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Modulating CO<sub>2</sub> Adsorption in Metal–Organic Frameworks via Metal-Ion Doping
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novel metal–organic framework {[Ni<sub>6</sub>(OH)<sub>4</sub>(BTB)<sub>8/3</sub>(H<sub>2</sub>O)<sub>6</sub>]·4H<sub>2</sub>O·9DMF}<sub><i>n</i></sub> (DMF = dimethylformamide)
based on 1,3,5-benzenetribenzoic acid (H<sub>3</sub>BTB) was successfully
synthesized under basic condition at room temperature, featuring a
unique twofold interpenetrated <b>pcu</b>-type net with [Ni<sub>6</sub>(OH)<sub>4</sub>(COO)<sub>8</sub>(H<sub>2</sub>O)<sub>6</sub>] cluster as building block. Its gas-adsorption behaviors
were investigated and modified by utilizing metal<sup>II</sup>-doped
procedure, which was certified to be a highly effective pathway in
enhancing CO<sub>2</sub> uptake capacity
