3D Printable Organohydrogel with Long-Lasting Moisture and Extreme-Temperature Tolerance for Flexible Electronics

Hydrogels with high electrical conductivity and mechanical stretchability are promising materials for flexible electronics. However, traditional hydrogels are applied in short-term usage at room temperature or low temperature due to their poor water-retention ability and freezing-tolerance property. Here, a dually cross-linked glycerol–organohydrogel (GL–organohydrogel) based on GL and acrylic acid was synthesized in a GL–water binary solvent. Fe3+ ions working as an electrolyte were added to improve the conductivity of the organohydrogel and form coordination interactions between Fe3+ ions and carboxyl groups of acrylic acid. The strong hydrogen bonding between GL and water molecules firmly lock water in the organohydrogel network, thereby endowing the GL–organohydrogel with the antifreezing property, long-term stability, and moisture lock-in capability. Our organohydrogel could endure extremely low temperature (−80 °C) over 30 days without freezing and retain its water content (almost 100% of its initial state) after being stored at room temperature (25 °C, 54% humidity) for 30 days. It also demonstrated desired stretchable properties, conductivity, three-dimensional (3D) printability, and self-healing ability. A wearable data glove was constructed by using the GL–organohydrogel and digital light processing technology. This work opens a new avenue for developing hydrogels with long-term stability, moisture lock-in capability, and extreme-temperature tolerance for stretchable electronics

3D Printable Organohydrogel with Long-Lasting Moisture and Extreme-Temperature Tolerance for Flexible Electronics

Hydrogels with high electrical conductivity and mechanical stretchability are promising materials for flexible electronics. However, traditional hydrogels are applied in short-term usage at room temperature or low temperature due to their poor water-retention ability and freezing-tolerance property. Here, a dually cross-linked glycerol–organohydrogel (GL–organohydrogel) based on GL and acrylic acid was synthesized in a GL–water binary solvent. Fe3+ ions working as an electrolyte were added to improve the conductivity of the organohydrogel and form coordination interactions between Fe3+ ions and carboxyl groups of acrylic acid. The strong hydrogen bonding between GL and water molecules firmly lock water in the organohydrogel network, thereby endowing the GL–organohydrogel with the antifreezing property, long-term stability, and moisture lock-in capability. Our organohydrogel could endure extremely low temperature (−80 °C) over 30 days without freezing and retain its water content (almost 100% of its initial state) after being stored at room temperature (25 °C, 54% humidity) for 30 days. It also demonstrated desired stretchable properties, conductivity, three-dimensional (3D) printability, and self-healing ability. A wearable data glove was constructed by using the GL–organohydrogel and digital light processing technology. This work opens a new avenue for developing hydrogels with long-term stability, moisture lock-in capability, and extreme-temperature tolerance for stretchable electronics

Coassembly of Tobacco Mosaic Virus Coat Proteins into Nanotubes with Uniform Length and Improved Physical Stability

Using tobacco mosaic virus coat proteins (TMVcp) from both sources of the plant and bacterial expression systems as building blocks, we demonstrate here a coassembly strategy of TMV nanotubes in the presence of RNA. Specifically, plant-expressed cp (cp_p) efficiently dominates the genomic RNA encapsidation to determine the length of assembled TMV nanotubes, whereas the incorporated <i>Escherichia coli-</i>expressed cp (cp_ec) improves the physical stability of TMV nanotubes by introducing disulfide bonds between the interfaces of subunits. We expect this coassembly strategy can be expanded to other virus nanomaterials to obtain desired properties based on rationally designed protein–RNA and protein–protein interfacial interactions

DataSheet1_Dam construction reshapes heavy metal pollution in soil/sediment in the three gorges reservoir, China, from 2008 to 2020.docx

Dam construction interfered with the original environment of the river system and greatly affected the geochemical behaviors of trace metals. Thus, a set of toxic metals of Cr, Ni, Cu, Zn, As, Cd, Pb and Hg in soil/sediment of the Three Gorges Reservoir (TGR) during the period of 2008–2020 were analyzed and summarized. The results showed that levels of trace metals (except Cr) were apparently higher than the soil background in the TGR and China, in which Cu, Zn, As, Cd, Pb and Hg corresponded to the moderately to highly contaminated grade. As expected, most trace metals (except Ni and As) were observed an evident increase after the full impoundment stage of 2008–2014, suggesting the dam construction of the TGR that promoting the sediment adsorption effects for trace metals. For spatial patterns, metal levels largely depended on the sampling sites, that intensive anthropogenic activities might well be the primary contributors. Main stream with higher concentrations of trace metals in comparison with tributaries reflected the larger loads of metal pollution. In the water-level-fluctuating zone, hydrological regime induced by damming played a critical role on the redistribution of trace metals through eroding soil/sediment particles or bedrocks and altering the physiochemical characteristics and vegetation coverage of soil/sediment. Finally, submerged sediment seemed as a major sink of trace metals that had greater concentration than that in the water-level-fluctuating zone.</p

A global dataset for prevalence of Salmonella Gallinarum between 1945 and 2021

Standard operating procedures were applied to remove duplicates and ensure accuracy of up-to-date results from available articles involving the prevalence of S. Gallinarum. It's the world’s largest dataset ever, including 201 independent studies between 1945 and 2021, covering 520 records of 901,491,709 million samples.<br

Selective in Situ Assembly of Viral Protein onto DNA Origami

Engineering hybrid protein–DNA assemblies in a controlled manner has attracted particular attention, for their potential applications in biomedicine and nanotechnology due to their intricate folding properties and important physiological roles. Although DNA origami has served as a powerful platform for spatially arranging functional molecules, <i>in situ</i> assembly of proteins onto DNA origami is still challenging, especially in a precisely controlled and facile manner. Here, we demonstrate <i>in situ</i> assembly of tobacco mosaic virus (TMV) coat proteins onto DNA origami to generate programmable assembly of hybrid DNA origami–protein nanoarchitectures. The protein nanotubes of controlled length are precisely anchored on the DNA origami at selected locations using TMV genome-mimicking RNA strands. This study opens a new route to the organization of protein and DNA into sophisticated protein–DNA nanoarchitectures by harnessing the viral encapsidation mechanism and the programmability of DNA origami

Additional file 1 of Reverse complete heart block using transcutaneous pacing and repeated plasmapheresis in a neonate with lupus: a case report

Supplementary Material

Simultaneous Fractionation, Desalination, and Dye Removal of Dye/Salt Mixtures by Carbon Cloth-Modified Flow-electrode Capacitive Deionization

The critical challenges of using electromembrane processes [e.g., electrodialysis and flow-electrode capacitive deionization (FCDI)] to recycle resources (e.g., water, salts, and organic compounds) from wastewater are the fractionation of dissolved ionic matter, the removal/recovery of organic components during desalination, and membrane antifouling. This study realized the simultaneous fractionation, desalination, and dye removal/recovery (FDR) treatment of dye/salt mixtures through a simple but effective approach, that is, using a carbon cloth-modified FCDI (CC-FCDI) unit, in which the carbon cloth layer was attached to the surface of each ion-exchange membrane (IEM). The IEMs and carbon-based flow-electrodes were responsible for the fractionation and desalination of dye and salt ions, while the carbon cloth layers contributed to the active membrane antifouling and dye removal/recovery by the electrosorption mechanism. Attributed to such features, the CC-FCDI unit accomplished the effective FDR treatment of dye/salt mixtures with wide ranges of salt and dye concentrations (5–20 g L–1 NaCl and 200–800 ppm methylene blue) and different dye components (cationic and anionic dyes) under various applied voltages (1.2–3.2 V). Moreover, the active membrane antifouling by virtue of the carbon cloth facilitated the excellent and sustainable FDR performance of CC-FCDI. The removal/recovery of dyes from the carbon cloth strongly depends on the characteristics of dye molecules, the surface properties of the carbon cloth, and the local pH at the IEM/CC interfaces. This study sheds light on the strategies of using multifunctional layer-modified FCDI units to reclaim resources from various high-salinity organic wastewater

Simultaneous Fractionation, Desalination, and Dye Removal of Dye/Salt Mixtures by Carbon Cloth-Modified Flow-electrode Capacitive Deionization

The critical challenges of using electromembrane processes [e.g., electrodialysis and flow-electrode capacitive deionization (FCDI)] to recycle resources (e.g., water, salts, and organic compounds) from wastewater are the fractionation of dissolved ionic matter, the removal/recovery of organic components during desalination, and membrane antifouling. This study realized the simultaneous fractionation, desalination, and dye removal/recovery (FDR) treatment of dye/salt mixtures through a simple but effective approach, that is, using a carbon cloth-modified FCDI (CC-FCDI) unit, in which the carbon cloth layer was attached to the surface of each ion-exchange membrane (IEM). The IEMs and carbon-based flow-electrodes were responsible for the fractionation and desalination of dye and salt ions, while the carbon cloth layers contributed to the active membrane antifouling and dye removal/recovery by the electrosorption mechanism. Attributed to such features, the CC-FCDI unit accomplished the effective FDR treatment of dye/salt mixtures with wide ranges of salt and dye concentrations (5–20 g L–1 NaCl and 200–800 ppm methylene blue) and different dye components (cationic and anionic dyes) under various applied voltages (1.2–3.2 V). Moreover, the active membrane antifouling by virtue of the carbon cloth facilitated the excellent and sustainable FDR performance of CC-FCDI. The removal/recovery of dyes from the carbon cloth strongly depends on the characteristics of dye molecules, the surface properties of the carbon cloth, and the local pH at the IEM/CC interfaces. This study sheds light on the strategies of using multifunctional layer-modified FCDI units to reclaim resources from various high-salinity organic wastewater