Green Production and Interaction of Carboxylated CNTs/Biogenic ZnO Composite for Antibacterial Activity

Using biomolecule-rich plant extracts, the conversion of metal ions to metal oxide nanoparticles via abiogenic approach is highly intriguing, environmentally friendly, and quick. The inherent inclination of plant extracts function as capping agents in the insitu synthesis. In this study, biogenic zinc oxide nanoparticles (ZnO−NPs) were synthesized using an aqueous leaf extract from Moringaoleifera. The ZnO−NPs were then mixed with carboxylated carbon nanotubes (CNTs) to create a carboxylated CNTs/biogenic ZnO composite using asol–gel method. The CNTs/ZnO composite displayed 18 mm, 16 mm, and 17 mm zones of inhibition (ZOI) against Bacillus cereus, Pseudomonas aeruginosa, and Escherichia coli, respectively. In contrast with ZnO−NPs, the produced carboxylated CNTs/ZnO composite demonstrated a 13 percent elevation in ZOI as antibacterial activity against Bacillus cereus ATCC 19659, Escherichia coli ATCC 25922, and Pseudomonas aeruginosa ATCC 27853. The characterization of ZnO−NPs and the carboxylated CNTs/ZnO composite were performed via FTIR, UV/Vis spectroscopy, SEM, and XRD. The XRD pattern depicted a nano−sized crystalline structure (Wurtzite) of ZnO−NPs and a carboxylated CNTs/ZnO composite. The current work comprehends a valuable green technique for killing pathogenic bacteria, and gives fresh insights into the manufacture of metal oxide composites for future research

Antibacterial and antioxidant screening applications of reduced-graphene oxide modified ternary SnO2-NiO-CuO nanocomposites

Generally, Graphene oxide (GO) was fabricated by modified Hummer’s method and was thermally reduced whereas the tri-metallic nanocomposite was prepared by ex-situ hybridization. Both the synthesized SnO2-NiO-CuO (SNC) and rGO-SnO2-NiO-CuO (GO-SNC) were calcined at 450 °C for 2 h. The degree of crystallinity and the crystallite size were examined through X-ray Diffraction (XRD) analysis and were found to increase with calcination temperature. The morphological changes were examined through scanning electron microscopy (SEM). The surface functional moieties were identified through Fourier transform infrared (FTIR) spectroscopy. Agar well diffusion method was used to evaluate samples against Gram-negative bacteria (E. coli) and Gram-positive bacteria (S. aureus). The antioxidant potential was analyzed against 2,2′-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid (ABTS) and 2,2-diphenyl-1-picryl-hydrazyl-hydrate (DPPH) free radicals and the highest activity was found for the as-synthesized NC whereas a clear decrease was seen in both activities with after calcination at 450 °C. It was also observed that the antibacterial and antioxidant activities increased with increasing sample dose in the reaction

Rheological and Mechanical Study of Micro-Nano Sized Biocarbon-PLA Biodegradable Biocomposites

Pinewood sawdust was pyrolyzed to create a micro-nanocarbon. The adsorbent’s particle size was reduced during a ball milling procedure to improve the surface area and encourage porosity growth. The synergistic effects of micro-nano-adsorbent-reinforced poly(lactic acid) (PLA) composites were investigated by analyzing the efficiency of the rheological process. The properties of the prepared composites also were examined using various characterization tests, including tensile and hardness tests, crystallinity tests, elemental composition, and plasticity behavior tests. Therefore, in-depth investigations and comparisons were also carried out to confirm the created composites’ efficacy compared to other outcomes

Rheological and mechanical study of micro-nano sized biocarbon-PLA biodegradable biocomposites

Pinewood sawdust was pyrolyzed to create a micro-nanocarbon. The adsorbent’s particle size was reduced during a ball milling procedure to improve the surface area and encourage porosity growth. The synergistic effects of micro-nano-adsorbent-reinforced poly(lactic acid) (PLA) composites were investigated by analyzing the efficiency of the rheological process. The properties of the prepared composites also were examined using various characterization tests, including tensile and hardness tests, crystallinity tests, elemental composition, and plasticity behavior tests. Therefore, in-depth investigations and comparisons were also carried out to confirm the created composites’ efficacy compared to other outcomes

Rheological and Mechanical Study of Micro-Nano Sized Biocarbon-PLA Biodegradable Biocomposites

Pinewood sawdust was pyrolyzed to create a micro-nanocarbon. The adsorbent’s particle size was reduced during a ball milling procedure to improve the surface area and encourage porosity growth. The synergistic effects of micro-nano-adsorbent-reinforced poly(lactic acid) (PLA) composites were investigated by analyzing the efficiency of the rheological process. The properties of the prepared composites also were examined using various characterization tests, including tensile and hardness tests, crystallinity tests, elemental composition, and plasticity behavior tests. Therefore, in-depth investigations and comparisons were also carried out to confirm the created composites’ efficacy compared to other outcomes

Synthesis and Characterization of Eco-Friendly Bio-Composite from Fenugreek as a Natural Resource

The present study show the usability of starch (tamarind) based-bio-composite film reinforced by fenugreek by various percentages to replace the traditional petrochemical plastics. The prepared bio-composite films were systematically characterized using the universal testing machine (UTM), soil degradation, scanning electron microscope (SEM), X-ray diffraction (XRD), thermogravimetric analyzer (TGA), and antibacterial tests. The experiments showed that a lower percentage of fenugreek improves biodegradation and mechanical strength. More than 60% of biodegradation occurred in only 30 days. Almost 3 N/mm2 tensile strength and 6.5% tensile strain were obtained. The presence of micropores confirmed by SEM images may accelerate the biodegradation process. Antibacterial activity was observed with two samples of synthesized bio-composite, due to photoactive compounds confirmed by FTIR spectra. The glass transition temperature was shown to be higher than the room temperature, with the help of thermal analysis. The prepared bio-composite containing 5% and 10% fenugreek showed antibacterial activities

Optimization of Ultrasonic-Assisted Enzymatic Extraction of Freeze-Dried Sea Buckthorn (<i>Hippophae rhamnoides</i> L.) Berry Oil Using Response Surface Methodology

The ultrasound-assisted extraction (UAE) of oil has received immense importance nowadays because of the enormous benefits the process offers. However, the literature evaluating this process is scarce for sea buckthorn oil. Furthermore, to date, to the best of our knowledge, a study evaluating the combined use of enzymes and UAE for this oil is lacking. In this study, oil from freeze-dried sea buckthorn berries was extracted using ultrasound-assisted enzymatic extraction (UAEE) and the effect of variables (time, enzyme concentration, and solvent to sample ratio) was evaluated on oil yield and its physiochemical properties (acid value, peroxide value, iodine value, density, and color). The optimum conditions were determined using the response surface methodology. The optimum conditions established were 5.08 mL/g, 14.65 min, and 3.13 U/g for a solvent to sample ratio, ultra-sonication time, and enzyme units, respectively. The oil yield was 18.32%. Physicochemical parameters were found better in UAEE oil than in the Soxhlet-extracted oil. Gas chromatography detected relatively higher levels of fatty acids, including palmitic, palmitoleic, and oleic acids in UAEE oil. The optimum conditions were also verified for adequacy by validation and results were matched with predicted values with 0.8 to 1.5 error %, which states that the model can be utilized to predict oil yield percentage

Extraction and Characterization of Modified Algae Derivative Cellulose and its Mixtures for Dye Removal

A new bio-sorbent derived from green algae biomass, Arthrospira platensis (Spirulina), was found to be economically practical for water decontamination. This biosorbent comprised of microalgae cellulose, poly(lactic acid) (PLA), Dabai activated carbon (AC), and montmorillonite (MMT), each plays a distinctive role in removing methylene blue (MB) dye. The presence of hydroxyl and carbonyl functional groups in algae cellulose, confirmed by the FTIR analysis, offered binding sites for dye removal. Scanning electron microscopy demonstrated the morphological structure of the biosorbent, highlighting the combined effect of microalgae cellulose, PLA, Dabai AC, and MMT mixtures. The inclusion of Dabai AC and MMT improved micropores and mesopores, enhancing adsorption reactions. The Brunauer-Emmett-Teller (BET) analysis confirmed that the sample containing microalgae cellulose, Dabai AC, and MMT clay in PLA had a specific surface area of 0.784 m2/g, three times higher than the PLA + cellulose sample. Additionally, adding 1% MMT to the sample improved the particle dispersion on the surface of the hydrophobic PLA, thereby improving its thermal properties. Remarkably, the biosorbent effectively eliminated 86.8% of MB dye from an initial concentration of 50 mg/L after 60 min of Vis-light irradiation using Ultraviolet-visible spectroscopy

Synthesis and Characterization of Ground Biochar (GB) Reinforced Composites for Removal of Heavy Metal from Palm Oil Mill Effluent (POME)

Heavy metal contamination ruins the ecosystem and water quality. The adsorption method for heavy metal remediation is preferred because of its low cost and high efficiency. This work created eco-friendly ground biochar (GB) biomass-based derivatives reinforced polylactic acid (PLA) with titanium dioxide (TiO2). The composites improved palm oil mill effluent (POME) conditions, and H2SO4 activation increased pores by 80%. PLA and TiO2 altered GB characteristics, according to FTIR analysis. A significant adhesion interaction showed that GB, PLA, and TiO2 particles were compatible. Ball milling's shear force increased surface area, according to Brunauer-Emmett-Teller (BET) research. Particle size reduction increased GB porosity. Scanning electron microscopy (SEM) was used to study the porous structure of GB and the synergistic effect of PLA and TiO2 on POME during treatment. The SEM showed several components on the composite surface, demonstrating its efficacy. Atomic absorption spectroscopy (AAS) showed that sample C's composite, which had the most GB, decreased POME heavy metals by 94.4% manganese (Mn), 88.4% cadmium (Cd), and 94.4% zinc (Zn). The resulting POME met the Malaysian Department of Environment's POME discharge limit by reducing chemical oxygen demand (COD), total suspended solids (TSS), turbidity, and pH