Side-View Operando Optical Microscopy Analysis of a Graphite Anode to Study Its Kinetic Hysteresis

Operando analyses have provided several breakthroughs in the construction of high-performance materials and devices, including energy storage systems. However, despite the advances in electrode engineering, the formidable issues of lithium intercalation and deintercalation kinetics cannot be investigated by using planar observations. This study concerns side-view operando observation by optical microscopy of a graphite anode based on its color changes during electrochemical lithiation. Since the graphite color varies according to the optical energy gap during lithiation and delithiation, this technique can be used to study the corresponding charge-discharge kinetics. In addition, the cell configuration uses liquid electrolytes similar to commercial cells, allowing practical application. Furthermore, this side-view observation has shown that microscale spatial variations in rate and composition control the insertion and deinsertion, revealing the kinetics throughout the whole electrode. The results of this study could enhance the fundamental understanding of the kinetics of battery materials

Tuning Locality of Pair Coherence in Graphene-based Andreev Interferometers

We report on gate-tuned locality of superconductivity-induced phase-coherent magnetoconductance oscillations in a graphene-based Andreev interferometer, consisting of a T-shaped graphene bar in contact with a superconducting Al loop. The conductance oscillations arose from the flux change through the superconducting Al loop, with gate-dependent Fraunhofer-type modulation of the envelope. We confirm a transitional change in the character of the pair coherence, between local and nonlocal, in the same device as the effective length-to-width ratio of the device was modulated by tuning the pair-coherence length xi(T) in the graphene layer.open1133sciescopu

Curvature-enhanced spin-orbit coupling in a carbon nanotube

Structure of the spin-orbit coupling varies from material to material and thus finding the correct spin-orbit coupling structure is an important step towards advanced spintronic applications. We show theoretically that the curvature in a carbon nanotube generates two types of the spin-orbit coupling, one of which was not recognized before. In addition to the topological phase-related contribution of the spin-orbit coupling, which appears in the off-diagonal part of the effective Dirac Hamiltonian of carbon nanotubes, there is another contribution that appears in the diagonal part. The existence of the diagonal term can modify spin-orbit coupling effects qualitatively, an example of which is the electron-hole asymmetric spin splitting observed recently, and generate four qualitatively different behavior of energy level dependence on parallel magnetic field. It is demonstrated that the diagonal term applies to a curved graphene as well. This result should be valuable for spintronic applications of graphitic materials.Comment: 6 pages, 4 figures, to be published on Physical Review

Ballistic spin field-effect transistors: Multichannel effects

We study a ballistic spin field-effect transistor (SFET) with special attention to the issue of multi-channel effects. The conductance modulation of the SFET as a function of the Rashba spin-orbit coupling strength is numerically examined for the number of channels ranging from a few to close to 100. Even with the ideal spin injector and collector, the conductance modulation ratio, defined as the ratio between the maximum and minimum conductances, decays rapidly and approaches one with the increase of the channel number. It turns out that the decay is considerably faster when the Rashba spin-orbit coupling is larger. Effects of the electronic coherence are also examined in the multi-channel regime and it is found that the coherent Fabry-Perot-like interference in the multi-channel regime gives rise to a nested peak structure. For a nonideal spin injector/collector structure, which consists of a conventional metallic ferromagnet-thin insulator-2DEG heterostructure, the Rashba-coupling-induced conductance modulation is strongly affected by large resonance peaks that arise from the electron confinement effect of the insulators. Finally scattering effects are briefly addressed and it is found that in the weakly diffusive regime, the positions of the resonance peaks fluctuate, making the conductance modulation signal sample-dependent.Comment: 18 pages, 15 figure

Sonographic measurements of normal gallbladder sizes in children.

PurposeOur goal was to establish the range of sonographic measurements of normal gallbladders in children.MethodsSix hundred ten children aged 0-16 years (male:female ratio, 1.5:1) with normal clinical and laboratory findings were included in this study. The sonographic parameters were the length, width, and calculated volume of the gallbladder, and the clinical parameters were the age, height, weight, and body surface area of the children. Statistical significance was determined through correlation and regression analyses.ResultsThe length of the gallbladder showed significant positive correlations with age (r = 0.65), height (r = 0.67), weight (r = 0.63), and body surface area (r = 0.65; p < 0.01). The calculated volume of the gallbladder also showed moderate correlations with age (r = 0.53), height (r = 0.55), weight (r = 0.61), and body surface area (r = 0.57; p < 0.01). The gallbladder width showed modest but significant correlations with age (r = 0.48), height (r = 0.53), weight (r = 0.53), and body surface area (r = 0.55; p < 0.01). The highest correlation coefficients were found between the gallbladder length and subject age (r = 0.65; p < 0.01) and between the gallbladder length and subject height (r = 0.67; p < 0.01). For all correlations, statistical significance remained after regression analysis (p < 0.01).ConclusionsValues for the size of the normal pediatric gallbladder are defined and will be helpful in the diagnosis of gallbladder abnormalities