The Environmental Impact of Micro/Nanomachines: A Review

Environmental sustainability represents a major challenge facing our world. Recent advances in synthetic micro/nanomachines have opened new horizons for addressing environmental problems. This review article highlights the opportunities and challenges in translating the remarkable progresses in nanomotor technology toward practical environmental applications. It covers various environmental areas that would benefit from these developments, including nanomachine-enabled degradation and removal of major contaminants or nanomotor-based water quality monitoring. Future operations of autonomous intelligent multifunctional nanomachines, monitoring and responding to hazardous chemicals (in a “sense and destroy” mode) and using bioinspired chemotactic search strategies to trace chemical plumes to their source, are discussed, along with the challenges of moving these exciting research efforts to larger-scale pilot studies and eventually to field applications. With continuous innovations, we expect that man-made nano/microscale motors will have profound impact upon the environment

Water-Driven Micromotors

We demonstrate the first example of a water-driven bubble-propelled micromotor that eliminates the requirement for the common hydrogen peroxide fuel. The new water-driven Janus micromotor is composed of a partially coated Al–Ga binary alloy microsphere prepared <i>via</i> microcontact mixing of aluminum microparticles and liquid gallium. The ejection of hydrogen bubbles from the exposed Al–Ga alloy hemisphere side, upon its contact with water, provides a powerful directional propulsion thrust. Such spontaneous generation of hydrogen bubbles reflects the rapid reaction between the aluminum alloy and water. The resulting water-driven spherical motors can move at remarkable speeds of 3 mm s^–1 (<i>i</i>.<i>e</i>., 150 body length s^–1), while exerting large forces exceeding 500 pN. Factors influencing the efficiency of the aluminum–water reaction and the resulting propulsion behavior and motor lifetime, including the ionic strength and environmental pH, are investigated. The resulting water-propelled Al–Ga/Ti motors move efficiently in different biological media (<i>e</i>.<i>g</i>., human serum) and hold considerable promise for diverse biomedical or industrial applications

'Lapideum regnum'

We demonstrate the first example of a water-driven bubble-propelled micromotor that eliminates the requirement for the common hydrogen peroxide fuel. The new water-driven Janus micromotor is composed of a partially coated Al–Ga binary alloy microsphere prepared <i>via</i> microcontact mixing of aluminum microparticles and liquid gallium. The ejection of hydrogen bubbles from the exposed Al–Ga alloy hemisphere side, upon its contact with water, provides a powerful directional propulsion thrust. Such spontaneous generation of hydrogen bubbles reflects the rapid reaction between the aluminum alloy and water. The resulting water-driven spherical motors can move at remarkable speeds of 3 mm s^–1 (<i>i</i>.<i>e</i>., 150 body length s^–1), while exerting large forces exceeding 500 pN. Factors influencing the efficiency of the aluminum–water reaction and the resulting propulsion behavior and motor lifetime, including the ionic strength and environmental pH, are investigated. The resulting water-propelled Al–Ga/Ti motors move efficiently in different biological media (<i>e</i>.<i>g</i>., human serum) and hold considerable promise for diverse biomedical or industrial applications

Hydrogen-Bubble-Propelled Zinc-Based Microrockets in Strongly Acidic Media

Tubular polyaniline (PANI)/Zn microrockets are described that display effective autonomous motion in extreme acidic environments, without any additional chemical fuel. These acid-driven hydrogen-bubble-propelled microrockets have been electrosynthesized using the conical polycarbonate template. The effective propulsion in acidic media reflects the continuous thrust of hydrogen bubbles generated by the spontaneous redox reaction occurring at the inner Zn surface. The propulsion characteristics of PANI/Zn microrockets in different acids and in human serum are described. The observed speed–pH dependence holds promise for sensitive pH measurements in extreme acidic environments. The new microrockets display an ultrafast propulsion (as high as 100 body lengths/s) along with attractive capabilities including guided movement and directed cargo transport. Such acid-driven microtubular rockets offer considerable potential for diverse biomedical and industrial applications

Water-Driven Micromotors

We demonstrate the first example of a water-driven bubble-propelled micromotor that eliminates the requirement for the common hydrogen peroxide fuel. The new water-driven Janus micromotor is composed of a partially coated Al–Ga binary alloy microsphere prepared <i>via</i> microcontact mixing of aluminum microparticles and liquid gallium. The ejection of hydrogen bubbles from the exposed Al–Ga alloy hemisphere side, upon its contact with water, provides a powerful directional propulsion thrust. Such spontaneous generation of hydrogen bubbles reflects the rapid reaction between the aluminum alloy and water. The resulting water-driven spherical motors can move at remarkable speeds of 3 mm s^–1 (<i>i</i>.<i>e</i>., 150 body length s^–1), while exerting large forces exceeding 500 pN. Factors influencing the efficiency of the aluminum–water reaction and the resulting propulsion behavior and motor lifetime, including the ionic strength and environmental pH, are investigated. The resulting water-propelled Al–Ga/Ti motors move efficiently in different biological media (<i>e</i>.<i>g</i>., human serum) and hold considerable promise for diverse biomedical or industrial applications

Hydrogen-Bubble-Propelled Zinc-Based Microrockets in Strongly Acidic Media

Tubular polyaniline (PANI)/Zn microrockets are described that display effective autonomous motion in extreme acidic environments, without any additional chemical fuel. These acid-driven hydrogen-bubble-propelled microrockets have been electrosynthesized using the conical polycarbonate template. The effective propulsion in acidic media reflects the continuous thrust of hydrogen bubbles generated by the spontaneous redox reaction occurring at the inner Zn surface. The propulsion characteristics of PANI/Zn microrockets in different acids and in human serum are described. The observed speed–pH dependence holds promise for sensitive pH measurements in extreme acidic environments. The new microrockets display an ultrafast propulsion (as high as 100 body lengths/s) along with attractive capabilities including guided movement and directed cargo transport. Such acid-driven microtubular rockets offer considerable potential for diverse biomedical and industrial applications

Hydrogen-Bubble-Propelled Zinc-Based Microrockets in Strongly Acidic Media

Tubular polyaniline (PANI)/Zn microrockets are described that display effective autonomous motion in extreme acidic environments, without any additional chemical fuel. These acid-driven hydrogen-bubble-propelled microrockets have been electrosynthesized using the conical polycarbonate template. The effective propulsion in acidic media reflects the continuous thrust of hydrogen bubbles generated by the spontaneous redox reaction occurring at the inner Zn surface. The propulsion characteristics of PANI/Zn microrockets in different acids and in human serum are described. The observed speed–pH dependence holds promise for sensitive pH measurements in extreme acidic environments. The new microrockets display an ultrafast propulsion (as high as 100 body lengths/s) along with attractive capabilities including guided movement and directed cargo transport. Such acid-driven microtubular rockets offer considerable potential for diverse biomedical and industrial applications

Rocket Science at the Nanoscale

Autonomous propulsion at the nanoscale represents one of the most challenging and demanding goals in nanotechnology. Over the past decade, numerous important advances in nanotechnology and material science have contributed to the creation of powerful self-propelled micro/nanomotors. In particular, micro- and nanoscale rockets (MNRs) offer impressive capabilities, including remarkable speeds, large cargo-towing forces, precise motion controls, and dynamic self-assembly, which have paved the way for designing multifunctional and intelligent nanoscale machines. These multipurpose nanoscale shuttles can propel and function in complex real-life media, actively transporting and releasing therapeutic payloads and remediation agents for diverse biomedical and environmental applications. This review discusses the challenges of designing efficient MNRs and presents an overview of their propulsion behavior, fabrication methods, potential rocket fuels, navigation strategies, practical applications, and the future prospects of rocket science and technology at the nanoscale

Hydrogen-Bubble-Propelled Zinc-Based Microrockets in Strongly Acidic Media

Tubular polyaniline (PANI)/Zn microrockets are described that display effective autonomous motion in extreme acidic environments, without any additional chemical fuel. These acid-driven hydrogen-bubble-propelled microrockets have been electrosynthesized using the conical polycarbonate template. The effective propulsion in acidic media reflects the continuous thrust of hydrogen bubbles generated by the spontaneous redox reaction occurring at the inner Zn surface. The propulsion characteristics of PANI/Zn microrockets in different acids and in human serum are described. The observed speed–pH dependence holds promise for sensitive pH measurements in extreme acidic environments. The new microrockets display an ultrafast propulsion (as high as 100 body lengths/s) along with attractive capabilities including guided movement and directed cargo transport. Such acid-driven microtubular rockets offer considerable potential for diverse biomedical and industrial applications

Catalytic Iridium-Based Janus Micromotors Powered by Ultralow Levels of Chemical Fuels

We describe catalytic micromotors powered by remarkably low concentrations of chemical fuel, down to the 0.0000001% level. These Janus micromotors rely on an iridium hemispheric layer for the catalytic decomposition of hydrazine in connection to SiO₂ spherical particles. The micromotors are self-propelled at a very high speed (of ∼20 body lengths s^–1) in a 0.001% hydrazine solution due to osmotic effects. Such a low fuel concentration represents a 10 000-fold decrease in the level required for common catalytic nanomotors. The attractive propulsion performance, efficient catalytic energy-harvesting, environmentally triggered swarming behavior, and magnetic control of the new Janus micromotors hold considerable promise for diverse practical applications