Free energy determination of phase coexistence in model C60: A comprehensive Monte Carlo study

The free energy of the solid and fluid phases of the Girifalco C60 model are determined through extensive Monte Carlo simulations. In this model the molecules interact through a spherical pair potential, characterized by a narrow and attractive well, adjacent to a harshly repulsive core. We have used the Widom test particle method and a mapping from an Einstein crystal, in order to estimate the absolute free energy in the fluid and solid phases, respectively; we have then determined the free energy along several isotherms, and the whole phase diagram, by means of standard thermodynamic integrations. We highlight how the interplay between the liquid-vapor and the liquid-solid coexistence conditions determines the existence of a narrow liquid pocket in the phase diagram, whose stability is assessed and confirmed in agreement with previous studies. In particular, the critical temperature follows closely an extended corresponding-states rule recently outlined by Noro and Frenkel [J. Chem. Phys. 113:2941 (2000)]. We discuss the emerging "energetic" properties of the system, which drive the phase behavior in systems interacting through short-range forces [A. A. Louis, Phil. Trans. R. Soc. A 359:939 (2001)], in order to explain the discrepancy between the predictions of several structural indicators and the results of full free energy calculations, to locate the fluid phase boundaries. More generally, we aim to provide extended reference data for calculations of the free energy of the C60 fullerite in the low temperature regime, as for the determination of the phase diagram of higher order fullerenes and other fullerene-related materials, whose description is based on the same model adopted in this work.Comment: RevTeX, 11 pages, 9 figure

Kaons and pions in strange quark matter

The behavior of kaons and pions in strange quark matter in weak equilibrium, is investigated within the SU(3) Nambu-Jona-Lasinio [NJL] model. This work focuses a region of high densities where the behavior of mesons has not been explored in the framework of this model. It is found that above the density where strange valence quarks appear in the medium, $\rho = 3.8 \rho_0$, a change of behavior of different observables is observed indicating a tendency to the restoration of flavor symmetry. In particular, the splitting between charge multiplets, $K^+, K^-; K^0, {\bar K^0} {and} \pi^+, \pi^-$ decrease and the low energy modes with quantum numbers of $K^-, \bar K^0 {and} \pi^+$, which are excitations of the Fermi sea, are less relevant than for lower densities.Comment: 10 pages, 3 figures included; revised version, some changes in the discussio

Interplay between chiral and axial symmetries in a SU(2) Nambu--Jona-Lasinio Model with the Polyakov loop

We consider a two flavor Polyakov--Nambu--Jona-Lasinio (PNJL) model where the Lagrangian includes an interaction term that explicitly breaks the U$_A(1)$ anomaly. At finite temperature, the restoration of chiral and axial symmetries, signaled by the behavior of several observables, is investigated. We compare the effects of two regularizations at finite temperature, one of them, that allows high momentum quarks states, leading to the full recovery of chiral symmetry. From the analysis of the behavior of the topological susceptibility and of the mesonic masses of the axial partners, it is found in the SU(2) model that, unlike the SU(3) results, the recovery of the axial symmetry is not a consequence of the full recovery of the chiral symmetry. Thus, one needs to use an additional idea, by means of a temperature dependence of the anomaly coefficient, that simulates instanton suppression effects.Comment: 21 pages, 5 figures; PRD versio

Presumed Neuroglycopenia Caused by Severe Hypoglycemia in Horses.

BackgroundNeuroglycopenia refers to a shortage of glucose in the brain resulting in neuronal dysfunction and death if left untreated. Presumed neuroglycopenia has not been described in horses.ObjectiveTo report neurological signs in horses with presumed neuroglycopenia as the result of severe hypoglycemia.AnimalsNinety horses (hours to 28 years of age) diagnosed with hypoglycemia (blood glucose concentration < 75 mg/dL [< 4.2 mmol/L]).MethodsRetrospective study. Electronic medical records were searched. Signalment, history, complaint, clinical signs, laboratory findings including CSF analysis, electroencephalogram, clinical or definitive diagnosis, and outcome were recorded. Kruskal-Wallis analysis of variance and logistic regression were used to investigate association between blood glucose concentration and data extracted. Statistical significance was set at P < 0.05.ResultsThirty-eight and 52 horses had mild (50-74 mg/dL [2.8-4.1 mmol/L]), and severe hypoglycemia (< 50 mg/dL [< 2.8 mmol/L]), respectively. Most common causes of hypoglycemia included liver and gastrointestinal (40%) disease, sepsis (33%), neoplasia (7%), and insulin-induced (4%). Most common neurologic deficits included obtundation (100%), seizures (42%), and disorientation (22%). CSF-glucose was severely low (mean 2.5 mg/dL [0.1 mmol/L], median 0 mg/dL). Paroxysmal discharges in support of seizures were identified in the occipital (visual) and parietal (closest to temporal-auditory) cortical regions upon EEG examination (8/8 horses).Conclusions and clinical importanceNeuroglycopenia is presumed to occur in horses as the result of severe hypoglycemia. Subclinical seizures, and intermittent blindness and deafness of cortical origin can occur. Severe altered state of consciousness and seizures can be observed at a blood glucose cut-off value of < 42 mg/dL (< 2.3 mmol/L)