Magnetic field symmetry of pump currents of adiabatically driven mesoscopic structures

We examine the scattering properties of a slowly and periodically driven mesoscopic sample using the Floquet function approach. One might expect that at sufficiently low driving frequencies it is only the frozen scattering matrix which is important. The frozen scattering matrix reflects the properties of the sample at a given instant of time. Indeed many aspects of adiabatic scattering can be described in terms of the frozen scattering matrix. However, we demonstrate that the Floquet scattering matrix, to first order in the driving frequency, is determined by an additional matrix which reflects the fact that the scatterer is time-dependent. This low frequency irreducible part of the Floquet matrix has symmetry properties with respect to time and/or a magnetic field direction reversal opposite to that of the frozen scattering matrix. We investigate the quantum rectification properties of a pump which additionally is subject to an external dc voltage. We split the dc current flowing through the pump into several parts with well defined properties with respect to a magnetic field and/or an applied voltage inversion.Comment: 13 pages, 4 figure

How Bulk Sensitive is Hard X-ray Photoelectron Spectroscopy: Accounting for the Cathode-Electrolyte Interface when Addressing Oxygen Redox.

Sensitivity to the "bulk" oxygen core orbital makes hard X-ray photoelectron spectroscopy (HAXPES) an appealing technique for studying oxygen redox candidates. Various studies have reported an additional O 1s peak (530-531 eV) at high voltages, which has been considered a direct signature of the bulk oxygen redox process. Here, we find the emergence of a 530.4 eV O 1s HAXPES peak for three model cathodes-Li2MnO3, Li-rich NMC, and NMC 442-that shows no clear link to oxygen redox. Instead, the 530.4 eV peak for these three systems is attributed to transition metal reduction and electrolyte decomposition in the near-surface region. Claims of oxygen redox relying on photoelectron spectroscopy must explicitly account for the surface sensitivity of this technique and the extent of the cathode degradation layer

Probing the Protostellar Envelope around L1157: the Dust and Gas Connection

We present observations of the Class 0 protostar L1157-mm using the Combined Array for Research in Millimeter-wave Astronomy (CARMA) in 3 mm dust continuum and N2H+ line emission. In the N2H+ line, we detect a large-scale envelope extended over a linear size of ~20,000AU flattened in the direction perpendicular to the outflow. This N2H+ feature coincides with the outer envelope seen in the 8 micron extinction by Looney et al. Meanwhile, the dust continuum traces the compact, nearly spherical structure of the inner envelope, where N2H+ becomes depleted. This highly flattened N2H+ envelope also shows dynamical signatures consistent with gravitational infall in the inner region, but a slow, solid-body rotation at large scales. This flattened structure is not a rotationally supported circumstellar disk; instead, it resembles a prestellar core both morphologically and kinematically, representing the early phase of a Class 0 system. In this paper, we construct a simple model to interpret both the dust continuum and N2H+ emission and suggest a possible dynamical scenario for the overall properties of the envelope.Comment: Accepted for publication by the ApJ, 34 pages, 10 figures and 2 table

Making Sense of Corporate Tour-Guide Bloggers’ Networking Behavior: A Social Network Perspective

Drawing on studies of social networks and technology sensemaking, this study examines tour guide bloggers’ perceptions of their corporate blogs and how their perceptions and interpretations lead to different types of relationships in their blog networks. We conduct a qualitative case study of a major Taiwanese travel agency. Our findings suggest that corporate bloggers as actors make different senses on blogging and these senses lead them to establish different levels of closeness to their alters (other network actors). Providing social support and especially material support play significant roles in aggrandizing the transitivity, which help to attract more visitors to their blogs. However, the innovation and potential connections that may follow from the individualistic styles of some bloggers in addition to the hedonic emotional support to a travel blog should not be overlooked. Corporate bloggers should thus consider offering more incentives and should be given freedom to prosper in their grassroots use of technology

Externally Fed Accretion onto Protostars

The asymmetric molecular emission lines from dense cores reveal slow, inward motion in the clouds' outer regions. This motion is present both before and after the formation of a central star. Motivated by these observations, we revisit the classic problem of steady, spherical accretion of gas onto a gravitating point mass, but now include self-gravity of the gas and impose a finite, subsonic velocity as the outer boundary condition. We find that the accretion rate onto the protostar is lower than values obtained for isolated, collapsing clouds, by a factor that is the Mach number of the outer flow. Moreover, the region of infall surrounding the protostar spreads out more slowly, at a speed close to the subsonic, incoming velocity. Our calculation, while highly idealized, provides insight into two longstanding problems -- the surprisingly low accretion luminosities of even the most deeply embedded stellar sources, and the failure so far to detect spatially extended, supersonic infall within their parent dense cores. Indeed, the observed subsonic contraction in the outer regions of dense cores following star formation appears to rule out a purely hydrodynamic origin for these clouds.Comment: accepted by MNRA

Solution of the Nuclear Shell Model by Symmetry-Dictated Truncation

The dynamical symmetries of the Fermion Dynamical Symmetry Model are used as a principle of truncation for the spherical shell model. Utilizing the usual principle of energy-dictated truncation to select a valence space, and symmetry-dictated truncation to select a collective subspace of that valence space, we are able to reduce the full shell model space to one of manageable dimensions with modern supercomputers, even for the heaviest nuclei. The resulting shell model then consists of diagonalizing an effective Hamiltonian within the restricted subspace. This theory is not confined to any symmetry limits, and represents a full solution of the original shell model if the appropriate effective interaction of the truncated space can be determined. As a first step in constructing that interaction, we present an empirical determination of its matrix elements for the collective subspace with no broken pairs in a representative set of nuclei with $130\le A \le 250$. We demonstrate that this effective interaction can be parameterized in terms of a few quantities varying slowly with particle number, and is capable of describing a broad range of low-energy observables for these nuclei. Finally we give a brief discussion of extending these methods to include a single broken collective pair.Comment: invited paper for J. Phys. G, 57 pages, Latex, 18 figures a macro are available under request at [email protected]

Floquet states and persistent currents transitions in a mesoscopic ring

We consider the effect of an oscillating potential on the single-particle spectrum and the time-averaged persistent current of a one-dimensional phase-coherent mesoscopic ring with a magnetic flux. We show that in a ring with an even number of spinless electrons the oscillating potential has a strong effect on the persistent current when the excited side bands are close to the eigen levels of a pure ring. Resonant enhancement of side bands of the Floquet state generates a sign change of the persistent current.Comment: 2 figure

Quantifying Inactive Lithium in Lithium Metal Batteries

Inactive lithium (Li) formation is the immediate cause of capacity loss and catastrophic failure of Li metal batteries. However, the chemical component and the atomic level structure of inactive Li have rarely been studied due to the lack of effective diagnosis tools to accurately differentiate and quantify Li+ in solid electrolyte interphase (SEI) components and the electrically isolated unreacted metallic Li0, which together comprise the inactive Li. Here, by introducing a new analytical method, Titration Gas Chromatography (TGC), we can accurately quantify the contribution from metallic Li0 to the total amount of inactive Li. We uncover that the Li0, rather than the electrochemically formed SEI, dominates the inactive Li and capacity loss. Using cryogenic electron microscopies to further study the microstructure and nanostructure of inactive Li, we find that the Li0 is surrounded by insulating SEI, losing the electronic conductive pathway to the bulk electrode. Coupling the measurements of the Li0 global content to observations of its local atomic structure, we reveal the formation mechanism of inactive Li in different types of electrolytes, and identify the true underlying cause of low Coulombic efficiency in Li metal deposition and stripping. We ultimately propose strategies to enable the highly efficient Li deposition and stripping to enable Li metal anode for next generation high energy batteries

Floquet scattering theory of quantum pumps

We develop the Floquet scattering theory for quantum mechanical pumping in mesoscopic conductors. The nonequilibrium distribution function, the dc charge and heat currents are investigated at arbitrary pumping amplitude and frequency. For mesoscopic samples with discrete spectrum we predict a sign reversal of the pumped current when the pump frequency is equal to the level spacing in the sample. This effect allows to measure the phase of the transmission coefficient through the mesoscopic sample. We discuss the necessary symmetry conditions (both spatial and temporal) for pumping.Comment: 11 pages, 5 figure