Data_Sheet_1_Mechanically Robust and Thermally Stable Colorful Superamphiphobic Coatings.PDF

Colorful super anti-wetting coatings are receiving growing attention, but are challenging to invent. Here, we report a general method for preparing mechanically robust and thermally stable colorful superamphiphobic coatings. A composite of palygorskite (PAL) nanorods and iron oxide red (IOR) was prepared by solid-state grinding or hydrothermal reaction, which was then modified by hydrolytic condensation of silanes to form a suspension. Superamphiphobic coatings were prepared by spray-coating the suspension onto substrates. The superamphiphobicity depends upon the surface microstructure and chemical composition, which are controllable by the PAL/IOR concentration and the solid-state grinding time. The colorful coatings show excellent superamphiphobicity with high contact angles and low sliding angles for water and various organic liquids of low surface tension, e.g., toluene and n-decane. The coatings also feature high mechanical, chemical and thermal stability, which is superior to all the reported colorful super anti-wetting coatings. Moreover, superamphiphobic coatings of different colors can be prepared via the same procedure using the other metal oxides instead of IOR. We believe the colorful superamphiphobic coatings may find applications in many fields like anti-climbing of oils and restoration of cultural relics, as the coatings are applicable onto various substrates.</p

Green Synthesis of Ant Nest-Inspired Superelastic Silicone Aerogels

Green synthesis of aerogels with high mechanical properties has long remained a big challenge ever since Kistler’s report in 1931. Inspired by ant nests, we report a green method to synthesize strong, superelastic and flexible silicone aerogels. The aerogels are prepared by hydrolytic condensation of silanes with trace amounts of catalyst and surfactant (0.094 mmol mol^–1) followed by drying the hydrogels at ambient pressure. The aerogels can quickly recover their original shape after repeated compression and bending. The aerogels can be functionalized via their Si–OH or vinyl groups for specific purposes. We also extend the method for forming aerogel coatings on diverse types of materials. Our study demonstrates that green synthesis of superelastic aerogels is feasible and bioinspiration is an efficient strategy

Design of Waterborne Superhydrophobic Fabrics with High Impalement Resistance and Stretching Stability by Constructing Elastic Reconfigurable Micro-/Micro-/Nanostructures

Superhydrophobic fabrics have great application potential in many fields including wearable electronic devices, sports textiles, and human health monitoring, but good water impalement resistance and stretching stability are the prerequisites. Here, we report the design of waterborne superhydrophobic fabrics with high impalement resistance and stretching stability by constructing elastic reconfigurable micro-/micro-/nanostructures. Following theoretical analysis, two approaches were proposed and employed: (i) regulating distance between the microfibers of polyester fabrics to decrease the solid–liquid contact area, and (ii) forming reconfigurable two-tier hierarchical micro-/nanostructures on the microfibers by stretching during dipping to further decrease the solid–liquid contact area. The effects of microfiber distance and micro-/nanostructures on microfibers on superhydrophobicity and impalement resistance were studied. The superhydrophobic fabrics show excellent impalement resistance as verified by high-speed water impact, water jetting, and rainfall, etc. The fabrics also show excellent stretching stability, as 100% stretching and 1000 cycles of cyclic 100% stretching–releasing have no obvious influence on superhydrophobicity. Additionally, the fabrics show good antifouling property, self-cleaning performance, as well as high abrasion and washing stability. The experimental results agree with the theoretical simulation very well. We anticipate that this study will boost the development of impalement-resistant and stretching-stable superhydrophobic surfaces

A prediction model for cesarean delivery based on the glycemia in the second trimester: a nested case control study from two centers

Maternal glycemia is associated with the risk of cesarean delivery (CD); therefore, our study aims to developed a prediction model based on glucose indicators in the second trimester to earlier identify the risk of CD. This was a nested case-control study, and data were collected from the 5th Central Hospital of Tianjin (training set) and Changzhou Second People’s Hospital (testing set) from 2020 to 2021. Variables with significant difference in training set were incorporated to develop the random forest model. Model performance was assessed by calculating the area under the curve (AUC) and Komogorov-Smirnoff (KS), as well as accuracy, sensitivity, specificity, positive predictive value (PPV), and negative predictive value (NPV). A total of 504 eligible women were enrolled; of these, 169 underwent CD. Pre-pregnancy body mass index (BMI), first pregnancy, history of full-term birth, history of livebirth, 1 h plasma glucose (1hPG), glycosylated hemoglobin (HbA1c), fasting plasma glucose (FPG), and 2 h plasma glucose (2hPG) were used to develop the model. The model showed a good performance, with an AUC of 0.852 [95% confidence interval (CI): 0.809–0.895]. The pre-pregnancy BMI, 1hPG, 2hPG, HbA1c, and FPG were identifies as the more significant predictors. External validation confirmed the good performance of our model, with an AUC of 0.734 (95%CI: 0.664–0.804). Our model based on glucose indicators in the second trimester performed well to predict the risk of CD, which may reach the earlier identification of CD risk and may be beneficial to make interventions in time to decrease the risk of CD.</p

Design of Waterborne Superhydrophobic Fabrics with High Impalement Resistance and Stretching Stability by Constructing Elastic Reconfigurable Micro-/Micro-/Nanostructures

Superhydrophobic fabrics have great application potential in many fields including wearable electronic devices, sports textiles, and human health monitoring, but good water impalement resistance and stretching stability are the prerequisites. Here, we report the design of waterborne superhydrophobic fabrics with high impalement resistance and stretching stability by constructing elastic reconfigurable micro-/micro-/nanostructures. Following theoretical analysis, two approaches were proposed and employed: (i) regulating distance between the microfibers of polyester fabrics to decrease the solid–liquid contact area, and (ii) forming reconfigurable two-tier hierarchical micro-/nanostructures on the microfibers by stretching during dipping to further decrease the solid–liquid contact area. The effects of microfiber distance and micro-/nanostructures on microfibers on superhydrophobicity and impalement resistance were studied. The superhydrophobic fabrics show excellent impalement resistance as verified by high-speed water impact, water jetting, and rainfall, etc. The fabrics also show excellent stretching stability, as 100% stretching and 1000 cycles of cyclic 100% stretching–releasing have no obvious influence on superhydrophobicity. Additionally, the fabrics show good antifouling property, self-cleaning performance, as well as high abrasion and washing stability. The experimental results agree with the theoretical simulation very well. We anticipate that this study will boost the development of impalement-resistant and stretching-stable superhydrophobic surfaces

Design of Waterborne Superhydrophobic Fabrics with High Impalement Resistance and Stretching Stability by Constructing Elastic Reconfigurable Micro-/Micro-/Nanostructures

Superhydrophobic fabrics have great application potential in many fields including wearable electronic devices, sports textiles, and human health monitoring, but good water impalement resistance and stretching stability are the prerequisites. Here, we report the design of waterborne superhydrophobic fabrics with high impalement resistance and stretching stability by constructing elastic reconfigurable micro-/micro-/nanostructures. Following theoretical analysis, two approaches were proposed and employed: (i) regulating distance between the microfibers of polyester fabrics to decrease the solid–liquid contact area, and (ii) forming reconfigurable two-tier hierarchical micro-/nanostructures on the microfibers by stretching during dipping to further decrease the solid–liquid contact area. The effects of microfiber distance and micro-/nanostructures on microfibers on superhydrophobicity and impalement resistance were studied. The superhydrophobic fabrics show excellent impalement resistance as verified by high-speed water impact, water jetting, and rainfall, etc. The fabrics also show excellent stretching stability, as 100% stretching and 1000 cycles of cyclic 100% stretching–releasing have no obvious influence on superhydrophobicity. Additionally, the fabrics show good antifouling property, self-cleaning performance, as well as high abrasion and washing stability. The experimental results agree with the theoretical simulation very well. We anticipate that this study will boost the development of impalement-resistant and stretching-stable superhydrophobic surfaces

Design of Waterborne Superhydrophobic Fabrics with High Impalement Resistance and Stretching Stability by Constructing Elastic Reconfigurable Micro-/Micro-/Nanostructures

Superhydrophobic fabrics have great application potential in many fields including wearable electronic devices, sports textiles, and human health monitoring, but good water impalement resistance and stretching stability are the prerequisites. Here, we report the design of waterborne superhydrophobic fabrics with high impalement resistance and stretching stability by constructing elastic reconfigurable micro-/micro-/nanostructures. Following theoretical analysis, two approaches were proposed and employed: (i) regulating distance between the microfibers of polyester fabrics to decrease the solid–liquid contact area, and (ii) forming reconfigurable two-tier hierarchical micro-/nanostructures on the microfibers by stretching during dipping to further decrease the solid–liquid contact area. The effects of microfiber distance and micro-/nanostructures on microfibers on superhydrophobicity and impalement resistance were studied. The superhydrophobic fabrics show excellent impalement resistance as verified by high-speed water impact, water jetting, and rainfall, etc. The fabrics also show excellent stretching stability, as 100% stretching and 1000 cycles of cyclic 100% stretching–releasing have no obvious influence on superhydrophobicity. Additionally, the fabrics show good antifouling property, self-cleaning performance, as well as high abrasion and washing stability. The experimental results agree with the theoretical simulation very well. We anticipate that this study will boost the development of impalement-resistant and stretching-stable superhydrophobic surfaces

Design of a Separated Solar Interfacial Evaporation System for Simultaneous Water and Salt Collection

Solar-driven interfacial evaporation (SIE) is very promising to alleviate the freshwater scarcity issue. However, salt deposition on the sample surface will reduce evaporation performance, and compromised light absorption will result in a low water collection rate in conventional SIE apparatuses. Here, we report the design of a separated SIE system composed of a polypyrrole@Co3O4@aluminum sheet and a T-shaped superhydrophilic polyethylene/polypropylene nonwoven fabric right under the sheet. The photothermal surface exposed outside the closed SIE system is separated from the evaporation surface. Thus, salt fouling of solar evaporators is thoroughly avoided and the freshwater collection rate is greatly enhanced. Compared with conventional SIE systems, the separated SIE system has many advantages: simultaneous water and salt collection, a long-term stable evaporation rate even for concentrated brine (1.25 kg m–2 h–1 under 1 kW m–2 (1 sun) illumination, 15 wt % NaCl(aq), ≥120 h), high salt collection efficiency (≥97%), and a high water collection rate under natural sunlight, e.g., 0.72 kg m–2 h–1 in early spring (0.5–0.6 sun, 19–24 °C) and 0.33 kg m–2 h–1 in cold winter (0.3–0.4 sun, −6 to 4 °C). We foresee that the separated SIE system holds great potential for practical freshwater and salt collection from seawater

Design of Waterborne Superhydrophobic Fabrics with High Impalement Resistance and Stretching Stability by Constructing Elastic Reconfigurable Micro-/Micro-/Nanostructures

Superhydrophobic fabrics have great application potential in many fields including wearable electronic devices, sports textiles, and human health monitoring, but good water impalement resistance and stretching stability are the prerequisites. Here, we report the design of waterborne superhydrophobic fabrics with high impalement resistance and stretching stability by constructing elastic reconfigurable micro-/micro-/nanostructures. Following theoretical analysis, two approaches were proposed and employed: (i) regulating distance between the microfibers of polyester fabrics to decrease the solid–liquid contact area, and (ii) forming reconfigurable two-tier hierarchical micro-/nanostructures on the microfibers by stretching during dipping to further decrease the solid–liquid contact area. The effects of microfiber distance and micro-/nanostructures on microfibers on superhydrophobicity and impalement resistance were studied. The superhydrophobic fabrics show excellent impalement resistance as verified by high-speed water impact, water jetting, and rainfall, etc. The fabrics also show excellent stretching stability, as 100% stretching and 1000 cycles of cyclic 100% stretching–releasing have no obvious influence on superhydrophobicity. Additionally, the fabrics show good antifouling property, self-cleaning performance, as well as high abrasion and washing stability. The experimental results agree with the theoretical simulation very well. We anticipate that this study will boost the development of impalement-resistant and stretching-stable superhydrophobic surfaces

Design of a Separated Solar Interfacial Evaporation System for Simultaneous Water and Salt Collection

Solar-driven interfacial evaporation (SIE) is very promising to alleviate the freshwater scarcity issue. However, salt deposition on the sample surface will reduce evaporation performance, and compromised light absorption will result in a low water collection rate in conventional SIE apparatuses. Here, we report the design of a separated SIE system composed of a polypyrrole@Co3O4@aluminum sheet and a T-shaped superhydrophilic polyethylene/polypropylene nonwoven fabric right under the sheet. The photothermal surface exposed outside the closed SIE system is separated from the evaporation surface. Thus, salt fouling of solar evaporators is thoroughly avoided and the freshwater collection rate is greatly enhanced. Compared with conventional SIE systems, the separated SIE system has many advantages: simultaneous water and salt collection, a long-term stable evaporation rate even for concentrated brine (1.25 kg m–2 h–1 under 1 kW m–2 (1 sun) illumination, 15 wt % NaCl(aq), ≥120 h), high salt collection efficiency (≥97%), and a high water collection rate under natural sunlight, e.g., 0.72 kg m–2 h–1 in early spring (0.5–0.6 sun, 19–24 °C) and 0.33 kg m–2 h–1 in cold winter (0.3–0.4 sun, −6 to 4 °C). We foresee that the separated SIE system holds great potential for practical freshwater and salt collection from seawater