex that exhibits excellent therapeutic efficacy and safety has great potential in the clinic

CONTAG values of individual study units.

CONTAG values of individual study units.</p