Additional file 6 of Prognostic biomarker SMARCC1 and its association with immune infiltrates in hepatocellular carcinoma

Additional file 6: Figure 6. Relationships of SMARCC1 with the other 10 DNA methylation sites in HCC based on TCGA database

Additional file 5 of Prognostic biomarker SMARCC1 and its association with immune infiltrates in hepatocellular carcinoma

Additional file 5: Figure 5. a The prognostic values of the other 4 transcription factors in HCC from Kaplan‐Meier Plotter online tool. b The relevance of SMARCC1 expression in relation to the other 4 transcription factors expression in HCC from GEPIA database

Additional file 1 of Prognostic biomarker SMARCC1 and its association with immune infiltrates in hepatocellular carcinoma

Additional file 1: Figure 1. SMARCC1 mRNA expression levels of HCC patients in subgroups with different ages, genders, races, weights tumour stages, tumour grades,metastasis status and TP‐53 mutant

Additional file 2 of Prognostic biomarker SMARCC1 and its association with immune infiltrates in hepatocellular carcinoma

Additional file 2: Figure 2. The survival curve were analyzed in regards to the mRNA expression level of SMARCC1 in subgroups of HCC patients. OS analysis of Male, Asian race, Alcohol consumption, Hepatitis virus infected, Female, White race, Non-alcohol consumption and Non-hepatitis virus infected. OS, overall survival

Additional file 3 of Prognostic biomarker SMARCC1 and its association with immune infiltrates in hepatocellular carcinoma

Additional file 3: Figure 3. The relevance of SMARCC1 gene expression in relation to the 10 hub genes

Additional file 4 of Prognostic biomarker SMARCC1 and its association with immune infiltrates in hepatocellular carcinoma

Additional file 4: Figure 4. The prognostic values of the top 10 hub genes in HCC

Adhering Low Surface Energy Materials without Surface Pretreatment via Ion–Dipole Interactions

Low surface energy materials resist adhesion due to their chemical inertness and non-wetting properties. Herein, we report the creation of a transparent ionogel adhesive that uses ion–dipole interactions to achieve a higher bonding performance to polytetrafluoroethylene (PTFE) relative to most commercial glues. The ionogel adhesive is composed of a poly­(hexafluorobutyl acrylate-co-methyl methacrylate) random copolymer and a hydrophobic ionic liquid. The prepared ionogel can adhere to various hydrophobic substrates, such as PTFE, polypropylene, and polyethylene, as well as hydrophilic glass, ceramics, and steel. The design strategy and adhesion behavior are well interpreted using the density functional theory calculations and molecular dynamics simulations. The straightforward ultraviolet-curing method, high optical clarity, versatile adhesion ability, and reversible adhesion capabilities make this high-performance adhesive a promising product for commercialization

Data_Sheet_1_Nitrogen and Phosphorus Co-doped Porous Carbon for High-Performance Supercapacitors.docx

As one of the most promising fast energy storage devices, supercapacitor has been attracting intense attention for many emerging applications. However, how to enhance the electrochemical performance of electrode materials is still the main issue among various researches. In this paper, hierarchical porous carbons derived from Eleocharis dulcis has been prepared by chemical activation process with the aid of KOH at elevated temperature. Results show that the N, P co-doped porous carbon exhibits excellent electrochemical performance, it owns a specific capacitance of 340.2 F/g at 1 A/g, and obtains outstanding cycling stability of 96.9% of capacitance retention at 10 A/g after 5,000 cycles in a three-electrode system. Moreover, in the two-electrode system, the product still maintains a high specific capacitance of 227.2 F/g at 1 A/g, and achieves good electrochemical cycle stability (94.2% of capacitance retention at 10 A/g after 10,000 cycles); besides, its power/energy density are 3694.084 and 26.289 Wh/kg, respectively. Therefore, the combination of facile synthesis strategy and excellent electrochemical performance makes Eleocharis dulcis-based porous carbon as a promising electrode material for supercapacitor.</p

Nickel-Catalyzed Ring-Opening of Benzofurans for the Divergent Synthesis of <i>ortho</i>-Functionalized Phenol Derivatives

The ring-opening reaction of benzofuran is a highly desirable, yet underdeveloped transformation for the construction of valuable phenol derivatives. Herein, we report a nickel-catalyzed ring-opening transformation of benzofuran with silanes, giving ortho-alkene-, branched/linear alkyl silane-, and alkenyl silane-substituted phenol derivatives selectively. Control experiments and DFT calculations supported Ni–H insertion and β–O elimination to achieve the formal C–O bond activation of benzofuran but not through the direct oxidative addition of nickel (0) into the C–O bond of benzofurans. Further regioselective hydrosilylation or dehydrogenative silylation occurs via Ni­(I)–H or Ni­(I)–[Si] intermediates to form ortho-branched/linear alkyl silane- or alkenyl silane-substituted phenol derivatives