16 research outputs found

    Anisotropic magnetoresistivity in structured elastomer composites: modelling and experiments

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    A constitutive model for the anisotropic magnetoresistivity in structured elastomer composites (SECs) is proposed. The SECs considered here are oriented pseudo-chains of conductive-magnetic inorganic materials inside an elastomer organic matrix. The pseudo-chains are formed by fillers which are simultaneously conductive and magnetic dispersed in the polymer before curing or solvent evaporation. The SEC is then prepared in the presence of a uniform magnetic field, referred to as Hcuring. This procedure generates the pseudo-chains, which are preferentially aligned in the direction of Hcuring. Electrical conduction is present in that direction only. The constitutive model for the magnetoresistance considers the magnetic pressure, Pmag, induced on the pseudo-chains by an external magnetic field, H, applied in the direction of the pseudo-chains. The relative changes in conductivity as a function of H are calculated by evaluating the relative increase of the electron tunnelling probability with Pmag, a magneto-elastic coupling which produces an increase of conductivity with magnetization. The model is used to adjust experimental results of magnetoresistance in a specific SEC where the polymer is polydimethylsiloxane, PDMS, and fillers are microparticles of magnetite?silver (referred to as Fe3O4[Ag]). Simulations of the expected response for other materials in both superparamagnetic and blocked magnetic states are presented, showing the influence of the Young´s modulus of the matrix and filler´s saturation magnetization.Fil: Mietta, J. L.. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; ArgentinaFil: Tamborenea, Pablo Ignacio. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; ArgentinaFil: Negri, Ricardo Martin. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentin

    Numerical Simulations of Stick Percolation: Application to the Study of Structured Magnetorheological Elastomers

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    In this article we explore how structural parameters of composites filled with one-dimensional, electrically conducting elements (such as sticks, needles, chains, or rods) affect the percolation properties of the system. To this end, we perform Monte Carlo simulations of asymmetric two-dimensional stick systems with anisotropic alignments. We compute the percolation probability functions in the direction of preferential orientation of the percolating objects and in the orthogonal direction, as functions of the experimental structural parameters. Among these, we considered the average length of the sticks, the standard deviation of the length distribution, and the standard deviation of the angular distribution. We developed a computer algorithm capable of reproducing and verifying known theoretical results for isotropic networks and which allows us to go beyond and study anisotropic systems of experimental interest. Our research shows that the total electrical anisotropy, considered as a direct consequence of the percolation anisotropy, depends mainly on the standard deviation of the angular distribution and on the average length of the sticks. A conclusion of practical interest is that we find that there is a wide and well-defined range of values for the mentioned parameters for which it is possible to obtain reliable anisotropic percolation under relatively accessible experimental conditions when considering composites formed by dispersions of sticks, oriented in elastomeric matrices.Fil: Mietta, J. L.. Consejo Nacional de Investigaciones CientĂ­ficas y TĂ©cnicas. Oficina de CoordinaciĂłn Administrativa Ciudad Universitaria. Instituto de QuĂ­mica, FĂ­sica de los Materiales, Medioambiente y EnergĂ­a. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de QuĂ­mica, FĂ­sica de los Materiales, Medioambiente y EnergĂ­a; ArgentinaFil: Negri, Ricardo Martin. Consejo Nacional de Investigaciones CientĂ­ficas y TĂ©cnicas. Oficina de CoordinaciĂłn Administrativa Ciudad Universitaria. Instituto de QuĂ­mica, FĂ­sica de los Materiales, Medioambiente y EnergĂ­a. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de QuĂ­mica, FĂ­sica de los Materiales, Medioambiente y EnergĂ­a; ArgentinaFil: Tamborenea, Pablo Ignacio. Consejo Nacional de Investigaciones CientĂ­ficas y TĂ©cnicas. Oficina de CoordinaciĂłn Administrativa Ciudad Universitaria. Instituto de FĂ­sica de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de FĂ­sica de Buenos Aires; Argentin

    Possible neighbouring group participation of a nitro-group in the conversion of 3-hydroxymethyl-2-(2-nitrophenyl)-1,2,3,4-tetrahydroisoquinoline into its 3-chloromethyl derivative

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    The alcohol 12 reacted with 4-toluenesulfonyl chloride in boiling dichloromethane solution to give the chlorinated product 13 rather than the expected tosylate 3 by a mechanism that could involve neighbouring group participation of the nitro-substituent. In contrast, the isomeric alcohol 15 reacted normally with 4-toluenesulfonyl chloride giving the tosylate 16 under similar conditions
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