16 research outputs found
A Post-Functionalizable <i>Iso</i>-Polyoxotitanate Cage Cluster
During solvothermal
alcoholysis of a mixture of TiI<sub>4</sub> and TiÂ(O<sup><i>i</i></sup>Pr)<sub>4</sub>, a {I@Ti<sub>22</sub>} cage cluster encapsulating
an OH and iodide guests is crystallized. The {I@Ti<sub>22</sub>} host–guest
cluster surface is postfunctionalizable with catecholate and carboxylate
ligands. The synthetic details, structural characterization, spectroscopic
properties of the obtained cages clusters are provided. The present
study provides candidates for modeling ligand exchange and electron-hole
transfer at the titanate nanoparticle surface, and meanwhile offers
new opportunities for understanding the TiO<sub>2</sub> nanocrystalline
formation in solvothermal processes
Detection of Clinical Specimens by mRT-PCR.
<p>Detection of Clinical Specimens by mRT-PCR.</p