SR-FTiR microscopy and FTIR imaging in the earth sciences

During the last decades, several books have been devoted to the application of spectroscopic methods in mineralogy. Several short courses and meetings have addressed particular aspects of spectroscopy, such as the analysis of hydrous components in minerals and Earth materials. In these books, complete treatment of the infrared theory and practical aspects of instrumentation and methods, along with an exhaustive list of references, can be found. The present chapter is intended to cover those aspects of infrared spectroscopy that have been developed in the past decade and are not included in earlier reviews such as Volume 18 of Reviews in Mineralogy. These new topics involve primarily: (1) the use of synchrotron radiation (SR), which, although not a routine method, is now rather extensively applied in infrared studies, in particular those requiring ultimate spatial and time resolution and the analysis of extremely small samples (a few tens of micrometers); (2) the development of imaging techniques also for foreseen time resolved studies of geo-mineralogical processes and environmental studies.Comment: 36 pages, 24 figures - Reviews in Mineralogy & Geochemistry - Vol. 78 (2013) in pres

Molecular simulation of the phase behavior of noble gases using accurate two-body and three-body intermolecular potentials

Gibbs ensemble Monte Carlo simulations are reported for the vapor- liquid phase coexistence of argon, krypton, and xenon. The calculations employ accurate two-body potentials in addition to contributions from three-body dispersion interactions resulting from third-order triple-dipole, dipole-dipole-quadrupole, dipole- quadrupole-quadrupole, quadrupole-quadrupole-quadrupole, and fourth- order triple- dipole terms. It is shown that vapor-liquid equilibria are affected substantially by three-body interactions. The addition of three-body interactions results in good overall agreement of theory with experimental data. In particular, the subcritical liquid- phase densities are predicted accurately. (C) 1999 American Institute of Physics. S0021- 9606(99)50728-9

XANES Study of Structural Disorder in Amorphous Silicon

An investigation of the structure of several amorphous silicon (a-Si) films is presented. Samples were prepared by using the ion beam sputtering technique at different substrate deposition temperatures. X-ray absorption spectroscopy and multiple scattering formalism have been used to detect structural variations of the a-Si films. The analysis of the XANES (X-ray absorption near-edge structure) spectra shows that increasing the substrate deposition temperature leads to a structural change toward a higher-level short-range order.

Dynamic network model of banking system stability

This paper presents a dynamic model of banking interactions, which uses interbank connections to study the stability of the banking system. The dynamic model extends previous work on network models of the banking system taking inspiration from large scale, complex, interconnected systems studied within the domain of engineering. The banking system is represented as a network where nodes are individual banks and the links between any two banks consist of interbank loans and borrowing. The dynamic structure of the model is represented as a set of differential equations, which, to the best of our knowledge, is an original characteristic of our approach. This dynamic structure not only allows us to analyse systemic risk but also to incorporate an analysis of control mechanisms. Uncertainty is introduced in the system by applying stochastic shocks to the bank deposits, which are assigned as an exogenous signal. The behaviour of the system can be analysed for different initial conditions and parameter sets. This paper shows some preliminary results under different combinations of bank reserve ratios, bank capital sizes and different degrees of bank inter-connectedness. The results show that both reserve ratio and link rate have a positive effect on the stability of the system in the presence of moderate shocks. However, for high values of the shocks, high reserve ratios may have a detrimental effect on the survival of banks. In future work, we will apply strategies from the domain of control engineering to the dynamic model to characterise more formally the stability of the banking network

The Changing Profile of Mexican Migrants to the United States: New Evidence from California and Mexico

Using recent data from southern California and Mexico we challenge the notion that the demographic profile of post-1970 Mexican migrants to the United States has remained constant. We find that more recent cohorts of migrants: (1) are more likely to settle permanently in the United States, (2) have higher proportions of females, (3) are younger, (4) have higher educational attainment, (5) are increasingly likely to originate in southern Mexico and the Mexico City Metropolitan area, and (6) are increasingly likely to depart from urban areas within Mexico. Although we find no direct evidence that the legalization programs mandated by the Immigration Reform and Control Act of 1986 led to a stronger propensity to settle permanently in the United States, logistic regression analyses demonstrate the importance of the other three principal explanatory factors suggested by Cornelius (1992), namely, economic crisis in Mexico, the changing character of U.S. demand for labor, and social networks

Attenuation of choroidal tickness in patients with Alzheimer disease: evidence from an Italian prospective study

INTRODUCTION: To compare the 12-month choroidal thickness (CT) change between Alzheimer disease (AD) patients and normal subjects. METHODS: In this prospective, observational study, 39 patients with a diagnosis of mild to moderate AD and 39 age-matched control subjects were included. All the subjects underwent neuropsychological (Mini Mental State Examination, Alzheimer disease Assessment Scale-Cognitive Subscale, and the Clinical Dementia Rating Scale) and ophthalmological evaluation, including spectral domain optical coherence tomography, at baseline and after 12 months. CT was measured manually using the caliper tool of the optical coherence tomography device. RESULTS: After 12 months, AD patients had a greater reduction of CT than controls (P≤0.05, adjusted for baseline CT, age, sex, axial length, and smoking). DISCUSSION: CT in patients with AD showed a rate of thinning greater than what could be expected during the natural course of aging

Scattering by Interstellar Dust Grains. II. X-Rays

Scattering and absorption of X-rays by interstellar dust is calculated for a model consisting of carbonaceous grains and amorphous silicate grains. The calculations employ realistic dielectric functions with structure near X-ray absorption edges, with resulting features in absorption, scattering, and extinction. Differential scattering cross sections are calculated for energies between 0.3 and 10 keV. The median scattering angle is given as a function of energy, and simple but accurate approximations are found for the X-ray scattering properties of the dust mixture, as well as for the angular distribution of the scattered X-ray halo for dust with simple spatial distributions. Observational estimates of the X-ray scattering optical depth are compared to model predictions. Observations of X-ray halos to test interstellar dust grain models are best carried out using extragalactic point sources.Comment: ApJ, accepted. 27 pages, 12 figures. Much of this material was previously presented in astro-ph/0304060v1,v2,v3 but has been separated into the present article following recommendation by the refere

Latinos in Massachusetts: Legal Immigration to New England During the 1990s

This fact sheet summarizes information about legal immigration flows to the New England Region during the 1990s employing Immigration and Naturalization Service data. Although the annual number of legal permanent residents (e.g., green card holders) from Latin America and the Caribbean fell during the decade, as a percent of all legal immigrants who settled in New England their representation rose. Among all Latin American and Caribbean immigrants who settled in the region, more than half chose Massachusetts or Connecticut. And although most reported working in lower-skilled occupations, from 10 percent to 30 percent of immigrants from each c o u n t ry were working in professional, administrative, or technical support positions. Finally, at least 80 percent of all new legal permanent residents from each nation except Haiti relied on family-based entry categories to obtain their new status

Microwave broadband characterization of aging of SU-8 polymer as CPW substrate

In this paper we present the methodology and the numerical results related to the analysis of aging of the SU- 8 polymer when used as a primary layer for the realization of Coplanar Waveguide (CPW) structures. As test devices, we used a set of transmission lines with different lengths and T-shaped open stubs shunt resonators; by using these geometries, we are able to acquire the data in a broadband range, in principle between 1 GHz and 40 GHz. We conduct the analysis by comparing two different technology run: the first wafer with a deposited layer by a 12-year-old SU-8 and the second wafer, with the same photolithographed metallic geometries, with a brand-new processed SU-8 photoresist